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21.
Recent models of chemical weathering in alpine glacial meltwaters suggest that sulphide oxidation is a major source of solute in the distributed component of the subglacial hydrological system. This reaction requires O2, and may lower dissolved oxygen levels to below saturation with respect to the atmosphere. This should result in an inverse association between SO72- and dissolved oxygen saturation. However, measurements of O2 saturation in bulk meltwaters draining the Haut Glacier d'Arolla, Switzerland, show that there is a positive association between SO42- and O2 saturation. The O2 content of glacial meltwaters depends on the initial content of snow and icemelt, which may be controlled by the rate of melting, and the kinetic balance between O2 losses (e.g. sulphide oxidation, microbial respiration) and gains (e.g. diffusion of O2 into solution). 相似文献
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Oxygen self diffusion rates were determined in quartz samples exchanged with18O-enriched CO2 between 745 and 900°C and various pressures, and the diffusion profiles were measured using an ion microprobe. The activation energy (Q) and preexponential factor (D0) at P(CO2) = P(tot) = 100 bar, for diffusion parallel to the c-axis are 159 ( ± 13) kJ/g atom and 2.10 (+0.75/ −0.55) × 10−8 cm2/s. This rate is approximately 100 times slower than that obtained from hydrothermal experiments and 100 times faster than a previous 1-bar quartz-O2 exchange experiment. The oxygen diffusion rate measured at 0.6 bar, 888°C, and at 900°C in vacuum is in agreement with the previous 1-bar exchange experiments with18O2. The effect of higher CO2 pressures is small. At 900°C, the diffusion rate exchanged with CO2 is = 2.35 × 10−15 cm2/s at 100 bar, 2.24 × 10−15 cm2/s at 3.45 kbar and 8.13 × 10−15 cm2/s at 7.2 kbar.There is probably a diffusing species, other than oxygen, that enhances the oxygen diffusion rate in these quartz-CO2 systems, relative to that occurring at very low pressures or in a vacuum. The effect of this diffusing species, however, is not as strong as that associated with H2O. Preserved oxygen isotope fractionations between coexisting minerals in a slowly cooled, high-grade metamorphic terrane will vary depending upon whether a water-rich phase was present or not. Closure temperatures will be approximately 100°C higher in rocks where no water-rich phase was present during cooling. The measured fractionations between coexisting minerals in metamorphic rocks may potentially be used as a sensor of water presence during retrogression. 相似文献
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Alastair D. L. Sharp 《Surveys in Geophysics》1982,5(3):229-244
Macroseismic studies, linear refraction profiles, and a two-dimensional seismic array study on Mount Etna, have all detected anomalous low velocity zones beneath the volcano. Seismic travel time delays together with high frequency attenuation observations confirm the presence of a large volume of partial melt beneath the volcano. A simplified three-dimensional model of the main storage system of Mount Etna is presented.Paper presented at the Symposium Volcanoes of the Earth and Planets, held at the University of Lancaster, March 17, 1981. 相似文献
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James Glimm Shuling Hou Hongjoong Kim Yoon-ha Lee David H. Sharp Kenny Ye Qisu Zou 《Computational Geosciences》2001,5(3):173-197
We consider numerical solutions of the Darcy and Buckley–Leverett equations for flow in porous media. These solutions depend on a realization of a random field that describes the reservoir permeability. The main content of this paper is to formulate and analyze a probability model for the numerical coarse grid solution error. We explore the extent to which the coarse grid oil production rate is sufficient to predict future oil production rates. We find that very early oil production data is sufficient to reduce the prediction error in oil production by about 30%, relative to the prior probability prediction. 相似文献
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W. Edwin Sharp 《Mathematical Geology》2007,39(8):785-786
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