The composition and crystallinity of the near-surface regions of weathered alkali feldspars

Our ability to identify thin non-stoichiometric and amorphous layers beneath mineral surfaces has been tested by undertaking X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) work on alkali feldspars from pH 1 dissolution experiments. The outcomes of this work were used to help interpret XPS and TEM results from alkali feldspars weathered for <10,000 years in soils overlying the Shap Granite (north-west England). The chemistry of effluent solutions indicates that silica-rich layers a few nanometers in thickness formed during the pH 1 experiments. These layers can be successfully identified by XPS and have lower Al/Si, Na/Si, K/Si and Ca/Si values than the outermost ∼9 nm of unweathered controls. Development of Al-Si non-stoichiometry is coupled with loss of crystal structure to produce amorphous layers that are identifiable by TEM where >∼2.5 nm thick, whereas the crystallinity of albite is retained despite leaching of Na to depths of tens to hundreds on nanometers. Integration of XPS data over the outermost 6-9 nm of naturally weathered Shap feldspars shows that they have stoichiometric Al/Si and K/Si ratios, which is consistent with findings of previous TEM work on the same material that they lack amorphous layers. There is some XPS evidence for loss of K from the outermost couple of nanometers of Shap orthoclase, and the possibility of leaching of Na from albite to greater depths cannot be excluded using the XPS or TEM results. This study demonstrates that the leached layer model, as formulated from laboratory experiments, is inapplicable to the weathering of alkali feldspars within acidic soils, which is an essentially stoichiometric reaction.     

Provenance of the Bosnian Flysch

Sandwiched between the Adriatic Carbonate Platform and the Dinaride Ophiolite Zone, the Bosnian Flysch forms a c. 3000 m thick, intensely folded stack of Upper Jurassic to Cretaceous mixed carbonate and siliciclastic sediments in the Dinarides. New petrographic, heavy mineral, zircon U/Pb and fission-track data as well as biostratigraphic evidence allow us to reconstruct the palaeogeology of the source areas of the Bosnian Flysch basin in late Mesozoic times. Middle Jurassic intraoceanic subduction of the Neotethys was shortly followed by exhumation of the overriding oceanic plate. Trench sedimentation was controlled by a dual sediment supply from the sub-ophiolitic high-grade metamorphic soles and from the distal continental margin of the Adriatic plate. Following obduction onto Adria, from the Jurassic–Cretaceous transition onwards a vast clastic wedge (Vranduk Formation) was developed in front of the leading edge, fed by continental basement units of Adria that experienced Early Cretaceous synsedimentary cooling, by the overlying ophiolitic thrust sheets and by redeposited elements of coeval Urgonian facies reefs grown on the thrust wedge complex. Following mid-Cretaceous deformation and thermal overprint of the Vranduk Formation, the depozone migrated further towards SW and received increasing amounts of redeposited carbonate detritus released from the Adriatic Carbonate Platform margin (Ugar Formation). Subordinate siliciclastic source components indicate changing source rocks on the upper plate, with ophiolites becoming subordinate. The zone of the continental basement previously affected by the Late Jurassic–Early Cretaceous thermal imprint has been removed; instead, the basement mostly supplied detritus with a wide range of pre-Jurassic cooling ages. However, a c. 80 Ma, largely synsedimentary cooling event is also recorded by the Ugar Formation, that contrasts the predominantly Early Cretaceous cooling of the Adriatic basement and suggests, at least locally, a fast exhumation.     

Sedimentology of the continental end‐Permian extinction event in the Sydney Basin,eastern Australia

Upper Permian to Lower Triassic coastal plain successions of the Sydney Basin in eastern Australia have been investigated in outcrop and continuous drillcores. The purpose of the investigation is to provide an assessment of palaeoenvironmental change at high southern palaeolatitudes in a continental margin context for the late Permian (Lopingian), across the end‐Permian Extinction interval, and into the Early Triassic. These basins were affected by explosive volcanic eruptions during the late Permian and, to a much lesser extent, during the Early Triassic, allowing high‐resolution age determination on the numerous tuff horizons. Palaeobotanical and radiogenic isotope data indicate that the end‐Permian Extinction occurs at the top of the uppermost coal bed, and the Permo‐Triassic boundary either within an immediately overlying mudrock succession or within a succeeding channel sandstone body, depending on locality due to lateral variation. Late Permian depositional environments were initially (during the Wuchiapingian) shallow marine and deltaic, but coastal plain fluvial environments with extensive coal‐forming mires became progressively established during the early late Permian, reflected in numerous preserved coal seams. The fluvial style of coastal plain channel deposits varies geographically. However, apart from the loss of peat‐forming mires, no significant long‐term change in depositional style (grain size, sediment‐body architecture, or sediment dispersal direction) was noted across the end‐Permian Extinction (pinpointed by turnover of the palaeoflora). There is no evidence for immediate aridification across the boundary despite a loss of coal from these successions. Rather, the end‐Permian Extinction marks the base of a long‐term, progressive trend towards better‐drained alluvial conditions into the Early Triassic. Indeed, the floral turnover was immediately followed by a flooding event in basinal depocentres, following which fluvial systems similar to those active prior to the end‐Permian Extinction were re‐established. The age of the floral extinction is constrained to 252.54 ± 0.08 to 252.10 ± 0.06 Ma by a suite of new Chemical Abrasion Isotope Dilution Thermal Ionization Mass Spectrometry U‐Pb ages on zircon grains. Another new age indicates that the return to fluvial sedimentation similar to that before the end‐Permian Extinction occurred in the basal Triassic (prior to 251.51 ± 0.14 Ma). The character of the surface separating coal‐bearing pre‐end‐Permian Extinction from coal‐barren post‐end‐Permian Extinction strata varies across the basins. In basin‐central locations, the contact varies from disconformable, where a fluvial channel body has cut down to the level of the top coal, to conformable where the top coal is overlain by mudrocks and interbedded sandstone–siltstone facies. In basin‐marginal locations, however, the contact is a pronounced erosional disconformity with coarse‐grained alluvial facies overlying older Permian rocks. There is no evidence that the contact is everywhere a disconformity or unconformity.     

The S-External pyrenees of Huesca

An Upper Cretaceous-Paleocene series is more or less detached from the Hercynian basement and piled up southward as a Younger Calcareous Chain. A broad belt of Eocene flysch with limestone intercalations terminates eastward against a contemporaneous cross-structure and is affected by a zone of persistent overturning.

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Zusammenfassung Eine Oberkreide-PalÄozÄn-Serie ist teilweise vom herzynischen Untergrund abgeschert und südwÄrts als Jüngere Kalkkette aufgestaucht. Eine breite Zone von EozÄn-Flysch mit Kalkeinlagerungen endet nach Osten an einer gleichaltrigen Querstruktur. Sie enthÄlt einen durchgehend überkippten Streifen.

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Résumé La série néocrétacée-paléocène est plus ou moins décollée du socle hercynien et déversée au sud comme «ChaÎne calcaire postérieure». Une large zone de flysch éocène à intercalations calcaires se termine vers l'est contre un accident transversal contemporain et est affectée d'une bande persistante de renversement.

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Undamped oscillations of collisionless stellar systems: Spheres,spheroids and discs

The collisionless Boltzmann equation governing self-gravitating systems such as galaxies has recently been shown to admit exact oscillating solutions with planar and spherical symmetry. The relation of the spherically symmetric solutions to the Virial theorem, as well as generalizations to non-uniform spheres, uniform spheroids and discs form the subject of this paper. These models generalize known families of static solutions. The case of the spheroid is worked out in some detail. Quasiperiodic as well as chaotic time variation of the two axes is demonstrated by studying the surface of section for the associated Hamiltonian system with two degrees of freedom. The relation to earlier work and possible implications for the general problem of collisionless relaxation in self gravitating systems are also discussed     

Comparison of Two Methods Used to Model Shape Parameters of Pareto Distributions

Two methods are compared for estimating the shape parameters of Pareto field-size (or pool-size) distributions for petroleum resource assessment. Both methods assume mature exploration in which most of the larger fields have been discovered. Both methods use the sizes of larger discovered fields to estimate the numbers and sizes of smaller fields: (1) the tail-truncated method uses a plot of field size versus size rank, and (2) the log–geometric method uses data binned in field-size classes and the ratios of adjacent bin counts. Simulation experiments were conducted using discovered oil and gas pool-size distributions from four petroleum systems in Alberta, Canada and using Pareto distributions generated by Monte Carlo simulation. The estimates of the shape parameters of the Pareto distributions, calculated by both the tail-truncated and log–geometric methods, generally stabilize where discovered pool numbers are greater than 100. However, with fewer than 100 discoveries, these estimates can vary greatly with each new discovery. The estimated shape parameters of the tail-truncated method are more stable and larger than those of the log–geometric method where the number of discovered pools is more than 100. Both methods, however, tend to underestimate the shape parameter. Monte Carlo simulation was also used to create sequences of discovered pool sizes by sampling from a Pareto distribution with a discovery process model using a defined exploration efficiency (in order to show how biased the sampling was in favor of larger fields being discovered first). A higher (more biased) exploration efficiency gives better estimates of the Pareto shape parameters.     

Statistics-based outlier detection for wireless sensor networks

Wireless sensor network (WSN) applications require efficient, accurate and timely data analysis in order to facilitate (near) real-time critical decision-making and situation awareness. Accurate analysis and decision-making relies on the quality of WSN data as well as on the additional information and context. Raw observations collected from sensor nodes, however, may have low data quality and reliability due to limited WSN resources and harsh deployment environments. This article addresses the quality of WSN data focusing on outlier detection. These are defined as observations that do not conform to the expected behaviour of the data. The developed methodology is based on time-series analysis and geostatistics. Experiments with a real data set from the Swiss Alps showed that the developed methodology accurately detected outliers in WSN data taking advantage of their spatial and temporal correlations. It is concluded that the incorporation of tools for outlier detection in WSNs can be based on current statistical methodology. This provides a usable and important tool in a novel scientific field.     

A parametric study on the impact of satellite attitude errors on GOCE gravity field recovery

In the recent design of the Gravity field and steady-state Ocean Circulation Explorer (GOCE) satellite mission, the gravity gradients are defined in the gradiometer reference frame (GRF), which deviates from the actual flight direction (local orbit reference frame, LORF) by up to 3–4°. The main objective of this paper is to investigate the effect of uncertainties in the knowledge of the gradiometer orientation due to attitude reconstitution errors on the gravity field solution. In the framework of several numerical simulations, which are based on a realistic mission configuration, different scenarios are investigated, to provide the accuracy requirements of the orientation information. It turns out that orientation errors have to be seriously considered, because they may represent a significant error component of the gravity field solution. While in a realistic mission scenario (colored gradiometer noise) the gravity field solutions are quite insensitive to small orientation biases, random noise applied to the attitude information can have a considerable impact on the accuracy of the resolved gravity field models.     

The role of organic coatings in the enrichment of marine particles with selenium. The fixation of selenite on an adsorbed amino acid

The enrichment of marine particles with selenium cannot be explained as that with metals present in cationic form by complexation with anionic functional groups of adsorbed organic matter. Physicochemical data obtained using a model system are reported. The surface of the particles is modelized by a mercury electrode whose surface charge density can be easily changed, covered by a layer of adsorbed polymers. Studies with different kinds of macromolecules and salts show a specific interaction between adsorbed polyalanine and selenite. The results can be explained by the concordance of the distances between two oxygen atoms in this oxyanion and between two amine groups of the adsorbed polypeptide. A similar mechanism could occur in marine aggregates whatever their nature, as long as they contain amine groups at their surface which result in this concordance. Some prospects derived from the results are discussed.