Compartmentalisation and groundwater–surface water interactions in a prospective shale gas basin: Assessment using variance analysis and multivariate statistics on water quality data

An environmental concern with hydraulic fracturing for shale gas is the risk of groundwater and surface water contamination. Assessing this risk partly involves the identification and understanding of groundwater–surface water interactions because potentially contaminating fluids could move from one water body to the other along hydraulic pathways. In this study, we use water quality data from a prospective shale gas basin to determine: if surface water sampling could identify groundwater compartmentalisation by low-permeability faults; and if surface waters interact with groundwater in underlying bedrock formations, thereby indicating hydraulic pathways. Variance analysis showed that bedrock geology was a significant factor influencing surface water quality, indicating regional-scale groundwater–surface water interactions despite the presence of an overlying region-wide layer of superficial deposits averaging 30–40 m thickness. We propose that surface waters interact with a weathered bedrock layer through the complex distribution of glaciofluvial sands and gravels. Principal component analysis showed that surface water compositions were constrained within groundwater end-member compositions. Surface water quality data showed no relationship with groundwater compartmentalisation known to be caused by a major basin fault. Therefore, there was no chemical evidence to suggest that deeper groundwater in this particular area of the prospective basin was reaching the surface in response to compartmentalisation. Consequently, in this case compartmentalisation does not appear to increase the risk of fracking-related contaminants reaching surface waters, although this may differ under different hydrogeological scenarios.     

Using qPCR Assays to Predict Rates of Cometabolism of TCE in Aerobic Groundwater

Monitored natural attenuation (MNA) is commonly used as a remedy for trichloroethene (TCE) in anaerobic groundwater; however, MNA has not been applied to TCE contamination in aerobic groundwater. Under aerobic conditions, bacteria initiate the degradation of many organic substances with oxygenase enzymes. Several of these enzymes are known to degrade TCE through a fortuitous reaction known as cometabolism. There are commercially available qPCR assays that can determine the number of gene copies of these enzymes. If the qPCR assay could be used to predict the first-order rate constant for cometabolism of TCE, the qPCR assay could be used to screen sites to determine whether MNA was a plausible remedy for TCE contamination. This study reevaluated data from water samples that were collected from 19 wells on five sites in Minnesota, New York, and Utah. Data had previously been published on the rate constant for cometabolism of TCE in the water samples as determined by a ¹⁴C-assay and the abundance of gene copies for five enzymes that cometabolize TCE as determined using a qPCR assay. The Michaelis-Menten (Haldane) kinetic parameters for cometabolism of TCE and the abundance of DNA for the five oxygenase enzymes were used to predict the rate constant for cometabolism of TCE. The predicted rate constants were evaluated and validated by comparing them to the rate constants derived from the ¹⁴C-assay. For predicted rate constants greater than 0.003 per year, the predicted rate constants agreed with the measured rate constants within a factor of three. The qPCR assay serves as a convenient screening tool to determine whether MNA is a plausible remedy for an aerobic plume of TCE.     

The ductility reduction factor in the seismic design of buildings

This paper presents new trends in the relationship between the ductility reduction factor and the ductility demand in the seismic design of buildings. A total of 4860 inelastic time-history analyses were carried out to study this relationship using 60 single-degree-of-freedom models excited by an ensemble of 81 earthquake accelerogram records from around the world. The asymmetrical distribution of the results highlighted the inaccuracies associated with assuming a normal distribution simply described by the mean and standard deviation to represent the data. A probability of exceedence approach has been used based on counting the number of occurrences the ductility demand exceeds a specified level. The ductility reduction factors developed in this study are consistent with other studies in the long-period range but are different in the short-period range. The ductility reduction factor for very short period buildings of limited ductility has been found to be greater than previously predicted. © 1998 John Wiley & Sons, Ltd.     

Prevalence of Bacillus sp. among the biofilm forming community on Ti surface in marine environment

Prevalence of bacterial species involved in biomineralization of manganese on titanium (Ti) surfaces in marine environment was revealed in this research work. This study involves one year sea water exposure of Ti and their periodical biofilm characterization was carried out to quantify the manganese oxidizing bacterial (MOB) presence in the biofilm formed on titanium surfaces. The total viable count study of Ti coupons exposed to sea water for one year resulted in 60% of the MOB in overall biofilm population. The biochemical characterization of MOB isolates were performed for the genus level identification of the seven bacterial isolates. Further, the seven strains were subjected to 16S rRNA gene sequencing. Evolutionary analysis was performed using MEGA 7 to obtain closely related strains within the groups. The manganese oxidizing ability of the bacterial isolates were determined with Leucoberbelin Blue Assay (LBB) and Atomic Absorption Spectroscopy studies (AAS). The results show that among the isolated marine MOB species, Bacillus sp. and Leptothrix sp. have the maximum Mn oxidizing property. The microtitre plate assay was performed to determine the biofilm forming ability of the isolated marine MOB species. All the results have confirmed the prevalence of Bacillus sp. among the biofilm colonizers on Ti surfaces when exposed in sea water.     

The fate of antimony in a major lowland river system,the Waikato River,New Zealand

Antimony is an element that is becoming of increasing concern as an environmental contaminant. Geothermal systems are a source of Sb into some fresh waters of New Zealand’s North Island. The purpose of this research was to determine the factors controlling the behaviour of geothermally-derived Sb in the large lowland Waikato River system. The Waikato River is New Zealand’s longest and most utilised river. Antimony in the system exhibited mainly conservative behaviour, and seasonally variable dilution was found to be the most important control on Sb concentrations. The most significant potential removal process was identified as adsorption of Sb onto suspended particulate material (SPM). The adsorption of Sb onto the SPM is enhanced at low (<5) pH conditions, and in the anoxic base of stratified lakes. There was evidence that the adsorption of Sb is mainly onto Fe oxides in SPM, and changes with changing Fe concentrations. Therefore, Sb adsorption was higher in winter (when Fe concentrations in SPM were higher) than in summer. In Lake Ohakuri, which was stratified during the late summer/early autumn of 2007, there was also potential for removal of Sb as Sb₂S₃ in the presence of sulfide formed in the anoxic layer. The behaviour of Sb was conservative through the estuary at the mouth of the river.     

Erosive flood events on the surface of Mars: Application to Mangala and Athabasca Valles

We address key factors involved in determining water flow conditions in outflow channels on Mars, including the temperature of the sub-surface water being released and the environmental conditions of low temperature, low atmospheric pressure, and low acceleration due to gravity. We suggest how some of the assumptions made in previous work may be improved. Our model considers the thermodynamic effects of simultaneous evaporation and freezing of water, and fluid dynamical processes including changes in flow rheology caused by assimilation of cold rock and ice eroded at the channel bed, and ice crystal growth due to water freezing. We model how far initially turbulent water could flow in a channel before it erodes and entrains enough material to become laminar, and subsequently ceases to erode the bed. An ice raft will begin to form on the flood while transition occurs between turbulent and laminar flow. Estimates are given for water transit times, ～17–19 h, initial water depths, 50–62 m, and average flow speeds, 5–12 m s^?1, in the Mangala and Athabasca Valles. We show that these two outflow channels, and by implication others like them, could plausibly have been formed in single water release events. Resulting mean erosion rates are approximately 0.7 mm s^?1, a factor of three greater than previous estimates based on combinations of estimates of flood duration and required water volumes. This is explained by the consideration of the effects of eroded ice and the physics of thermal erosion in the present study.     

Coral reef recovery status in south Andaman Islands after the bleaching event 2010

The Andaman and Nicobar Islands are one of the Union Territories of India, located in the eastern part of the Bay of Bengal. In 2010 summer, the increment in sea surface water temperature (up to 34℃) resulted in the bleaching of about 74% to 77% of corals in the South Andaman. During this event, coral species such as Acropora cerealis, A. humilis, Montipora sp., Favia pallida, Diploastrea sp., Goniopora sp. Fungia concinna, Gardineroseries sp., Porites sp., Favites abdita and Lobophyllia robusta were severely affected. This study is to assess the recovery status of the reef ecosystem by estimating the percentage of Live Coral cover, Bleached coral cover, Dead coral with algae, Rubble, Sandy flat, Algal assemblage and other associated organisms. The sedimentation rate (mg cm-2 d-1) and coral coverage (%) were assessed during this study period. The average sedimentation rate was ranged between 0.27 and 0.89 mg cm-2 d-1 . The observed post bleaching recovery of coral cover was 21.1% at Port Blair Bay and 13.29% at Havelock Island. The mortality rate of coral cover due to this bleaching was estimated as 2.05% at Port Blair Bay and 9.82% at Havelock Island. Once the sea water temperature resumed back to the normal condition, most of the corals were found recovered.     

Field test of the superconducting gravimeter as a hydrologic sensor

We report on a field test of a transportable version of a superconducting gravimeter (SG) intended for groundwater storage monitoring. The test was conducted over a 6-month period at a site adjacent to a well in the recharge zone of the karstic Edwards Aquifer, a major groundwater resource in central Texas. The purpose of the study was to assess requirements for unattended operation of the SG in a field setting and to obtain a gravimetric estimate of aquifer specific yield. The experiment confirmed successful operation of the SG, but water level changes were small (<0.3 m) leading to uncertainty in the estimate of specific yield. Barometric pressure changes were the dominant cause of both water level variations and non-tidal gravity changes. The specific yield estimate (0.26) is larger than most published values and dependent mainly on low frequency variations in residual gravity and water level time series.     

A Paddock to reef monitoring and modelling framework for the Great Barrier Reef: Paddock and catchment component

Targets for improvements in water quality entering the Great Barrier Reef (GBR) have been set through the Reef Water Quality Protection Plan (Reef Plan). To measure and report on progress towards the targets set a program has been established that combines monitoring and modelling at paddock through to catchment and reef scales; the Paddock to Reef Integrated Monitoring, Modelling and Reporting Program (Paddock to Reef Program). This program aims to provide evidence of links between land management activities, water quality and reef health. Five lines of evidence are used: the effectiveness of management practices to improve water quality; the prevalence of management practice adoption and change in catchment indicators; long-term monitoring of catchment water quality; paddock & catchment modelling to provide a relative assessment of progress towards meeting targets; and finally marine monitoring of GBR water quality and reef ecosystem health. This paper outlines the first four lines of evidence.     

Surface lowering of limestone pavement as determined by cosmogenic (36Cl) analysis

Determination of the rate and total amount of limestone pavement surface lowering is a critical issue in developing models of regional landscape change in limestone terrain. Erratic‐capped pedestals have frequently been used for this purpose but problems concerning definition and measurement of pedestal height, and the absence of a secure timeframe for erratic emplacement, have resulted in conflicting interpretations. We have used cosmogenic (³⁶Cl) to establish the emplacement age of erratic boulders and the total amount of pavement surface lowering at sites in northwest England. Since erratic emplacement at 17.9 ka the limestone pavement has been lowered by 22–45 cm (average: 33 ± 10 cm), assuming lowering was continuous. Although indicating some spatial heterogeneity, the results contrast with earlier reported values based on the measurement of pedestal heights and inferred age for deglaciation. We consider that changes in climate and the character and duration of regolith covers to have been important influences in promoting surface lowering. It is argued that nivation (chemical and mechanical snow‐related processes) associated with several cool/cold periods is likely to have played an important role in surface lowering. Complicating factors associated with surface lowering (thickness and longevity of snow and regolith covers) are identified but as yet cannot be quantified. Copyright © 2012 John Wiley & Sons, Ltd.