A depositional model for hydromagnesite–magnesite playas near Atlin,British Columbia,Canada

This study formulates a comprehensive depositional model for hydromagnesite–magnesite playas. Mineralogical, isotopic and hydrogeochemical data are coupled with electron microscopy and field observations of the hydromagnesite–magnesite playas near Atlin, British Columbia, Canada. Four surface environments are recognized: wetlands, grasslands, localized mounds (metre‐scale) and amalgamated mounds composed primarily of hydromagnesite [Mg₅(CO₃)₄(OH)₂·4H₂O], which are interpreted to represent stages in playa genesis. Water chemistry, precipitation kinetics and depositional environment are primary controls on sediment mineralogy. At depth (average ≈ 2 m), Ca–Mg‐carbonate sediments overlay early Holocene glaciolacustrine sediments indicating deposition within a lake post‐deglaciation. This mineralogical change corresponds to a shift from siliciclastic to chemical carbonate deposition as the supply of fresh surface water (for example, glacier meltwater) ceased and was replaced by alkaline groundwater. Weathering of ultramafic bedrock in the region produces Mg–HCO₃ groundwater that concentrates by evaporation upon discharging into closed basins, occupied by the playas. An uppermost unit of Mg‐carbonate sediments (hydromagnesite mounds) overlies the Ca–Mg‐carbonate sediments. This second mineralogical shift corresponds to a change in the depositional environment from subaqueous to subaerial, occurring once sediments ‘emerged’ from the water surface. Capillary action and evaporation draw Mg–HCO₃ water up towards the ground surface, precipitating Mg‐carbonate minerals. Evaporation at the water table causes precipitation of lansfordite [MgCO₃·5H₂O] which partially cements pre‐existing sediments forming a hardpan. As carbonate deposition continues, the weight of the overlying sediments causes compaction and minor lateral movement of the mounds leading to amalgamation of localized mounds. Radiocarbon dating of buried vegetation at the Ca–Mg‐carbonate boundary indicates that there has been ca 8000 years of continuous Mg‐carbonate deposition at a rate of 0·4 mm yr^?1. The depositional model accounts for the many sedimentological, mineralogical and geochemical processes that occur in the four surface environments; elucidating past and present carbonate deposition.     

Trapped intercumulus liquid in the Main Zone of the eastern Bushveld Complex, South Africa

Lateral variations in the amount of trapped intercumulus liquid in the Main Zone of the eastern Bushveld Complex are constrained by new Sr-isotopic, whole-rock and mineralogical data from three profiles that are separated laterally by ca.100 km and represent thicknesses of 551–1,127 m of Main Zone gabbronorites below the Pyroxenite Marker. An analysis of the An-contents (100×Ca/(Ca+Na)) of plagioclase cores within the Thornhill (north), Roossenekal and Stoffberg (south) profiles show similar systematic, up-section variations from An₆₆ to An₅₉. In contrast, both the An-contents of bulk plagioclase separates and the Mg-numbers (100×Mg/(Mg+Fe_T)) of orthopyroxenes show pronounced lateral variations from Thornhill (An_67-61; Mg#_67-61), through Roossenekal (An_64-58; Mg#_64-55) to Stoffberg (An_59-55; Mg#_59-50). These mineralogical variations are interpreted to be the result of reaction between cumulus minerals and an increasing amount of trapped liquid from north to south. Modelling of the trapped liquid shift of orthopyroxene compositions suggests that the amount of trapped liquid in the cumulates increased from near 0% at Thornhill, through 10–30% at Roossenekal to 30–45% at Stoffberg. A two- to eightfold southward increase in whole-rock concentrations of P, Ti, Y, Zr and Ba is consistent with the trapped liquid model. However, the 14-fold increase in Rb from Thornhill to Stoffberg is too great to be accounted for by trapped liquid alone, but can be explained by local assimilation of partial melts of the country rock. Constant initial ⁸⁷Sr/⁸⁶Sr isotopic ratios of Main Zone plagioclase separates (0.7081–0.7085) in all the three profiles do not preclude assimilation of adjacent basaltic to rhyolitic country rock with initial ratios between 0.6924–0.7096. The southward increase in the amount of trapped liquid is ascribed to an increased cooling rate by enhanced heat loss and partial assimilation of country rock xenoliths in the distal cumulate sequence at Stoffberg. Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorised users.     

Editorial 2003

2002 was a highly successful year. The most recent (2001) ISIImpact Factors for journal citations confirm that Journal ofPetrology remains the premier journal in the field of petrology(Journal of Petrology—3.283; Earth & Planetary ScienceLetters—2.700; Geochimica Cosmochimica Acta—2.614;Contributions to Mineralogy & Petrology     

Temperature effects on the calcite skeletal composition of deep-water gorgonians (Isididae)

We test for and calibrate a proxy for ocean temperature based on the skeletal composition of the widely distributed, deep-sea gorgonians in the family Isididae (bamboo corals), through use of three complementary methods: a short-term comparison of element/Ca ratios to a four-year temperature record, a long-term comparison with oceanographic records spanning forty years, and a geographic comparison of Isidids collected at sites ranging from the tropics to Antarctica. The assays consistently support a temperature-dependency for Mg/Ca ratios and suggest S/Ca is indirectly affected by temperature, but indicate little or no effect of temperature on P/Ca and Sr/Ca. The consensus relationship between Mg/Ca and temperature for Isidid calcite from the comparisons with the temperature time-series is T = −0.505 + 0.048 Mg/Ca, where T is in °C, Mg/Ca is in mmol/mol, and the applicable range is 3-6 °C. The results of the geographic assay, though imprecise, suggest the applicable range extends to temperatures below freezing. The scatter of data points around the regression of temperature and Mg/Ca is wide in all assays. This could reflect the effect of factors other than temperature on Mg/Ca ratios, but is also likely to reflect limitations of the field data, the effects of assumed constant growth rates in the corals and instrumental analytical error. The combined effects of micro-scale variability in growth rates and wide confidence intervals for each data point suggests that environmental reconstruction from Isidid internode calcite from sparse data or at time scales less than decades be done with caution. Comparisons within and among colonies do not indicate strong vital effects on ontogenetic variability in the corals, other than possibly close to the central pore of the coral. However, similar Mg/Ca ratios for Isidids from Antarctic and more temperate regions suggest adaptation to local conditions and hence a role for physiology at higher taxonomic levels, at least. Taxonomically higher level vital effects are also suggested by large differences between gorgonian families in their regressions between Mg/Ca and temperature, by Mg/Ca ratios that overlap over a wide temperature and habitat range, and for a non-linear relationship between temperature and the slope of the Mg/Ca-temperature relationship across the order.     

Petrogenesis of syenites at a rifted continental margin: origin,contamination and interaction of alkaline mafic and felsic magmas in the Astrophyllite Bay Complex,East Greenland

The Astrophyllite Bay Complex in East Greenland (part of the Palaeogene North Atlantic Igneous Province) consists of an alkaline diorite plug, with detached trachyandesitic pillows, surrounded by co-magmatic syenite that was emplaced into Archaean basement. The diorite intrusion has yielded a 47.11 ± 0.68 Ma Rb-Sr isochron age. Saw-cut profiles through pillow-syenite-gneiss sections have been taken to resolve close spatial elemental and isotopic (Sr-Nd-Hf-Pb-O) variations. The diorite and syenite formed from alkaline basaltic, mantle-derived, melts with complex histories of prolonged assimilation and fractional crystallisation. Each evolved to different extents in separate magma chambers during the establishment of new plumbing systems in the Kangerlussuaq area. The diorite is dominated by lower crustal, granulite facies contamination, whereas the syenite shows evidence for greater degrees of upper crustal amphibolite facies contamination, indicating stalling and fractionation of magmas at different levels within the crust. The syenite and diorite magmas were subsequently emplaced as separate pulses into the basement gneisses at Astrophyllite Bay giving rise to superimposed local contamination trends between pillow/syenite and syenite/gneiss, respectively.     

Small-scale spatial variations of natural radionuclide and trace metal distributions in sediments from the Hudson River estuary

Multiple sediment cores were collected in June 1994 in the turbidity maximum zone of the Hudson River estuary off Manhattan, New York. Results from X-radiography of the sediments and measurements of natural radionuclides (²³⁴Th,⁷Be, and²¹⁰Pb) and trace metals (Ag, Cd, Cu, Pb, and Zn) show significant spatial variability of sediment composition and structure and patchy distributions of radionuclides activities and trace metal concentrations in this small area (0.6 km × 0.5 km). Radionuclide and trace metal analyses confirm prior work (Olsen et al. 1978; Olsen et al. 1981; Hirschberg et al. 1996) that show the western margin area of the river acts as a repository of these chemical constituents at least for the short-term period (0.5–1 yr), and the mid-channel area is not a depositional area for sediments and associated chemical constituents.⁷Be profiles reveal short-term sediment deposition rates ranging from 6 cm yr^?1 to 26 cm yr^?1 in the western margin area. Significant spatial variations in excess²³⁴Th and⁷Be inventories (up to a factor of 10 and 5 for²³⁴Th and⁷Be, respectively) are found in the western margin depositional area, although the inventories are balanced, on average, with in situ production in water column and atmospheric supply. The spatial variation of surficial excess²¹⁰Pb and trace metal concentrations in depositional areas of the western margin are ≤10% for Ag, Cu, Pb, and Zn and 29% for Cd. However, the variations in the transition zone range from 28% to 93%. This variability is likely related to variations in tidal current velocity, bottom shear stress, and river channel morphology.     

Thermochronology of the Yidun Arc, central eastern Tibetan Plateau: constraints from Ar/Ar K-feldspar and apatite fission track data

Four K-feldspar samples from the Yidun Arc, eastern Tibetan Plateau, were analysed by the ⁴⁰Ar/³⁹Ar method with the aim of recovering information on their thermal history using multiple diffusion domain (MDD) theory. Arrhenius plots for each of the samples reveal low retentivity early in the heating experiments, a property that is attributed to their recrystallised nature. This low argon retentivity appears to violate the MDD assumption that volume diffusion is the only mechanism for argon transport within the crystals, thus the thermal histories derived from these analyses are considered suspect. Nevertheless, the age spectra themselves suggest that the majority of samples had cooled below 200 °C prior to the Eocene collision of India with Asia. Thermal history modelling from apatite fission track analyses from the same and nearby samples shows slow cooling through the apatite fission track partial annealing zone during the Cenozoic in samples from the high elevation, low relief areas of the Yidun Arc, while samples from the major Jinsha River valley show rapid cooling through the partial annealing zone beginning in the Miocene. These results suggest that significant Cenozoic denudation has been localised and that most parts of the Yidun Arc have experienced very little denudation during the Cenozoic.     

Clast sizes of ejecta from explosive eruptions on asteroids: implications for the fate of the basaltic products of differentiation

We use a simple model of the formation, growth, coalescence and migration of veins of basaltic melt generated by partial melting in chondritic asteroids to deduce the sizes of, and pressures within, the fluid-filled dikes reaching the surfaces of such bodies. The gas contents ( 1000 ppm of mainly CO and N₂) of the asteroids were high enough that bubbles of free gas trapped in the melt veins gave the basaltic melts significant buoyancy; expansion of these gases as a dike opened to the vacuum at the surface led to fragmentation of the melts into liquid droplets which were transported upwards by the accelerating gases to the surface. The sizes of these droplets and, hence, of the pyroclastic glass beads into which they cooled, are calculated to lie in the range 30 μm to 4 mm; this range is essentially independent of the size or gas content of the asteroid parent and only weakly dependent on the internal pressure of the erupting fluid. The fate of the pyroclasts, however, does depend on all of these factors. At very low internal pressures, significant separation of the gas and liquid in a rising dike may take place and not all of the liquid will be expelled from the dike when it opens to the surface. For relatively large ( 100 km radius) asteroids with relatively low ( 300 ppm) gas contents, the larger clasts are too heavy to be lifted from the level at which magma fragmentation takes place by the gas flow and so would also remain behind to form basaltic veins. The apparent absence of basaltic veins in meteorites then implies both that internal pressures in near-surface dikes were generally greater than 0.3 MPa and that low gas contents were not common. Finally, as long as pyroclasts are lofted from the magma fragmentation level, they will be accelerated to at least 90% of the final gas speed. If this speed exceeds the escape speed from the asteroid (as happens readily for high gas contents and small asteroids), the pyroclasts will be expelled into space and lost from the meteorite record. Otherwise (low gas contents or large asteroids), they will eventually fall back to be incorporated into the surface regolith, modifying the chemical and physical properties of meteorites subsequently derived from it.