High-resolution ion-microprobe measurement of lead isotopes: Variations within single zircons from Lac Seul,northwestern Ontario

Selected-area measurements of lead-isotope ratios in zircons have been made at high mass resolution using a modified A.E.I. IM20 ion-microprobe. At a working resolution of 3200 it is shown that the important interfering molecular peaks generated from the zircon matrix may be separated from atomic lead peaks. Corrections for overlapping peaks, which are necessary in measurements of lead isotopes at low mass resolution, are then only required for ²⁰⁸Pb.Measurements on N.B.S. standards show no isotope discrimination within counting statistics. Determination of ²⁰⁷Pb/²⁰⁶Pb on 29 single zircon grains from a tonalite gneiss and a granite from Lac Seul, northwestern Ontario, give very variable ratios with mean values close to those of bulk separates. Peaks in the distribution of 207/206 ratios obtained from the tonalite gneiss may be interpreted as evidence for two stages of lead loss. High 207/206 ratios are shown to be significant for at least two zircons and probably record a minimum age of formation of 3.3 ± 0.1 b.y. for the gneiss.     

Transport and retention of suspended particulate matter and bacteria in the Humber-Ouse Estuary, United Kingdom, and their relationship to hypoxia and anoxia

Data are presented on dissolved oxygen (DO) concentrations and their relationship to salinity, suspended particulate matter (SPM), concentrations, and the turbidity maximum in the Humber-Ouse Estuary, United Kingdom, during summer 1995. Measurements in the upper Humber during March 1995 showed DO in the range 82% to 87% of saturation. Suspended particulate matter concentrations were <5000 mg l^?1 and salinity was in the range 0.5 to 12. In contrast, a pronounced DO sag occurred in the upper reaches of the Ouse during medium and spring tide, summer conditions. The DO minimum was essentially an anoxic level and was associated with the location of the turbidity maximum, at salinities between about 0.4 and 1.5. SPM concentrations at 1 m beneath the surface reached 25,000 mg l^?1 in the turbidity maximum, between about 20 km and 40 km from the tidal limit. Suspended particulate matter concentrations were much lower at neap tides, although dense suspensions of SPM (>60,000 mg l^?1) occurred within 1 m of the bed in the turbidity maximum region. A spring-neap record showed a dramatic and tidally controlled decrease in DO at very low salinities as the tides progressed from neaps to springs. An anchor station located down-channel of the turbidity maximum showed that about 95% of the variance in DO, which varied from 28% at low-water slack to 67% at high-water slack, could be explained in terms of salinity variation. At the up-channel margins of the turbidity maximum, DO increased from zero (anoxia) near high water to 60% near low water slack, in contrast to the behavior down-channel of the turbidity maximum. About 82% of the variance in DO could be explained in terms of salinity variations alone. Only 43% of the DO variance could be explained in terms of SPM alone. Up-channel of the turbidity maximum, SPM concentrations were relatively low (<3000 mg l^?1) and DO levels varied from 48% of saturation near high water to 83% near low water slack. About 76% of the variance in DO could be explained in terms of salinity variations alone. Within the turbidity maximum region, DO varied from <2% saturation on the early flood and late ebb and maximized around 7% at high water slack. About 63% of the variance in DO could be explained in terms of salinity variation alone. This increased to 70% when suspended particulate matter was taken into account. Only 29% of the DO variance could be explained in terms of suspended particulate matter alone. Because bacteria were likely to have been the cause of the observed reduction in DO, the numbers of bacteria, both free-living and attached to particles, were measured in the turbidity maximum region. Numbers of free-living bacteria were low and most of the bacteria were attached to sediment particles. There was a linear correlation between total bacterial number and suspended particulate matter concentration, suggesting that the strong DO demand was exerted locally as a result of bacterial activity associated with increased suspended particulate matter concentrations. An order of magnitude analysis of DO consumption within the Ouse’s turbidity maximum, based on the premise that DO depletion was directly related to suspended particulate matter concentrations and that DO addition was due to reaeration, indicates that complete deoxygenation could have occurred with an oxygen depletion rate of ～0.01 mg DO h^?1/g suspended particulate matter during the residence time of waters within the turbidity maximum (～7 d). This rate was sufficiently fast that anoxic to aerobic conditions were able to develop a spring-neap periodicity within the turbidity maximum, but too slow to generate substantial intratidal fluctuations in DO. This is in accordance with the observations, which show that relatively little of the intratidal variance in DO could be explained in terms of suspended particulate matter fluctuations, whereas most of the variance could be explained in terms of salinity, which behaved as a surrogate measure for the proximity of the turbidity maximum.     

Distinguishing lower and upper crustal processes in magmas erupted during the buildup to the 7.7 ka climactic eruption of Mount Mazama, Crater Lake, Oregon, using 238U–230Th disequilibria

Uranium-series isotope ratios determined for 35 volcanic rocks and 4 glass separates erupted from ~36 to 4.8 ka at Mt. Mazama, Crater Lake, Oregon, identify both ²³⁰Th-excess and ²³⁸U-excess components. U–Th isotope compositions cover a wide range, exceeding those previously measured for the Cascade arc. Age-corrected (²³⁰Th/²³²Th) and (²³⁸U/²³²Th) activity ratios range from 1.113 to 1.464 and from 0.878 to 1.572 (44.4 % ²³⁰Th-excess to 8.8 % ²³⁸U-excess), respectively. The most distinctive aspect of the data set is the contrast in U–Th isotope ratios between low and high Sr (LSr, HSr) components that have been previously identified in products of the 7.7 ka caldera-forming climactic eruption and preclimactic rhyodacite lavas. The LSr component exclusively contains ²³⁸U-excess, but the HSr component, as well as more primitive lavas, are marked by ²³⁰Th-excess. ²³⁰Th-excesses such as those recorded at Mt. Mazama are commonly observed in the Cascades. Melting models suggest that high ²³⁰Th-excesses observed in the more primitive lavas evolved through mixing of a mantle melt with a partial melt of a mafic lower crustal composition that contained garnet in the residuum that was produced through dehydration melting of amphibolite that was initially garnet free. Dehydration melting in the lower crust offers a solution to the “hot-slab paradox” of the Cascades, where low volatile contents are predicted due to high slab temperatures, yet higher water contents than expected have been documented in erupted lavas. The ²³⁸U-excess observed at Mt. Mazama is rare in Cascade lavas, but occurs in more than half of the samples analyzed in this study. Traditionally, ²³⁸U-excess in arc magmas is interpreted to reflect slab fluid fluxing. Indeed, ²³⁸U-excess in arcs is common and likely masks ²³⁰Th-excess resulting from lower crustal interaction. Isotopic and trace element data, however, suggest a relatively minor role for slab fluid fluxing in the Cascades. We propose that ²³⁸U-excess reflects melting and assimilation of young, hydrothermally altered upper crust. The processes related to generating ²³⁸U-excess are likely important features at Mt. Mazama that accompanied development of a large-scale silicic magma chamber that led to the caldera-forming eruption.     

Asymmetry of compton scattering by relativistic electrons with an isotropic velocity distribution: Astrophysical implications

The angular distribution of low-frequency radiation after a single scattering by relativistic electrons with an isotropic velocity distribution differs markedly from the Rayleigh angular function. In particular, the scattering by an ensemble of ultrarelativistic electrons is described by the law p=1?cosα, where α is the scattering angle. Thus, photons are mostly scattered backward. We discuss some consequences of this fact for astrophysical problems. We show that a hot atmosphere of scattering electrons is more reflective than a cold one: the fraction of incident photons reflected after a single scattering can be larger than that in the former case by up to 50%. This must affect the photon exchange between cold accretion disks and hot coronae (or advective flows) near relativistic compact objects, as well as the rate of cooling (through multiple inverse-Compton scattering of the photons supplied from outside) of optically thick clouds of relativistic electrons in compact radio sources. Scattering asymmetry also causes the spatial diffusion of photons to proceed more slowly in a hot plasma than in a cold one, which affects the shapes of Comptonization spectra and the time delay in the detection of soft and hard radiation from variable X-ray sources.     

Automated co-registration of images from multiple bands of Liss-4 camera

Three multi-spectral bands of the Liss-4 camera of IRS-P6 satellite are physically separated in the focal plane in the along-track direction. The time separation of 2.1 s between the acquisition of first and last bands causes scan lines acquired by different bands to lie along different lines on the ground which are not parallel. Therefore, the raw images of multi-spectral bands need to be registered prior to any simple application like data visualization. This paper describes a method for co-registration of multiple bands of Liss-4 camera through photogrammetric means using the collinearity equations. A trajectory fit using the given ephemeris and attitude data, followed by direct georeferencing is being employed in this model. It is also augmented with a public domain DEM for the terrain dependent input to the model. Finer offsets after the application of this parametric technique are addressed by matching a small subsection of the bands (100×100 pixels) using an image-based method. Resampling is done by going back to original raw data when creating the product after refining image coordinates with the offsets. Two types of aligned products are defined in this paper and their operational flow is described. Datasets covering different types of terrain and also viewed with different geometries are studied with extensive number of points. The band-to-band registration (BBR) accuracies are reported. The algorithm described in this paper for co-registration of Liss-4 bands is an integral part of the software package Value Added Products generation System (VAPS) for operational generation of IRS-P6 data products.     

Decorrelated GRACE time-variable gravity solutions by GFZ,and their validation using a hydrological model

We have analyzed recent gravity recovery and climate experiment (GRACE) RL04 monthly gravity solutions, using a new decorrelating post-processing approach. We find very good agreement with mass anomalies derived from a global hydrological model. The post-processed GRACE solutions exhibit only little amplitude damping and an almost negligible phase shift and period distortion for relevant hydrological basins. Furthermore, these post-processed GRACE solutions have been inspected in terms of data fit with respect to the original inter-satellite ranging and to SLR and GPS observations. This kind of comparison is new. We find variations of the data fit due to solution post-processing only within very narrow limits. This confirms our suspicion that GRACE data do not firmly ‘pinpoint’ the standard unconstrained solutions. Regarding the original Kusche (J Geod 81:733–749, 2007) decorrelation and smoothing method, a simplified (order-convolution) approach has been developed. This simplified approach allows to realize a higher resolution—as necessary, e.g., for generating computed GRACE observations—and needs far less coefficients to be stored.     

Total N,total P and organic matters content in floodplain soils of Xianghai Nature Reserve

Soil sediment samples of 10 layers with a spacing of 10 cm each were collected in different floodplain zones adjacent to Huolin River in the Xianghai Nature Reserve, and contents of total N, total P and organic matters were analyzed. The results showed that contents of total N, total P and organic matters were generally decreasing with the increase of distance from sample locations to the river channel, and contents of the three items were generally higher in the upper soil layer than that in the lower soil layer. The content variations displayed how flooding functions influenced nutrient matter content variations in floodplain soils since the flood inundation frequencies of the sample locations varied. The correlation analysis displayed that there were remarkable relativities between total N, total P and organic matters within definite spatial distance from the Huolin River channel.