Molekular Connectivity Indizes als strukturchemische Stoffparameter ökotoxikologischer Relevanz

The molecular connectivity index developed by Randic as a numerical expression characterizes the position and bond of atoms in the molecular structure. Since significant correlations between the molar refraction as well as electron polarizability and ecotoxicologically relevant parameters of substances were determined in the preceding investigations, such connections are investigated also for this index and sorption coefficients, bioconcentration factors and toxicity data. By the example of 56 differentiated organic substances, significant regression relations are demonstrated between bioconcentration factors, sorption coefficients and toxicity data as well as the valency molecular connectivity indices. By these regressions it is possible to determine essential distribution and action parameters of chemical substances from the structure for assesing an ecotoxicological risk. The possibilities resulting from this for predicting ecotoxicologically relevant parameters of substances are discussed.     

Unusual spatial-temporal dynamics of geomagnetic disturbances during the main phase of the extremely strong magnetic storm of November 7–8, 2004

The spatial dynamics of geomagnetic variations and pulsations, auroras, and riometer absorption during the development of the main phase of the extremely strong magnetic storm of November 7–8, 2004, has been studied. It has been indicated that intense disturbances were observed in the early morning sector of auroral latitudes rather than in the nighttime sector, as usually takes place during magnetic storms. The unusual spatial dynamics was revealed at the beginning of the storm main phase. A rapid poleward expansion of disturbances from geomagnetic latitudes of 65°–66° to 74°–75° and the development of the so-called polar cap substorm with a negative bay amplitude of up to 2500 nT, accompanied by precipitation of energetic electrons (riometer absorption) and generation of Pi2–Pi3 pulsations, were observed when IMF B _z was about ?45 nT. The geomagnetic activity maximum subsequently sharply shifted equatorward to 60°–61°. The spatial dynamics of the westward electrojet, Pi2–Pi3 geomagnetic pulsations, and riometer absorption was similar, which can indicate that the source of these phenomena is common.     

The birthplaces of active regions and X-ray bright points

A comparison of soft X-ray pictures of the Sun (S-054 experiment of Skylab) with K-line spectroheliograms (Mount Wilson) shows that the X-ray bright points tend to emerge randomly throughout the Ca network pattern. However, all those bright points that developed into active regions emerged at the boundaries of network cells. This suggests that the magnetic flux of active regions comes from greater depths in the convection zone than the shallow flux that gives rise to the random emergence of bright points.Also Physics Department, C-011, University of California at San Diego, La Jolla, Calif., U.S.A.     

Favourable uranium–phosphate exploration trends guided by the application of statistical factor analysis technique on the aerial gamma spectrometric data in Syrian desert (Area-1), Syria

A scored lithological map including 10 radiometric units is established through applying factor analysis approach to aerial spectrometric data of Area-1, Syrian desert, which includes Ur, eU, eTh, K%, eU/eTh, eU/K%, and eTh/K%. A model of four rotated factors F1, F2, F3, and F4 is adapted for representing 234,829 data measured points in Area-1, where 86% of total data variance is interpreted. A geological scored pseudo-section derived from the lithological scored map is established and analyzed in order to show the possible stratigraphic and structural traps for uranium occurrences associated with phosphate deposits in the studied Area-1. These identified traps presented in this paper need detailed investigation and must be necessarily followed and checked by ground validations and subsurface well logging, in order to locate the anomalous uranium occurrences and explore with more confidence and certitude their characteristics as a function of depth.     

The First Results of U–Pb Isotope Dating of Detrital Zircons from the Upper Mesoproterozoic Gulliksenfellet Quartzite (Southern Part of Wedel Jarlsberg Land,Southwest Spitsbergen)

The first results of U–Pb isotopic dating (LA–ICP–MS) of detrital zircons from metasedimentary rocks of the pre-Devonian basement of the SW part of western Spitsbergen (from Upper Mezoproterozoic Gulliksenfellet quartzite) showed ages ranging from 1700 ± 25 to 2948 ± 27 Ma.     

Measuring proton energies and fluxes using EIT (SOHO) CCD areas outside the solar disk images

An indirect proton flux measuring tool based on discrimination of the energy deposited by protons in 128 × 128 pixel EIT CCD areas outside the solar disk images is presented. Single pixel intensity events are converted into proton incident energy flux using modeled energy deposition curves for angles of incidence ±60° in four EIT spatial areas with different proton stopping power. The extracted proton flux is corrected for both the loss of one‐pixel events in the range of angles of incidence as well as for the contribution to the single pixel events resulting from scattered middle‐energy protons (low‐energy or high‐energy particles are stopped by the EIT components or pass through them, accordingly). A simple geometrical approach was found and applied to correct for a non‐unique relation between the proton‐associated CCD output signal and the incident proton energy. With this geometrical approximation four unique proton incident energy ranges were determined as 45–49, 145–154, 297–335, and 390–440 MeV. The indirect proton flux measuring tool has been tested by comparing Solar Energetic Particles (SEP) flux temporal profiles extracted from the EIT CCD frames and downloaded from the GOES database for the Bastille Day (BD) of 2000 July 14 and the more recent 2005 January 20 events. The SEP flux temporal profiles and proton spectra extracted from the EIT in the relatively narrow energy ranges between 45 and 440 MeV reported here are consistent with the related GOES profiles. The four additional EIT extracted ranges provide higher energy resolution of the SEP data. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)