Carbon isotopic fractionation between CO2 vapour,silicate and carbonate melts: an experimental study to 30 kbar

The carbon isotopic fractionation between CO₂ vapour and sodamelilite (NaCaAlSi₂O₇) melt over a range of pressures and temperatures has been investigated using solid-media piston-cylinder high pressure apparatus. Ag₂C₂O₄ was the source of CO₂ and experimental oxygen fugacity was buffered at hematite-magnetite by the double capsule technique. The abundance and isotopic composition of carbon dissolved in sodamelilite (SM) glass were determined by stepped heating and the ¹³C of coexisting vapour was determined directly by capsule piercing. CO₂ solubility in SM displays a complex behavior with temperature. At pressures up to 10 kbars CO₂ dissolves in SM to form carbonate ion complexes and the solubility data suggest slight negative temperature dependence. Above 20 kbars CO₂ reacts with SM to form immiscible Na-rich silicate and Ca-rich carbonate melts and CO₂ solubility in Na-enriched silicate melt rises with increasing temperature above the liquidus. Measured values for carbon isotopic fractionation between CO₂ vapour and carbonate ions dissoived in sodamelilite melt at 1200°–1400° C and 5–30 kbars average 2.4±0.2, favouring¹³C enrichment in CO₂ vapour. The results are maxima and are independent of pressure and temperature. Similar values of 2 are obtained for the carbon isotopic fractionation between CO₂ vapour and carbonate melts at 1300°–1400° C and 20–30 kbars.     

Age and structure of the southern Rockall Trough new evidence

The Rockall Trough separates the Rockall Plateau microcontinent from the shelf and slope west of the British Isles. The structure and age of the trough has been the source of considerable discussion. Although widely considered to be of oceanic origin, postulated ages for the spreading range from Permian to Cretaceous. New seismic profiles linked to the IPOD sites in the Bay of Biscay and to oceanic anomalies of known age are used to present a new assessment of the age and structure of the southern Rockall Trough. It is concluded that about 120 km of ocean crust is present in the trough and that spreading took place in the Albian-Maastrichtian interval.     

Low frequency edge waves over a trench-ridge topography adjoining a straight coastline

Abstract

The possible interaction of trapped midoceanic boundary waves with a nearby coastline is examined by considering a step trench-ridge topography adjoining a semi-infinite straight coastline. The full dispersion equation, including the effect of the earth's rotation, is derived for long waves over this topography. It is shown that the presence of the coastline begins to have a significant effect on the behaviour of quasigeostrophic ridge waves whenever the wave length is greater than three times the ridge coastline separation.

As an example, the dispersion curves are presented for the topography of the Heceta Bank off the coast of Oregon and it is conjectured that the presence of this off-shore ridge may provide an explanation for the anomalous direction of propagation of the 0.1 c.p.d. shelf wave reported by Mooers and Smith (1968).     

Dynamical conditions in planets and stars

With the available data in planets, stars and galaxies, it is studied the functions of angular momentaJ(M) and amounts of actionA _c(M) (associated to the non rotational terms in the kinetic energy). The results indicate that independently of how are these functionsJ(M),A _c(M) their ratioA _c/J remains a near invariant. It is independent also from the type of angular momenta: intrinsic spins of the bodies or the total angular (orbital) momenta of the bodies forming a system; for instance, the Solar System and the planets.The relationA _c(M) for the Solar System are analogous to these in the FGK stars of the main sequence, and the relationJ(M) (also for the Solar System) is analogous to the lower possible limit for binary stars.The different types of binary stars from the short period, detached systems to contactary systems, gives a range of functionsJ(M),A _c(M) that are the same that one can expect in stars with planetary systems. According to the detection limits given for planetary companions by Campbell, Walker and Yang (1988) (masses of less than 9 Jupiter masses and orbital periods of less than 50 years) we calculate the limits forJ(M) andA _c(M) This gives a lower limitA _c/J 1 associated to stars with planetary systems as 61 Cygni and to short period detached binaries. The upper limitA _c/J 16 correspond to planetary systems as the ours and probably to cataclysmic binaries. There are reasons to suspect that systems as the ours and in range 4 A _c/J 16 (with a lower limit analogous to contactary binaries as Algols and W Ursa Majoris) must be the most common type of planetary systems. The analogies with the functionsJ(M)A _c(M) for galaxies suggest cosmogonical conditions in the stellar formation.Independently of this, one can have boundary conditions for the Jacobi problem when applied to a collapsing cloud. Namely, from the initial stage (a molecular cloud) to the final stage (a formed stellar system: binary or planetary) the angular momenta and amounts of action decayed to 10^~4 the initial values, but in such a form thatA _c(t)/J(t) remains a near invariant.     

The upper Bathonian ammonite zonation of East Siberia

Modifications to the upper Bathonian zonal scale for northern East Siberia provided by the newly available paleontological record on Middle Jurassic reference sections in the Arctic regions of Yakutia and by the revised earlier collections, are justified. The oldest East Siberian members of Cadoceras are found to be characteristic not of the initial Callovian age as believed by Russian paleontologists, but of the terminal Bathonian age as was previously shown in the biostratigraphic scheme of East Greenland. The succession of zones and index species analogous to that of the latter is revealed in the studied region and the zonal boundaries in Siberia and East Greenland are inferred to be synchronous. Finds of Cadoceras calyx in the upper Bathonian scale permitted, for the first time, the recognition of a corresponding zone. The Bathonian-Callovian boundary is placed between the calyx and anabarense zones. The upper Bathonian zonal scale of northern East Siberia is now in total agreement with the East Greenland zonal scale.     

Permian volcanism in the Central Western Carpathians (Slovakia): Basin-and-Range type rifting in the southern Laurussian margin

The 1,500- to 2,000-m-thick Permian volcano-sedimentary Malu?iná Formation of the uppermost nappe of the Central Western Carpathians (a segment of the Alpine-Carpathian orogenic belt) occurs in several fault blocks distributed across Slovakia. This unit is a part of a post-Variscan overstep suite that followed accretion of the Gothic terranes to Laurussia. It consists of three upward-fining megacycles of semi-arid/arid, fluvial-lacustrine clastic redbeds and local dolomites and evaporites. Abundant intercalated volcanic rocks are predominantly mafic lava flows; volcaniclastic rocks and dykes are subordinate. Felsic rocks are represented by rare volcaniclastics and dykes. Compositionally, the mafic rocks are rift-related continental tholeiites with enriched light REE patterns having (La/Yb)_n ratios between 2 and 5.5 and with mantle-normalized patterns characterized by negative Nb-Ta anomalies. The rocks were derived from subcontinental lithospheric mantle and were affected by crustal contamination. It is inferred that the volcanism of the Malu?iná Formation formed in a Basin and Range tectonic setting in which rifting followed collision of the Palaeo-Tethys ridge with the trench bordering southern Laurussia. This model can be applied to other Permian volcanic suites of rift basins in the Eastern Alps and Carpathians over a strike-length of about 1,000 km, which indicates the width of the slab window.     

Efficacy of Selected Compounds on Thermocyclops oblongatus,one of the Main Intermediate Hosts of Guinea Worm in Africa

Ten selected compounds were tested on Thermocyclops oblongatus to determine their ability to be used for treatment of drinking water sources. None were shown to be interesting for individual application in household water tanks. Tested compounds, such as potassium permanganate or chlorine-releasing products, were ineffective or affected dramatically the taste or colour of the water. For collective application in water sources, temephos appeared to be the most valuable pesticide because it was effective against cyclops and harmless for environment. Other pesticides should be proposed as substitutes in case of cyclops resistance to temephos.     

An ephemeral turbidity maximum generated by resuspension of organic-rich matter in a macrotidal estuary, S.W. Wales

An ephemeral estuarine turbidity maximum (ETM) occurs at high water in the macrotidal Taf estuary (SW Wales, United Kingdom). A new mechanism of ETM formation, due to resuspension and advection of material by flood tidal currents, is observed that differs from classical mechanisms of gravitational circulation and tidal pumping. The flood tide advances across intertidal sand flats in the main body of the estuary, progressively entraining material from the rippled sands. Resuspension creates, a turbid front that has suspended sediment concentrations (SSC) of about 4,000 mg I⁻¹ by the time it reaches its landward limit which is also the landward limit of salt penetration. This turbid body constitutes the ETM. Deposition occurs at high slack water but the ETM retains SSC values up to 800 mg I⁻¹, 1–2 orders of magnitude greater than ambient SSC values in the river and estuarine waters on either side. The ETM retreats down the estuary during the ebb; some material is deposited thinly across emergent intertidal flats and some is flushed out of the estuary. A new ETM is generated by the next flood tide. Both location and SSC of the ETM scale on Q/R³ where Q is tidal range and R is river discharge. The greatest expression of the ETM occurs when a spring tide coincides with low river discharge. It does not form during high river discharge conditions and is poorly developed on neap tides. Particles in the ETM have effective densities (120–160 kg m⁻³) that are 3–4 times less than those in the main part of the estuary at high water. High chlorophyll concentrations in the ETM suggest that flocs probably originate from biological production in the estuary, including production on the intertidal sand flats.