Thermal insulation of the intertidal zone by the ice foot

Few studies have looked at the ecological significance of the ice foot in intertidal habitats. During the 2007 winter, we quantified the hourly variation of temperature at the intertidal zone and at the upper, dry coast on the southern Gulf of St. Lawrence (Nova Scotia, Canada) using submersible data loggers. While air temperature dropped to − 20 °C at the peak of the winter, intertidal temperature was never below − 7 °C during the winter. In fact, for almost two months when the ice foot was stable, temperature ranged only between − 2.4 °C and − 1.1 °C at the intertidal zone. The intertidal values are higher than published values of lethal temperature for cold-water intertidal invertebrates and seaweeds. Thus, the ice foot may prevent these organisms from experiencing lethal levels of thermal stress, contributing to their long-term persistence in these environmentally stressful habitats.     

A billion years of environmental stability and the emergence of eukaryotes: new data from northern Australia

Carbon isotopes through 6km of fully cored drill holes in 1.7 to 1.5 Ga carbonates of the Mount Isa and McArthur basins, Australia (which host the earliest known eukaryote biomarkers) provide the most comprehensive and best-dated delta 13C stratigraphy yet obtained from such ancient rocks. Both basins reveal remarkably stable temporal delta 13C trends (mean of -0.6% +/- 2% PDB [Peedee belemnite]) and confirm the impression of delta 13C stasis between 2.0 and 1.0 Ga, which, together with other evidence, suggest a prolonged period of stability in crustal dynamics, redox state of surface environments, and planetary climate. This delta 13C stasis is consistent with great stability in the carbon cycle controlled, we suggest, by P limitation of primary productivity. Recent evidence shows that P depletion is a major factor in obligate associations between photosymbionts and host cells. We argue that a billion years of stability in the carbon and nutrient cycles may have been the driving force that propelled prokaryotes toward photosymbiosis and the emergence of the autotrophic eukaryote cell.     

A supplemental sampling method for estuarine ichthyoplankton with emphasis on the atherinidae

A three-stage sampler, filtering water from the 0–5 cm, 5–25 cm, and 25–45 cm microhorizons was tested during conventional ichthyoplankton studies. The sampler was as much as 240X more efficient than 0.5 m nets in the collection of larval atherinids. The atherinids were found most abundantly in the 0–5 cm microhorizon, probably due to a positive phototaxic response.     

Melting of a Hydrous Mantle: I. Phase Relations of Natural Peridotite at High Pressures and Temperatures with Controlled Activities of Water, Carbon Dioxide, and Hydrogen

Four natural peridotite nodules ranging from chemically depletedto Fe-rich, alkaline and calcic (SiO₂ = 43.7–45.7 wt.per cent, A1₂O₃ = 1.6O–8.21 wt. per cent, CaO = 0.70–8.12wt. per cent, alk = 0.10–0.90 wt. per cent and Mg/(Mg+Fe²⁺)= 0.94–0.85) have been investigated in the hypersolidusregion from 800? to 1250?C with variable activities of H₂O,CO₂, and H₂. The vapor-saturated peridotite solidi are 50–200?Cbelow those previously published. The temperature of the beginningof melting of peridotite decreases markedly with decreasingMg/(Mg+SFe) of the starting material at constant CaO/Al₂O₃.Conversely, lowering CaO/Al₂O₃ reduces the temperature at constantMg/(Mg+Fe) of the starting material. Temperature differencesbetween the solidi up to 200?C are observed. All solidi displaya temperature minimum reflecting the appearance of garnet. Thisminimum shifts to lower pressure with decreasing Mg/(Mg + Fe)of the starting material. The temperature of the beginning ofmelting decreases isobarically as approximately a linear functionof the mol fraction of H₂O in the vapor (X_H2O^v). The data alsoshow that some CO₂ may dissolve in silicate melts formed bypartial melting of peridotite. Amphibole (pargasitic hornblende) is a hypersolidus mineralin all compositions, although its P/T stability field dependson bulk rock chemistry. The upper pressure stability of amphiboleis marked by the appearance of garnet. The vapor-saturated (H₂O) liquidus curve for one peridotiteis between 1250? and 1300?C between 10 and 30 kb. Olivine, spinel,and orthopyroxene are either liquidus phases or co-exist immediatelybelow the temperature of the peridotite liquidus. The data suggest considerable mineralogical heterogeneity inthe oceanic upper mantle because the oceanic geotherm passesthrough the P/T band covering the appearance of garnet in variousperidotites. The variable depth to the low-velocity zone is explained byvariable aHjo conditions in the upper mantle and possibly alsoby variations in the composition of the peridotite itself. Itis suggested that komatiite in Precambrian terrane could formby direct melting of hydrous peridotite. Such melting requiresabout 1250?C compared with 1600?C which is required for drymelting. The genesis of kimberlite can be related to partial meltingof peridotite under conditions of X_H2O^v = 0.5–0.25 (X_CO2^v= 0.5–0.75). Such activities of H₂O result in meltingat depths ranging between 125 and 175 km in the mantle. Thisrange is within the minimum depth generally accepted for theformation of kimberlite.     

The deglaciation of Norway after 10,000 B.P.

Several distinctive marginal moraines of Preboreal age have been observed in Norway. They are grouped into three major morainal zones that are radiocarbon dated at about 9900±100, 9600±100 and 9300±100 B.P. respectively. The following deglaciation of central Norway was rapid and most likely completed about 8500 B.P. Evidence of glacier fluctuations up to recent time is discussed. The results are based partly on observations by the field parties of the I.G.C.P. project 'Quaternary Glaciations in the Northern Hemisphere'.     

Supersequences, superbasins, supercontinents – evidence from the Neoproterozoic–Early Palaeozoic basins of central Australia

Neoproterozoic sedimentary basins cover a large area of central Australia. They rest upon rigid continental crust that varies from c. 40–50 km in thickness. Whilst the crust was in part formed during the Archaean and early Palaeoproterozoic, its final assembly occurred at approximately 1.1 Ga as the Neoproterozoic supercontinent, Rodinia, came into being. The assembly process left an indelible imprint on the region producing a strong crustal fabric in the form of a series of north dipping thrusts that pervade much of the thick craton and extend almost to the Moho. Following a period of stability (1.1–0.8 Ga), a large area of central Australia, in excess of 2.5 × 10⁶ km², began to subside in synchroneity. This major event was due to mantle instability resulting from the insulating effect of Rodinia. Initially, beginning c. 900 Ma, a rising superplume uplifted much of central Australia leading to peneplanation of the uplifted region and the generation of large volumes of sand‐sized clastic materials. Ultimately, the decline of the superplume led to thermal recovery and the development of a sag basin (beginning at c. 800 Ma), which in turn resulted in the redistribution of the clastic sediments and the development of a vast sand sheet at the base of the Neoproterozoic succession. The superbasin generated by the thermal recovery was short lived (c. 20 M.y.) but, in conjunction with the crustal fabric developed during supercontinent assembly, it set the stage for further long‐term basin development that extended for half a billion years well into the Late Palaeozoic. Following the sag phase at least five major tectonic episodes influenced the central Australian region. Compressional tectonics reactivated earlier thrust faults that had remained dormant within the crust, disrupting the superbasin, causing uplift of basement blocks and breaking the superbasin into the four basins now identified within the central Australian Neoproterozoic succession (Officer, Amadeus, Ngalia and Georgina Basin). These subsequent tectonic events produced the distinctive foreland architecture associated with the basins and were perhaps the trigger for the Neoproterozoic ice ages. The reactivated basins became asymmetric with major thrust faults along one margin paralleled by deep narrow troughs that formed the main depocentres for the remaining life of the basins. The final major tectonic event to influence the central Australian basins, the Alice Springs Orogeny, effectively terminated sedimentation in the region in the Late Palaeozoic (c. 290 Ma). Of the six tectonic episodes recorded in the basinal succession only one provides evidence of extension, suggesting the breakup of east Gondwana at the end of the Rodinian supercontinent cycle may have occurred at close to the time of the Precambrian–Cambrian boundary. The central Australian basins are thus the products of events surrounding the assembly and dispersal of Rodinia.     

Zero-valent iron and organic carbon mixtures for remediation of acid mine drainage: Batch experiments

A series of laboratory batch experiments was conducted to evaluate the potential for treatment of acid mine drainage (AMD) using organic C (OC) mixtures amended by zero-valent Fe (Fe⁰). Modest increases in SO₄ reduction rates (SRRs) of up to 15% were achieved by augmenting OC materials with 5 and 10 dry wt% Fe⁰. However, OC was essential for supporting SO₄ reducing bacteria (SRB) and therefore SO₄ reduction. This observation suggests a general absence of autotrophic SRB which can utilize H₂ as an electron donor. Sulfate reduction rates (SRRs), calculated using a mass-based approach, ranged from −12.9 to −14.9 nmol L⁻¹ d⁻¹  g⁻¹ OC. Elevated populations of SRB, iron reducing bacteria (IRB), and acid producing (fermentative) bacteria (APB) were present in all mixtures containing OC. Effective removal of Fe (91.6–97.6%), Zn (>99.9%), Cd (>99.9%), Ni (>99.9%), Co (>99.9%), and Pb (>95%) was observed in all reactive mixtures containing OC. Abiotic metal removal was achieved with Fe⁰ only, however Fe, Co and Mn removal was less effective in the absence of OC. Secondary disordered mackinawite [Fe_1+xS] was observed in field-emission scanning electron microscopy (FE-SEM) backscatter electron micrographs of mixtures that generated SO₄ reduction. Energy dispersive X-ray (EDX) spectroscopy revealed that Fe–S precipitates were Fe-rich for mixtures containing OC and Fe⁰, and S-rich in the absence of Fe⁰ amendment. Sulfur K-edges determined by synchrotron-radiation based bulk X-ray absorption near-edge structure (XANES) spectroscopy indicate solid-phase S was in a reduced form in all mixtures containing OC. Pre-edge peaks on XANES spectra suggest tetragonal S coordination, which is consistent with the presence of an Fe–S phase such as mackinawite. The addition of Fe⁰ enhanced AMD remediation over the duration of these experiments, however long-term evaluation is required to identify optimal Fe⁰ and OC mixtures.