Al-Cu-Fe alloys in the solar system: Going inside a Khatyrka-like micrometeorite (KT01) from the Nubian Desert,Sudan

A recently described micrometeorite from the Nubian desert (Sudan) contains an exotic Al-Cu-Fe assemblage closely resembling that observed in the Khatyrka chondrite (Suttle et al., 2019; Science Reports 9:12426). We here extend previous investigations of the geochemical, mineralogical, and petrographic characteristics of the Sudan spherule by measuring oxygen isotope ratios in the silicate components and by nano-scale transmission electron microscopy study of a focused ion beam foil that samples the contact between Al-Cu alloys and silicates. O-isotope work indicates an affinity to either OC or CR chondrites, while ruling out a CO or CM precursor. When combined with petrographic evidence we conclude that a CR chondrite parentage is the most likely origin for this micrometeorite. SEM and TEM studies reveal that the Al-Cu alloys mainly consist of Al metal, stolperite (CuAl), and khatyrkite (CuAl₂) together with inclusions in stolperite of a new nanometric, still unknown Al-Cu phase with a likely nominal Cu₃Al₂ stoichiometry. At the interface between the alloy assemblage and the surrounding silicate, there is a thin layer (200 nm) of almost pure MgAl₂O₄ spinel along with well-defined and almost perfectly spherical metallic droplets, predominantly iron in composition. The study yields additional evidence that Al-Cu alloys, the likely precursors to quasicrystals in Khatyrka, occur naturally. Moreover, it implies the existence of multiple pathways leading to the association in reduced form of these two elements, one highly lithophile and the other strongly chalcophile.     

Inter-laboratory comparison of oxygen isotope compositions from biogenic silica

Several techniques have been introduced in the last decades for the dehydration and release of O₂ from biogenic silica (opal-A) for oxygen-isotope analysis. However, only one silica standard is universally available: a quartz standard (NBS28) distributed by the IAEA, Vienna. Hence, there is a need for biogenic silica working standards. This paper compares the existing methods of oxygen-isotope analyses of opal-A and aims to characterize additional possible working standards to calibrate the δ¹⁸O values of biogenic silica. For this purpose, an inter-laboratory comparison was organized. Six potential working standard materials were analysed repeatedly against NBS28 by eight participating laboratories using their specific analytical methods. The materials cover a wide range of δ¹⁸O values (+23 to +43‰) and include diatoms (marine, lacustrine), phytoliths and synthetically-produced hydrous silica. To characterize the proposed standards, chemical analyses and imaging by scanning electron microscopy (SEM) were also performed. Despite procedural differences at each laboratory, all methods are in reasonable agreement with a standard deviation (SD) for δ¹⁸O values between 0.3‰ and 0.9‰ (1σ). Based on the results, we propose four additional biogenic silica working standards (PS1772-8: 42.8‰; BFC: 29.0‰; MSG60: 37.0‰; G95-25-CL leaves: 36.6‰) for δ¹⁸O analyses, available on request through the relevant laboratories.     

Impact of post-mixing chemical reactions on the major ion chemistry of bulk meltwaters draining the haut glacier d'arolla,valais, Switzerland

Until now, alpine glacial meltwaters have been assumed to consist of two components, dilute quickflow and concentrated delayed flow, the mixing of which has been regarded as chemically conservative for the major dissolved ions and electrical conductivity. Dye tracing results suggest that this two-component model adequately represents the sub-glacial hydrology of the Haut Glacier d'Arolla, Switzerland. However, laboratory dissolution experiments in which various concentrations of glacial rock flour are placed in dilute solutions show that this rock flour is highly reactive and suggest that bulk meltwaters may acquire significant amounts of solute through rapid chemical reactions with suspended sediment which occur after mixing of the two components. This view is supported by detailed analysis of variations in the hydrochemistry of meltwaters draining from the Haut Glacier d'Arolla over three diurnal cycles during the 1989 melt season. Variations in the composition of bulk meltwaters are controlled by two main factors: dilution of the delayed flow component by quickflow, and the extent of post-mixing reactions. The latter depends on the suspended sediment concentration in bulk meltwaters and on the duration of contact between these waters and suspended sediment. Seasonal changes in the magnitude of these factors result in changes in the character and causes of diurnal variations in meltwater chemistry. In June, these variations reflect discharge-related variations in residence time within a distributed subglacial drainage system; in July, when a channelized drainage system exists beneath the lower glacier, they primarily reflect the dilution of delayed flow by quickflow; in August, when suspended sediment concentrations are particularly high, they reflect varying degrees of solute acquisition by post-mixing reactions with suspended sediment that take place in arterial channels at the glacier bed.     

Book review

Mathematical Geosciences -     

On the temperature dependence of the reaction O + NO → NO12

The published data on the temperature dependence of the radiative combination of atomic oxygen with nitric oxide at pressures near 1 torr is examined. Arguments are advanced to suggest that radiation near the cut-off wavelength (～ 3875Å) is coming from the unstabilized activated complex, No¹₂. At 4000Å a positive activation energy of 1 kcal mole^?1 is deduced. Application of this temperature dependence with the rate coefficient at 5200Å is made to airglow measurements in aurora. The deduced NO concentration is about 10⁹ cm^?3, in general agreement with that deduced from the measured NO⁺/O⁺₂ ratio as well as an auroral model prediction.     

PAPPA: Primordial anisotropy polarization pathfinder array

The primordial anisotropy polarization pathfinder array (PAPPA) is a balloon-based instrument to measure the polarization of the cosmic microwave background and search for the signal from gravity waves excited during an inflationary epoch in the early universe. PAPPA will survey a 20° × 20° patch at the North Celestial Pole using 32 pixels in 3 passbands centered at 89, 212, and 302 GHz. Each pixel uses MEMS switches in a superconducting microstrip transmission line to combine the phase modulation techniques used in radio astronomy with the sensitivity of transition-edge superconducting bolometers. Each switched circuit modulates the incident polarization on a single detector, allowing nearly instantaneous characterization of the Stokes I, Q, and U parameters. We describe the instrument design and status.