Sodian stellerite from Capo Pula,Sardegna

The sodian stellerite (a zeolite) occurs as lustrous white or slightly pink, easily cleavable lamellae, filling cavities and fractures in an acid lava (andesite or rhyolite) in the cliff below S. Efisio Tower, near Capo Pula, Cagliari, Sardegna, Italy. The principal forms present are {010}, {011}, {111}. Single crystal photographs show an orthorhombic symmetry and Ammm (or Ammm) space group. An indexed X-ray diffraction powder pattern is provided. Unit cell dimensions, chemical formula, density, optical properties and thermal behaviour are given.     

Groundwater Resources In Hard Rock; Experiences from The Hvaler Study,Southeastern Norway

Investigations in a newly constructed subsea road tunnel in the Iddefjord granite at Hvaler and test-pumping of boreholes on land indicate that a topographic or geophysical anomaly is no guarantee of a substantially transmissive fracture zone. Many prominent fracture zones appear to have depressed transmissivity due to secondary swelling-clay mineral infillings. No current geophysical technique can adequately distinguish these zones from transmissive ones. Given that siting of boreholes on the basis of geology alone can be unreliable, hydrogeologists should concentrate on quantifying the chances of a successful boring, and optimizing those chances by sensible location, favourable borehole orientation and use of artificial enhancement techniques.     

Improved Petrological Modal Analyses from X-ray Powder Diffraction Data by use of the Rietveld Method I. Selected Igneous, Volcanic, and Metamorphic Rocks

Mineral modes have been determined for specimens of eight rocktypes from CuK X-ray powder diffraction data using the Rietveldmethod. The samples include two granites, a granodiorite, adamellite,gabbro, basalt, trachyte, and two granulite-facies metamorphicrocks. Up to eight individual mineral components have been measuredin each sample (no glassy phases were observed), with a detectionlimit of {small tilde}1 wt.%, depending on the mineral assemblage.Marked variations in grain size (i.e., granite vs. trachyte)provide no difficulties for the X-ray method. The X-ray resultscompare very favourably with (1) optical modes determined forthe medium–coarse-grained samples by point counting, (2)normative calculations obtained using locally enhanced catanormand mesonorm software, and (3) corresponding Rietveld modesdetermined, for two samples, from neutron powder data. Wheredifferences occur, these are discussed in relation to the limitationsof each of the methods. The improved accuracy of the X-ray method is due primarily tothe incorporation of the full diffraction profile in the Rietveldanalysis calculations, and the elimination of preferred orientationby collecting the data from samples packed in glass capillaries(i.e., Debye–Scherrer mode). The good agreement of theX-ray and neutron modes shows that the usual problems encounteredwith microabsorption, extinction, and sampling are of littleconcern in these rocks. The results highlight one of the majoradvantages provided by Rietveld modal analysis over the moretraditional ‘reference intensity’ X-ray methods,namely, that the crystal chemistry (and thus the calibrationconstants) of the individual phases can be adjusted dynamicallyduring each individual analysis. This not only provides moreaccurate phase abundances, but also gives important supplementaryinformation about the mineralogy of the major components.     

A Model of Magmatic Crystallization

A computer model simulating fractional crystallization at oneatmosphere pressure incorporates nine broadly-defined minerals—magnetite,olivine, hypersthene, augite, quartz, plagioclase, orthoclase,leucite, and nepheline. The crystallization temperature of eachmineral is considered to be a smooth function of the compositionof the magmatic liquid. These mineral temperature equationsare obtained by multiple linear regression analysis of informationfrom published silicate systems and rock melting experiments.The nine equations are solved for any primary liquid, withinthe broad range of common magma types, to select the crystallizingmineral or minerals. Partition ratios from published experimentsand analyses of lavas and phenocrysts permit calculation ofthe composition of the crystallizing mineral assemblage. Subtractionof a small amount of that composition from the primary liquidyields a new liquid, which may be recycled to yield a sequenceof liquids during fractional crystallization. The crystallizationmodel handles assemblages of co-precipitating minerals, andcan trace progressive saturation in new minerals, substitutionof a new mineral for an old mineral, and cessation of crystallizationof a mineral. The sequences of minerals and liquids derivedfrom a broad set of primary liquids are geologically realistic,so the model is useful in predicting phenocrysts in volcanicrocks and events during crystallization of shallow intrusions.     

A case study of warm air advection over a melting snow surface

When relatively warm, moist air moves over a snow surface, sensible heat and moisture are extracted from its lower layers and used to melt the snow. The depth of the cooled layer depends on horizontal wind speeds and the presence of high vertical wind shear. The mechanism for air mass modification appears to be turbulent mixing.     

Desert vegetation and timing of solar radiation

Timing and amount of solar radiation were examined as factors influencing the distribution of seven perennial plants on a small mountain located in the Chihuahuan Desert. Average direct beam solar radiation fluxes at differing times throughout the day and year were estimated with computer calculations. Principal components analysis was used to reduce the number of solar radiation parameters and include the maximum available information with a manageable number of variables. The remaining solar radiation parameters were compared to plant distributions using redundancy analysis and generalized additive models. Unimodal, bimodal, and monotonic responses were all found depending upon the species and solar radiation parameter. Niche separation at this location depends upon the timing as well as the amount of solar radiation.     

Investigation of submicron volcanic aerosol-particles by photoelectron emission

Volcanic aerosol emissions have been studied for the first time by in situ photoelectric charging. Explorative studies on Mt Etna reveal large concentrations of particles below 1000 nm with the spectrum peaking in the size range of 100–1000 nm diameter. Although a large fraction of the particles is already charged upon emission, the net electrical charge carried by the aerosol turned out to be close to zero.Particles with high photoelectric yield vary greatly in their relative abundance and seem to occur mainly at active points of the volcano.     

Use of Rhodamine water tracer in the marshland upwelling system

Rhodamine water tracer (RWT) was used to characterize the migration of waste water within the saline subsurface of a marshland upwelling system (MUS), which is an alternative on-site waste water treatment system for coastal areas. Field tracer studies were performed to investigate the fresh waste water plume movement within the saline ground water. Pore velocities were calculated using first detection times and ranged from 0.68 to 10.7 x 10(-4) cm/sec for the loamy sandy soil matrix present at the site. Use of RWT in the field also allowed determination of main and preferential flowpaths. One- and two-dimensional laboratory experiments were performed using silica sand to investigate the interactions of the organically rich waste water with RWT within the zone surrounding the point of injection (one-dimensional) and the impact of background salinity on plume movement (two-dimensional). The results from these studies were used to help explain the field data. One-dimensional breakthrough curves revealed retardation factors for the RWT in the waste water mixture of 1.73 to 1.90. These results were similar to other researchers, indicating little interaction between the waste water and RWT. Variations in pore water salinity (5, 15, 25, and 35 ppt) were found to have a significant effect on pore water velocities of the fresh water plume (two-dimensional), indicating the need to incorporate background salinities into the design process for MUS.     

Metadolerite age relationships in the Dalradian of northwest Donegal,Ireland and their orogenic significance

The structural relationships of several intrusive sheets belonging to the extensive metadolerite suite of the Appin (lower) Dalradian rocks of the Creeslough area, northwest Donegal, Ireland have been examined. It is concluded that, relative to the regional chronology of deformation of the enclosing metasediments, sheet emplacement has occurred: pre-D2; syn-D2; between D2 and D3; and syn-D3. The height of activity came in the post-D2, pre-D3 interval and coincided with the peak of regional metamorphism in the area. These relationships in Donegal are compared with those of the pretectonic basic rocks of the southwest Highlands and models are discussed.