Problems in oxygen isotope geothermometry in mafic granulite facies rocks from near Einasleigh,northern Queensland

Oxygen isotope geothermometry of coexisting minerals from five mafic granulites does not reflect the peak temperature of metamorphism as determined by other methods. Exchange of ¹⁸O between phases during slow cooling has (a) lowered the δ ¹⁸O of clinopyroxene relative to orthopyroxene in the presence of hornblende, (b) raised the δ ¹⁸O of quartz in a manner which is partly dependent on quartz abundance, and (c) lowered the δ ¹⁸O of plagioclase in some rocks.     

Diffusive Oxygen Emitters for Enhancement of Aerobic In Situ Treatment

Aerobic biodegradation can be enhanced within contaminant plumes by elevating typically low dissolved oxygen (D.O.) levels using materials or devices that passively release oxygen. We have developed passive devices that provide a uniform, steady, long-term source of oxygen by diffusion from pressurized polymeric tubing and report test results under lab and field conditions. Lab flow-through reactor tests were conducted to determine the diffusion coefficient (D) of oxygen through four readily available tubing materials. Oxygen diffusion was greatest through Tygon® 3350 platinum-cured silicone (D = 6.67 ± 10^-7 cm²/sec), followed by 2075 Ultra Chemical Resistant Tygon (1.59 ± 10^-7 cm²/sec), 2275 High Purity Tygon (5.11 ± 10^-8 cm²/sec), and low-density polyethylene (LDPE; 1.73 ± 10^-8 cm²/sec). Variable-pressure release tests with LDPE resulted in very close estimates of D, which confirmed that mass transfer is controlled by diffusion and that the concentration gradient is a valid approximation of the chemical potential driving diffusion. LDPE emitter devices were designed and installed in seven 8-inch-diameter well screens across a portion of a gasoline plume at a former service station. With the devices pressurized to 620.5 kPag (kilopascals gauge) late in the test, steady-state D.O. concentrations reached as high as 25 mg/L, comparing favorably to the value predicted using the mass-transfer coefficient estimated from the lab test (26.3 mg/L). The method can also be used to release other gases for other reasons: gaseous tracers (i.e., sulphur hexafluoride, helium, and argon), hydrogen (for reductive dechlorination), or light alkanes (for cometabolic biodegradation of methyl tertiary butyl ether [MTBE] or chlorinated solvents).     

Adding Human Health Risk Analysis Tools to Geographic Information Systems

The development of a module for performing human health risk analysis is presented. This risk module differs from other tools in that it is integrated into a geographic information system (GIS) in a plug–in fashion. The main challenge in the development of the risk module was handling the many different spatial data structures in an open GIS environment. Selection of programming language and other development issues are discussed. The application of the risk module to two mining activities in Bolivia is described.     

Volcanic Hazard in New Zealand: Scaling and Attenuation Relations for Tephra fall deposits from Taupo Volcano

This paper is a first step in developing a probabilistic hazard model for tephra fall deposits in New Zealand. The database consists of measurements of tephra thickness and eruptive volumefrom 32 past eruptive events at Taupo Volcano. From these are derivedrelations for the mean and maximum tephra thickness as a function ofevent volume and distance from the vent, and for the area enclosed byan isopach as a function of tephra thickness and volume. Thedirectional effects due to wind do not vary appreciably over thevolcanic region of New Zealand. The main feature of wind velocity is aflow to the east that becomes more consistent at higher altitudes. Thelarger the eruption, the more the location of the deposit of maximumthickness (the centre of deposit) tends to be displaced to the east ofvent. A directional attenuation relation about the centre of deposit isderived from the Taupo data. This, in combination with arelation for the position of the centre of deposit relative to thevent, provides a means of estimating the probability of a giventhickness of tephra fall deposit being exceeded at any distance anddirection from the vent in an eruption of given volume.