Fluoride-Selective Electrode as a Tool to Evaluate the Degradation of PFAS in Groundwater: A Bench-Scale Investigation

Fluoride (F⁻) concentration in groundwater can be used as an independent measure of the degradation of per- and polyfluoroalkyl substances (PFAS) at contaminated sites. This study assessed the impact of the groundwater matrix, oxidizing reagents, quenching agent, and sample handling procedures (filtration) on determinations of F⁻. F⁻ was quantified using a fluoride-selective electrode (FSE) using matrix spike recovery (acceptable range 75 to 125%) and electrode slope performance (ideal range −54 to −60 mV). For the unaltered aqueous matrices considered (ultrapure water, ultrapure water with sodium chloride, and simulated groundwater), matrix spike recoveries were greater than 93% and acceptable electrode slopes (−59.5 ± 0.2 mV) were obtained. Matrix spike recoveries and electrode slopes when persulfate or permanganate was added were 87 and 93%, and −58.4 ± 1.3 and −47.3 ± 2.2 mV, respectively. Therefore, quantifying F⁻ in matrices containing permanganate should involve use of either a matrix-matched calibration curve or the method of standard additions due to the low electrode slope. The addition of ascorbic acid as a quenching agent resulted in a decrease in matrix spike recoveries to <74% and suggests alternate quenching procedures should be used if an FSE is employed to measure F⁻. Removal of sediments by filtration prior to the addition of the fluoride spike led to improved matrix spike recoveries (>96%), which were otherwise underestimated using the FSE in the presence of sediments. While the FSE may be a quick and portable tool, its significant limitations need to be fully understood before it can be used to quantify the production of F⁻ resulting from the potential degradation of PFAS at field sites.     

Lights, camera … action? Altered attitudes and behaviour in response to the climate change film The Age of Stupid

The film The Age of Stupid depicts the world in 2055 devastated by climate change, combining this with documentary footage which illustrates many facets of the problems of climate change and fossil-fuel dependency. This study investigates the effects of the film on UK viewers’ attitudes and behaviour through a three-stage survey. Analysis of changes in attitudes focussed particularly on respondents’ concern about climate change, motivation to act, fear about the potential for catastrophe, beliefs about responsibility for action, and sense of agency. The film increased concern about climate change, motivation to act, and viewers’ sense of agency, although these effects had not persisted 10-14 weeks after seeing it. It was also successful in promoting some mitigation actions and behavioural change, although respondents reported barriers to further action, such as limited options for improving home energy efficiency among those in rented accommodation. However, filmgoers were atypical of the general public in that they exhibited very high levels of concern about climate change, knowledge about how to reduce their carbon emissions, and contact with organisations campaigning about climate change, before they saw the film. The paper considers how these factors may have enabled viewers to respond to the film as they did, as well as policy implications for those seeking to develop effective climate change communications.     

Storylines: an alternative approach to representing uncertainty in physical aspects of climate change

Investigating the relationships between climate extremes and crop yield can help us understand how unfavourable climatic conditions affect crop production. In this study, two statistical models, multiple linear regression and random forest, were used to identify rainfall extremes indices affecting wheat yield in three different regions of the New South Wales wheat belt. The results show that the random forest model explained 41–67% of the year-to-year yield variation, whereas the multiple linear regression model explained 34–58%. In the two models, 3-month timescale standardized precipitation index of Jun.–Aug. (SPI_JJA), Sep.–Nov. (SPI_SON), and consecutive dry days (CDDs) were identified as the three most important indices which can explain yield variability for most of the wheat belt. Our results indicated that the inter-annual variability of rainfall in winter and spring was largely responsible for wheat yield variation, and pre-growing season rainfall played a secondary role. Frequent shortages of rainfall posed a greater threat to crop growth than excessive rainfall in eastern Australia. We concluded that the comparison between multiple linear regression and machine learning algorithm proposed in the present study would be useful to provide robust prediction of yields and new insights of the effects of various rainfall extremes, when suitable climate and yield datasets are available.     

Sensitivity of modern climate to the presence,strength and salinity of Mediterranean-Atlantic exchange in a global general circulation model

Mediterranean Outflow Water (MOW) is thought to be a key contributor to the strength and stability of Atlantic Meridional Overturning Circulation (AMOC), but the future of Mediterranean-Atlantic water exchange is uncertain. It is chiefly dependent on the difference between Mediterranean and Atlantic temperature and salinity characteristics, and as a semi-enclosed basin, the Mediterranean is particularly vulnerable to future changes in climate and water usage. Certainly, there is strong geologic evidence that the Mediterranean underwent dramatic salinity and sea-level fluctuations in the past. Here, we use a fully coupled atmosphere–ocean General Circulation Model to examine the impact of changes in Mediterranean-Atlantic exchange on global ocean circulation and climate. Our results suggest that MOW strengthens and possibly stabilises the AMOC not through any contribution towards NADW formation, but by delivering relatively warm, saline water to southbound Atlantic currents below 800 m. However, we find almost no climate signal associated with changes in Mediterranean-Atlantic flow strength. Mediterranean salinity, on the other hand, controls MOW buoyancy in the Atlantic and therefore affects its interaction with the shallow-intermediate circulation patterns that govern surface climate. Changing Mediterranean salinity by a factor of two reorganises shallow North Atlantic circulation, resulting in regional climate anomalies in the North Atlantic, Labrador and Greenland-Iceland-Norwegian Seas of ±4 °C or more. Although such major variations in salinity are believed to have occurred in the past, they are unlikely to occur in the near future. However, our work does suggest that changes in the Mediterranean’s hydrological balance can impact global-scale climate.     

Future projections of temperature-related climate change impacts on the railway network of Great Britain

Great Britain’s main line railway network is known to experience various temperature-related impacts, e.g. track buckling and overhead power line sag at high ambient temperatures. Climate change could alter the frequency of occurrence of these impacts. We have therefore investigated the climate change impact on various temperature-related issues, identified during workshops with rail industry specialists, using a perturbed physics ensemble (PPE) of the Met Office’s regional climate model (RCM), HadRM3. We have developed novel approaches to combine RCM data with railway industry knowledge, typically by identifying key meteorological thresholds of interest and analysing exceedance of these out to the 2040s. We performed a statistical analysis of the projected changes for each issue, via bootstrapping of the unperturbed PPE member. Although neither the PPE nor the bootstrapping analysis samples the full range of uncertainty in the projections, they nonetheless provide complementary perspectives on the suitability of the projections for use in decision-making. Our main findings include projected increases in the summertime occurrence of temperature conditions associated with (i) track buckling, (ii) overhead power line sag, (iii) exposure of outdoor workers to heat stress, and (iv) heat-related delays to track maintenance; and (v) projected decreases in the wintertime occurrence of temperatures conditions associated with freight train failure owing to brake problems. For (i), the statistical significance varied with track condition and location; for (ii) and (iii), with location; and for (iv) and (v), projected changes were significant across Great Britain. As well as assessing the changes in climate-related hazard, information about the vulnerability of the network to past temperature-related incidents has been summarised. Combining the hazard and vulnerability elements will eventually support a climate risk assessment for the industry.     

Combining Organic Matter Source and Relative Trophic Position Determinations to Explore Trophic Structure

Stable isotope ratios of carbon and sulfur were used to assess organic matter utilization of numerically abundant consumers present in Apalachicola Bay, FL, USA. These results were used to infer nitrogen isotopic enrichment of organic matter sources in an effort to establish baseline δ ¹⁵N enrichment for trophic evaluations. We compared results from concentration-independent and concentration-dependent mixing models and found that the two methods resulted in widely different conclusions about the importance of organic matter sources that varied ninefold in sulfur concentrations. Nitrogen isotopic enrichment was used to determine relative trophic positions of consumer organisms. Source elemental concentrations of nitrogen were also considered in the calculation of relative trophic levels in a concentration-dependent approach. Concentration-independent and concentration-dependent methods of calculating trophic results were compared. While relative trophic levels of individual species varied continuously from approximately 1.7 to 3.5, comparisons of trophic level among consumers indicated four possible trophic groupings. Filter feeders (mussels and oysters) made up the lowest trophic tier while teleost fishes made up the highest trophic tier. Invertebrates sampled were assigned intermediate nondiscrete trophic levels. Because δ ¹⁵N values of important organic matter sources in the system were similar, the concentration-independent and concentration-dependent methods did not result in significantly different conclusions about trophic level for any of the consumers examined. However, a comparison of the two methods applied to a hypothetical case found that differences in base δ ¹⁵N values ranging approximately 4‰ resulted in significantly different trophic-level assignments when comparing the concentration-dependent and concentration-independent methods of trophic-level calculations. Our results confirm that consideration of the elemental concentrations of the base organisms is an important factor in determining source contributions and may affect trophic-level calculations in systems with a sufficient range of base nitrogen enrichment. However, this result depended on the relative isotopic signatures of the chosen sources and their elemental concentrations and should be considered individually for each system.     

Incidence of plastic fragments among burrow-nesting seabird colonies on offshore islands in northern New Zealand

Marine plastic pollution is ubiquitous throughout the world’s oceans, and has been found in high concentrations in oceanic gyres of both the northern and southern hemispheres. The number of studies demonstrating plastic debris at seabird colonies and plastic ingestion by adult seabirds has increased over the past few decades. Despite the recent discovery of a large aggregation of plastic debris in the South Pacific subtropical gyre, the incidence of plastics at seabird colonies in New Zealand is unknown. Between 2011 and 2012 we surveyed six offshore islands on the northeast coast of New Zealand’s North Island for burrow-nesting seabird colonies and the presence of plastic fragments. We found non-research related plastic fragments (0.031 pieces/m²) on one island only, Ohinau, within dense flesh-footed shearwater (Puffinus carneipes) colonies. On Ohinau, we found a linear relationship between burrow density and plastic density, with 3.5 times more breeding burrows in areas with plastic fragments found. From these data we conclude that plastic ingestion is a potentially a serious issue for flesh-footed shearwaters in New Zealand. Although these results do not rule out plastic ingestion by other species, they suggest the need for further research on the relationship between New Zealand’s pelagic seabirds and marine plastic pollution.     

A non-disturbing sampler for near-surface waters

A small, simple and inexpensive device is described which allows the sampling of waters with a minimum of disturbance. This is particularly important when determining near-surface profiles, for example, following a dye release.     

The Norwegian system and the distribution of claims to redfeed

Identifying competing interests and potential claims to a new marine resource, the plankton redfeed, which may be central as a solution to diminishing supplies of marine oils world wide, is critical prior to a commercial harvest thereof. The competing interests are found to be between those Norwegian fisheries organization taking an encompassing view of fisheries interests and those wanting more focus on the well-being of the coastal fishermen. Working within a corporatist setting, it is found, that interest organizations in Norway are included comprehensively by the national government in the decision-making process, but that the main group having the most power is Norges Fiskarlag, which will draw the quota distribution of a future redfeed harvest off shore and away from the coastal fishermen.