Leachable particulate iron in the Columbia River,estuary, and near-field plume

This study examines the distribution of leachable particulate iron (Fe) in the Columbia River, estuary, and near-field plume. Surface samples were collected during late spring and summer of 2004–2006 as part of four River Influence on Shelf Ecosystems (RISE) cruises. Tidal amplitude and river flow are the primary factors influencing the estuary leachable particulate Fe concentrations, with greater values during high flow and/or spring tides. Near the mouth of the estuary, leachable particulate Fe [defined as the particulate Fe solubilized with a 25% acetic acid (pH 2) leach containing a weak reducing agent to reduce Fe oxyhydroxides and a short heating step to access intracellular Fe] averaged 770 nM during either spring tide or high flow, compared to 320 nM during neap tide, low flow conditions. In the near-field Columbia River plume, elevated leachable particulate Fe concentrations occur during spring tides and/or higher river flow, with resuspended shelf sediment as an additional source to the plume during periods of coastal upwelling and spring tides. Near-field plume concentrations of leachable particulate Fe (at a salinity of 20) averaged 660 nM during either spring tide or high flow, compared to 300 nM during neap tide, low flow conditions. Regardless of tidal amplitude and river flow, leachable particulate Fe concentrations in both the river/estuary and near-field plume are consistently one to two orders of magnitude greater than dissolved Fe concentrations. The Columbia River is an important source of reactive Fe to the productive coastal waters off Oregon and Washington, and leachable particulate Fe is available for solubilization following biological drawdown of the dissolved phase. Elevated leachable Fe concentrations allow coastal waters influenced by the Columbia River plume to remain Fe-replete and support phytoplankton production during the spring and summer seasons.     

Active mud volcanoes on the upper slope of the western Nile deep-sea fan—first results from the P362/2 cruise of R/V Poseidon

In February 2008, cruise P362/2 was undertaken aboard R/V Poseidon to the Giza and North Alex mud volcanoes (MVs) on the upper slope of the western Nile deep-sea fan. Emitted fluids were strongly depleted in chloride and rich in hydrocarbons, predominantly of thermogenic origin. In-situ sediment temperature measurements indicate extremely high and moderate levels of activity for the North Alex MV and Giza MV, respectively, and suggest rapid changes from dormant to active stages. Both the physical properties of core sediments (e.g., color and magnetic susceptibility), and their assemblages of micro- and nannofossils point to different sources for the two mud volcanoes. Biostratigraphic dating suggests source depths of 2,100–2,450 mbsf for the Giza MV and 1,150–1,550 mbsf for the North Alex MV. Very high temperatures of up to 70°C in shallow sediments at the North Alex MV can be explained only if the fluid source were warmer and deeper than the sediment source.     

变质作用、板块构造及超级大陆旋回

麻粒岩相超高温变质作用（GUHTM）主要发育于新太古代至寒武纪岩石中;推测在深部较年轻的,特别是新生代造山带岩石中也会有GUHTM存在。岩石中最初出现GUHTM记录意味着产生瞬时极高热流处的地球动力学发生了改变。许多GUHTM带可能发育于类似现代大陆弧后的构造背景中。在较热的地球上,超大陆及其裂解形成的循环组合,尤其是经岩石圈减薄的洋盆卷入到其外翻过程中可能产生比现代太平洋边缘更热的大陆弧后。中温榴辉岩 高压麻粒岩相变质作用（EHPGM）也是最先发现于新太古代岩石记录中,并发育于从元古宙至古生代岩石中。EHPGM带是对GUHTM带的补充,并经常认为是记录了从俯冲至碰撞造山作用的过程。在元古宙岩石记录中的蓝片岩明显记录了与现代俯冲作用相关的低热流梯度。以发育柯石英(±硬柱石)或金刚石为特征的硬柱石蓝片岩和榴辉岩（高压变质作用,HPM）及超高压变质岩（UHPM）主要是在显生宙形成。HPMUHPM记录了显生宙俯冲碰撞造山带早期碰撞过程中的低热流梯度及陆壳的深俯冲作用。尽管与直觉不同,在超级大陆聚敛期（Wilson旋回洋盆打开和关闭）的大陆地块增生过程,许多HPMUHPM带看来确实是通过小洋盆关闭而发育起来的,反映双重热体制的双重变质带仅发育于新太古代以来的岩石记录中。双重热体制是现代板块构造的特点,而双重变质作用则是板块构造在岩石记录中的特征性标志。尽管构造样式很可能不同,新太古代以来GUHTM和EHPGM带的发育证明“元古宙板块构造体制”的开始。以冷俯冲和大陆地壳深俯冲至地幔,以及其中的部分又从深达300 km处发生折返为标志,“元古宙板块构造体制”在新元古代进化为“现代板块构造体制”,这个转变可由岩石中的HPMUHPM证明。记录这种极端条件的变质带年龄是不一致的,而变质作用发生时间与各大陆岩石圈聚合到超级克拉通（如Superia/Sclavia）或超级大陆（如Nuna (Columbia), Rodinia, Gondwana, 和Pangea）的时间却是一致的。     

Multi‐proxy study of Holocene environmental change and human activity in the Central Apennine Mountains,Italy

This paper describes a multi‐proxy palaeoecological investigation undertaken in conjunction with an archaeological survey of the Upper Sangro Valley in the Abruzzo National Park, Central Italy. Despite being a biodiversity hotspot and regarded as a near‐pristine area, the pollen, spore and diatom data all show major changes in the vegetation extending to over 2000 m a.s.l. during the mid to late Holocene. Although there are changes in ecological composition earlier in the Holocene they are different in type and magnitude from the changes which began about 800 cal a BC. The pollen and diatom evidence do not correlate well with regional palaeoclimate data, or on‐site isotopic evidence, but do appear to be related to Samnite (later Iron Age) clearance and upland grazing associated with transhumance and later annexation (and centuriation) of the lower slopes by Roman surveyors. The greatest change in vegetation was during the period c. AD 500–600 and corresponds with the Byzantine–Gothic Wars, and Lombard–Carolingian settlement reorganization into nucleated hilltop settlements which managed upland grazing. This pattern of intensive land use at all altitudes persisted until the early 20th century and only changed following rural depopulation after World War II. These data illustrate how cultural factors had a profound effect on this mountainous region which, in this case, far outweighed the effects of climatic fluctuations which are known to have occurred from both this study area and the region. Copyright © 2012 John Wiley & Sons, Ltd.     

Geodynamic modelling of the Century deposit,Mt Isa Province,Queensland

This paper is concerned with an example of quantitative modelling of orebody formation as a guide to reducing the risk for future mineral exploration. Specifically, the paper presents a detailed 3–D numerical model for the formation of the Century zinc deposit in northern Queensland. The model couples fluid flow with deformation, thermal transport and chemical reactions. The emphasis of the study is a systems approach where the holistic mineralising system is considered rather than concentrating solely on the mineral deposit. In so doing the complete plumbing system for mineralisation is considered with a view to specifying the critical conditions responsible for the ore deposit occurring where it does and having the size and metal grades that are observed. The numerical model is based on detailed geological, tectonic, isotopic and mineralogical data collected over the past 20 years. The conclusions are that the Century zinc deposit is located where it is because of the following factors: (i) a thermal anomaly is associated with the Termite Range Fault due to advection of heat from depth by fluid flow up the Termite Range Fault; (ii) bedding‐plane fissility in the shale rocks hosting the Century zinc deposit has controlled the wavelength and nature of D₁ folding in the vicinity of the deposit and has also controlled increases in permeability due to hydrofracture of the shales; such hydrofracture is also associated with the production of hydrocarbons as these shales passed through the ‘oil‐window’; (iii) Pb–Zn leached from crustal rocks in the stratigraphic column migrated up along faults normal to the Termite Range Fault driven by topographic relief associated with inversion at the end of the Isan Orogeny; these fluids mixed with H₂S derived at depth moving up the Termite Range Fault to mix with the crustal fluids to precipitate Pb–Zn in a plume downstream from the point of mixing. Critical factors to be used as exploration guides are high temperatures, carbonaceous fissile shales now folded into relatively tight D₁ folds, fault‐controlled plumbing systems that enable fluid mixing, depletion of metals upstream of the deposit and,in particular,a very wide Fe‐depletion halo upstream of the deposit.     

Spatial correlation of marine wind‐speed observations

Abstract

The spatial characteristics of the wind speeds from ships, drilling platforms, and satellites (SASS and SMMR) were investigated through autocorrelation analysis. Values of the spatial correlation coefficient in minimum separation classes revealed that SASS winds contained the least noise, followed by drilling‐platform and SMMR winds, measured ship winds and estimated ship winds. The variances explained by wind‐speed observations within a 100‐km radius of each other were found to be 86, 72, 62, 48 and 41%, respectively. Ship wind‐speed estimates made during hours of darkness showed significantly higher noise than daytime reports.     

Application of stress mapping in cross‐section to understanding ore geometry,predicting ore zones and development of drilling strategies

Stress mapping is a numerical modelling technique used to determine the distribution and relative magnitude of stress during deformation in a mineralised terrane. It is based on the general principle that fluid flow in the Earth's crust is primarily related to pressure gradients. It is best applied to epigenetic hydrothermal mineral deposits, where fluid flow and fluid flux are enhanced in dilational sections of structures and in sites of enhanced rock permeability due to high fracture density. These are defined by sites of low minimum principal stress (σ₃). Most stress mapping is carried out in two dimensions in plan view using geological maps. This is suitable for terranes with steeply dipping lithostratigraphy and structures in which the distribution of mineral deposits is largely controlled by fault structures portrayed on the maps. However, for terranes with gently dipping sequences and structures, and for situations where deposits are sited in and near the hinges of complex fold structures, stress mapping in cross‐section is preferable. The effectiveness of stress mapping is maximised if mineralisation was late in the evolutionary history of the host terrane, and hence the structural geometry of the terrane and contained deposits were essentially that expressed today. The orientation of syn‐mineralisation far‐field stresses must also be inferred. Two examples of orogenic gold deposits, which meet the above criteria, are used to illustrate the potential of stress mapping in cross‐section. Sunrise Dam, located in the Archaean Yilgarn Craton, is a lode‐gold deposit sited in a thrust‐fold belt. Stress mapping illustrates the heterogeneity of stress distribution in the complex structural geometry of the deposit, and predicts the preferential siting of ore zones around the intersections of more steeply dipping, linking thrusts and banded iron‐formation units, and below the controlling more gently dipping basal thrust, the Sunrise Shear. The Howley Anticline in the Pine Creek block hosts several Palaeoproterozoic gold deposits, sited in complex anticlinal structures in greywacke sequences. Stress mapping indicates that gold ores should develop in the hinge zones of symmetrical anticlines, in the hinge zones and more steeply dipping to overturned limbs of asymmetric anticlines, and in and around thrusts in both anticlines and parasitic synclines. The strong correlation between the predictions of the stress mapping, based on the distribution of low σ₃, and the location of gold ores emphasises the potential of stress mapping in cross‐section, not only as an exploration tool for the discovery of additional resources or deposits, but also as a test of geological models. Knowledge of the potential siting of gold ores and their probable orientations also provides a guide to drilling strategies in both mine‐ and regional‐scale exploration.     

The Congo Basin forests in a changing climate: Policy discourses on adaptation and mitigation (REDD+)

This paper discusses the discourses on climate change adaptation and mitigation that are currently at the forefront in the Congo Basin. On mitigation, the forests have enormous opportunities to contribute to the reducing emissions from deforestation and forest degradation (REDD+) mechanism. But the forest itself and its multiple dependent societies and sectors need to adapt to potential climate risks. Hence, actors are debating the design of climate change policy in the forest sector. Theoretically, we combine the agency-focus of frame analysis and discourse theory to analyze how different agents hold frames on climate change adaptation and mitigation policies in the region. This paper draws upon interviews with 103 different actors from government, international organizations, non-governmental organizations, research institutions and private sector in three countries: Cameroon, Central African Republic (CAR) and Democratic Republic of Congo (DRC). Three discourses were found on policy response to climate change in the forest sector: mitigation policy only, separated policy on adaptation and mitigation, and an integrated policy on adaptation and mitigation. The various frames articulated around each discourse by the coalitions include elements of: costs and benefits, scale of operation, effectiveness, financial resources and implementation mechanisms. Overall, the mitigation discourse, through its mix of actors, resources and interests seems to be stronger than the adaptation discourse. The paper finally outlines a number of implications of the discourses for policy design.     

Sensitivity of crop yields and land resource potential to climatic change in Ontario,Canada

Increasing concentrations of atmospheric CO₂ and other greenhouse gases are expected to contribute to a global warming. This paper examines the potential implications of a climatic change corresponding to a doubling of atmospheric concentrations of CO₂ on crop production opportunities throughout Ontario, a major food producing region in Canada. The climate is projected to become warmer and drier, but the extent of these shifts are expected to vary from region to region within Ontario. The effect of this altered climate on crop yields and the area of land capable of supporting specific crops varies according to region, soil quality and crop type. Most notable are the enhanced opportunities for grains and oilseeds in the northern regions, and the diminished production prospects for most crops in the most southerly parts of Ontario.