Biologically induced mineralization of dypingite by cyanobacteria from an alkaline wetland near Atlin,British Columbia,Canada

Background  

This study provides experimental evidence for biologically induced precipitation of magnesium carbonates, specifically dypingite (Mg₅(CO₃)₄(OH)₂·5H₂O), by cyanobacteria from an alkaline wetland near Atlin, British Columbia. This wetland is part of a larger hydromagnesite (Mg₅(CO₃)₄(OH)₂·4H₂O) playa. Abiotic and biotic processes for magnesium carbonate precipitation in this environment are compared.     

Attenuation effect on seasonal basin-scale water storage changes from GRACE time-variable gravity

In order to effectively recover surface mass or geoid height changes from the gravity recovery and climate experiment (GRACE) time-variable gravity models, spatial smoothing is required to minimize errors from noise. Spatial smoothing, such as Gaussian smoothing, not only reduces the noise but also attenuates the real signals. Here we investigate possible amplitude attenuations and phase changes of seasonal water storage variations in four drainage basins (Amazon, Mississippi, Ganges and Zambezi) using an advanced global land data assimilation system. It appears that Gaussian smoothing significantly affects GRACE-estimated basin-scale seasonal water storage changes, e.g., in the case of 800 km smoothing, annual amplitudes are reduced by about 25–40%, while annual phases are shifted by up to 10°. With these effects restored, GRACE-estimated water storage changes are consistently larger than model estimates, indicating that the land surface model appears to underestimate terrestrial water storage change. Our analysis based on simulation suggests that normalized attenuation effects (from Gaussian smoothing) on seasonal water storage change are relatively insensitive to the magnitude of the true signal. This study provides a numerical approach that can be used to restore seasonal water storage change in the basins from spatially smoothed GRACE data.     

Oxygen isotope evidence for short-lived high-temperature fluid flow in the lower oceanic crust at fast-spreading ridges

Millimeter-scale amphibole veins in the lower oceanic crust record fracture-controlled fluid flow at high-temperatures but the importance of this fluid flow for the thermal and chemical evolution of the lower oceanic crust is unclear. In the section of lower oceanic crust recovered at Hess Deep from ODP Hole 894G, which formed at the fast-spreading East Pacific Rise, these veins are randomly distributed with an average spacing of  1 m. We unravel the history of fluid flow through one of these veins by combining in situ O-isotope analyses of wall-rock plagioclase with major element analyses, geothermometry and diffusion modeling. Thermometry indicates vein sealing by amphibole at  720 °C over a narrow temperature interval (± 20 °C). In situ O-isotope analyses by ion microprobe, with a precision of < 0.5‰, reveal zoning of O-isotopes in plagioclase adjacent to the vein. The zoning profiles can be reproduced using a diffusion model if the duration of O-isotope exchange was ≤ 100 yr. A similar interval of fluid–rock exchange is suggested by modeling potassium depletion in plagioclase adjacent to the vein. If representative of fracture controlled fluid flow in the lower oceanic crust the limited duration of fluid flow, and its occurrence over a narrow temperature interval, suggest that high-temperature fluid flow in this porosity network does not transport significant heat.     

Inner-shell photoionization of O iii

A 25-state R -matrix calculation is performed to obtain photoionization cross-sections for transitions from the 1s²2s²2p²³P ground state of the O  iii ion. Results are obtained for a range of photon energies, including those at which K-shell photoionization processes take place. We compare our results with those from previous calculations. Excellent agreement is obtained. We also consider resonances owing to transitions of a 1s electron excited into the 2p orbital and compare with a recent calculation.     

The structure of a sunspot

Typical intensity profiles across a sunspot at several heliocentric angles are selected from recent observations of the Wilson Effect. In addition, the profile of the mean intensity at the surface of the spot is inferred from these observed profiles.With these data, the transfer equation is solved for the two-dimensional source function distribution within the sunspot for several models of the opacity distribution. For an opacity model in which unit optical depth in the umbra occurs at least 700 km below unit optical depth in the mean photosphere, it is possible to reproduce qualitatively all the features of the observed profiles.Although no assumption is made about the extent of the umbra below the surface, these solutions clearly show that, at a depth of 700 km below unit optical depth in the photosphere, the diameter of the umbral region, which is 10800 km at the surface, has increased to about 12000 km. Thus the shape of the umbral region below the surface is part of an inverted cone of semi-vertical angle approximately 45°. The run of gas pressure and density in the umbra is computed for the model and compared with the corresponding photospheric values.Of the National Bureau of Standards and University of Colorado.