Near‐infrared spectra of clinopyroxenes: Effects of calcium content and crystal structure

Abstract– Pyroxenes are among the most common minerals in the solar system and are ideally suited for remote geochemical analysis because of the sensitivity of their distinctive spectra to mineral composition. Fe²⁺ is responsible for the dominant pyroxene absorptions in the visible and near‐infrared, but substitutions of other cations such as Ca²⁺ change the crystal structure and site geometries and thus the crystal field splitting energies of the Fe cations. To define spectral systematics resulting from major pyroxene cations (Ca²⁺, Mg²⁺, and Fe²⁺), we focus on a suite of pyroxenes synthesized with only Ca²⁺, Mg²⁺, and Fe²⁺ in the two octahedral sites, specifically examining the effect of Ca²⁺ on pyroxene absorption bands. The modified Gaussian model is used to deconvolve pyroxene spectra into component bands that can then be linked directly to crystal field absorptions. In orthopyroxenes and low‐Ca clinopyroxenes, Ca²⁺‐content has a strong and predictable effect on the positions of the absorption bands. At a threshold of Wo₃₀, the crystal field environment stagnates and the M2 bands cease to change significantly as more Ca²⁺ is added. At Wo₅₀, when most of the M2 sites are filled by Ca²⁺, band positions do not change drastically, although the presence and strengths of the 1 and 2 μm bands are affected by even trace amounts of Fe²⁺ in the M2 site. It is thus apparent that next‐nearest neighbors and the distortions they impose on the pyroxene lattice affect the electronic states around the Fe²⁺ cations and control absorption band properties.     

Modification of a Parametrization of Shallow Convection in the Grey Zone Using a Mesoscale Model

In current operational numerical weather prediction models, the effect of shallow convection is parametrized. The grey zone of shallow convection is found between the horizontal resolutions of mesoscale numerical models (2–3 km) and large-eddy simulations (10–100 m or finer). At these horizontal scales the shallow convection is to some extent explicitly resolved by the model. The shallow-convection parametrization is still needed, but has to be regulated according to the model horizontal resolution. Here the behaviour of the non-hydrostatic mesoscale numerical weather prediction model Application of Research to Operations at Mesoscale is examined in the grey zone and a new scale-adaptive surface closure of its shallow-convection parametrization, dependent on horizontal resolution, is defined based on large-eddy simulation. The new closure is tested on a series of numerical experiments and validated on a 15-day-long real case period. Its impact on the development of deep convection is examined in detail. The idealized simulations show promising results, as the mean profiles of the subgrid and resolved turbulence change in the desired way. Based on the real case tests our modification has a low impact on model performance, but is part of a set of upgrades of the current parametrization that is aimed to treat the shallow convection grey zone.     

The lunar rock and mineral characterization consortium: Deconstruction and integrated mineralogical,petrologic, and spectroscopic analyses of mare basalts

The lunar rock and mineral characterization consortium (LRMCC) has conducted coordinated mineralogy/petrography/spectroscopy analyses of a suite of pristine lunar basalts. Four basalt slabs (two low‐Ti, two high‐Ti) and paired thin sections were analyzed. Thin sections were analyzed for mineralogy/petrography, while the slabs were used to prepare particulate separates of major mineral phases and bulk samples. Mineral separates and particulate bulk samples were crushed to controlled grain sizes and their reflectance spectra measured in the NASA RELAB at Brown University. The resulting data set provides an essential foundation for spectral mixing models, offers valuable endmember constraints for space weathering analyses, and represents critical new ground truth results for lunar science and exploration efforts.     

Contrasting rainfall generated debris flows from adjacent watersheds at Forest Falls, southern California, USA

Debris flows are widespread and common in many steeply sloping areas of southern California. The San Bernardino Mountains community of Forest Falls is probably subject to the most frequently documented debris flows in southern California. Debris flows at Forest Falls are generated during short-duration high-intensity rains that mobilize surface material. Except for debris flows on two consecutive days in November 1965, all the documented historic debris flows have occurred during high-intensity summer rainfall, locally referred to as ‘monsoon’ or ‘cloudburst’ rains. Velocities of the moving debris range from about 5 km/h to about 90 km/h. Velocity of a moving flow appears to be essentially a function of the water content of the flow. Low velocity debris flows are characterized by steep snouts that, when stopped, have only small amounts of water draining from the flow. In marked contrast are high-velocity debris flows whose deposits more resemble fluvial deposits. In the Forest Falls area two adjacent drainage basins, Snow Creek and Rattlesnake Creek, have considerably different histories of debris flows. Snow Creek basin, with an area about three times as large as Rattlesnake Creek basin, has a well developed debris flow channel with broad levees. Most of the debris flows in Snow Creek have greater water content and attain higher velocities than those of Rattlesnake Creek. Most debris flows are in relative equilibrium with the geometry of the channel morphology. Exceptionally high-velocity flows, however, overshoot the channel walls at particularly tight channel curves. After overshooting the channel, the flows degrade the adjacent levee surface and remove trees and structures in the immediate path, before spreading out with decreasing velocity. As the velocity decreases the clasts in the debris flows pulverize the up-slope side of the trees and often imbed clasts in them. Debris flows in Rattlesnake Creek are relatively slow moving and commonly stop in the channel. After the channel is blocked, subsequent debris flows cut a new channel upstream from the blockage that results in the deposition of new debris-flow deposits on the lower part of the fan. Shifting the location of debris flows on the Rattlesnake Creek fan tends to prevent trees from becoming mature. Dense growths of conifer seedlings sprout in the spring on the late summer debris flow deposits. This repeated process results in stands of even-aged trees whose age records the age of the debris flows.     

Cosmology from 3 years of WMAP CMB data

The combined 3 year observations from the Wilkinson Microwave Anisotropy Probe (WMAP) have yielded full-sky temperature and polarization maps in five frequency bands (K, Ka, Q, V, W) between 23 and 94 GHz. In this article we discuss the cosmological implications of these observations. The combination of temperature and polarization data leads to a significant improvement in the measurement of the reionization optical depth τ = 0.093 ± 0.029. This, in turn, breaks a number of key degeneracies present in the constraints from temperature measurements alone allowing the WMAP CMB data on its own to offer a powerful insight into the universe’s constituents and the processes that generated the initial conditions for structure formation.     

Governing geoengineering research: why, when and how?

Research on geoengineering – deliberate management of the Earth’s climate system – is being increasingly discussed within the science and policy communities. While justified as necessary in order to expand the range of options available to policy makers in the future, geoengineering research has already engendered public controversy. Proposed projects have been protested or cancelled, and calls for a governance framework abound. In this paper, we consider the reasons why geoengineering research might be subject to additional governance and suggest mechanisms that might be usefully applied in developing such a framework. We consider criteria for governance as raised by a review of the growing literature on geoengineering and other controversial scientific topics. We suggest three families of concern that any governance research framework must respond to: the direct physical risks of the research; the transparency and responsibility in decision making for the research; and the larger societal meanings of the research. We review what mechanisms might be available to respond to these three families of concern, and consider how these might apply to geoengineering research.     

The chemical changes of DOM from black waters to coastal marine waters by HPLC combined with ultrahigh resolution mass spectrometry

How dissolved organic matter (DOM) undergoes chemical changes during its transit from river to ocean remains a challenge due to its complex structure. In this study, DOM along a river transect from black waters to marine waters is characterized using an offline combination of reversed-phase high performance liquid chromatography (RP-HPLC) coupled to electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS), as well as tandem ESI-FTICR-MS. In addition, a water extract from degraded wood that mainly consists of lignins is used for comparison to the DOM from this transect. The HPLC chromatograms of all DOM samples and the wood extract show two major well-separated components; one is hydrophilic and the other is hydrophobic, based on their elution order from the C₁₈ column. From the FTICR-MS analysis of the HPLC fractions, the hydrophilic components mainly contain low molecular weight compounds (less than 400 Da), while the hydrophobic fractions contain the vast majority of compounds of the bulk C₁₈ extracted DOM. The wood extract and the DOM samples from the transect of black waters to coastal marine waters show strikingly similar HPLC chromatograms, and the FTICR-MS analysis further indicates that a large fraction of molecular formulas from these samples are the same, existing as lignin-like compounds. Tandem mass spectrometry experiments show that several representative molecules from the lignin-like compounds have similar functional group losses and fragmentation patterns, consistent with modified lignin structural entities in the wood extract and these DOM samples. Taken together, these data suggest that lignin-derived compounds may survive the transit from the river to the coastal ocean and can accumulate there because of their refractory nature.