Modeling the Potential Effect of Additives on Enhancing the Solubility of Aromatic Solutes Contained in Gasoline

The potential effect of two common gasoline additives, ethanol and methyl tertiary-butyl ether (MTBE), on enhancing the solubility of the aromatic solutes benzene, toluene, ethylbenzene, and o-, m-, and p-xylene, was examined using a computer model, ARSOL. Aqueous solute systems containing cosolvents ethanol and MTBE at 0, 0.1, 1, and 4.3 percent were modeled for both ethanol and MTBE systems. Five- and 10-percent ethanol systems were also modeled. Little solubility enhancement was predicted by modeling at cosolvent levels less than 1 percent. At cosolvent levels greater than 1 percent, predicted solute solubility increased curvilinearly with an increase in percent cosolvent; a 10 percent cosolvent system increased aromatic hydrocarbon solubility by approximately 100 percent. According to the model predictions, MTBE enhanced solute solubility more than ethanol, with enhancement by MTBE being approximately 10 percent greater than enhancement by ethanol at 4.3 percent cosolvent. Other concerns regarding gasoline additives are the observed reduction in partitioning of solutes to soils and sediments and the contamination of water supplies due to the high water solubility of the additives.     

Coda Q in the Kachchh Basin, Western India Using Aftershocks of the Bhuj Earthquake of January 26, 2001

Q_C-estimates of Kachchh Basin in western India have been obtained in a high frequency range from 1.5 to 24.0 Hz using the aftershock data of Bhuj earthquake of January 26, 2001 recorded within an epicentral distance of 80 km. The decay of coda waves of 30 sec window from 186 seismograms has been analysed in four lapse time windows, adopting the single backscattering model. The study shows that Q_c is a function of frequency and increases as frequency increases. The frequency dependent Q_c relations obtained for four lapse-time windows are: Q_c=82 f^1.17 (20–50 sec), Q_c=106 f^1.11 (30–60 sec), Q_c=126f^1.03 (40–70 sec) and Q_c=122f^1.02 (50–80 sec). These empirical relations represent the average attenuation properties of a zone covering the surface area of about 11,000, 20,000, 28,000 and 38,000 square km and a depth extent of about 60, 80, 95, 110 km, respectively. With increasing window length, the degree of frequency dependence, n, decreases marginally from 1.17 to 1.02, whereas Q₀ increases significantly from 82 to 122. At lower frequencies up to 6 Hz, Q_c⁻¹ of Kachchh Basin is in agreement with other regions of the world, whereas at higher frequencies from 12 to 24 Hz it is found to be low.     

Baseline levels of benzo(a)pyrene in southern California mussels

Marine mussels accumulate the carcinogen benzo(a)pyrene from contaminated environments. Baseline studies in California indicate that levels of the carcinogen in mussels are at or near zero, except in areas of human activity. This finding runs counter to previous suggestions that benzo(a)pyrene is widely distributed in marine organisms.     

Desertification processes in the Ili River delta under anthropogenic pressure

Desertification of delta landscapes, mainly soil cover, is considered on the example of the Ili River, which basin is located in Kazakhstan and China. Long-term researches on the Ili River were begun in 1968 before creation of the large Kapchagay reservoir and proceed with the use of the space imagery NASA/MODIS/Terra. Degradation of delta landscapes is differentiated in space and in time depending on the features of the natural water regime and its transformation because of flow regulation. The main accent in research has been made on the newest processes of desertification, caused by intensification of irrigation. Characteristics of drying, desertification and salinization of soils in delta are estimated on the state of spring 2008.     

Global high resolution versus Limited Area Model climate change projections over Europe: quantifying confidence level from PRUDENCE results

Four high resolution atmospheric general circulation models (GCMs) have been integrated with the standard forcings of the PRUDENCE experiment: IPCC-SRES A2 radiative forcing and Hadley Centre sea surface temperature and sea-ice extent. The response over Europe, calculated as the difference between the 2071–2100 and the 1961–1990 means is compared with the same diagnostic obtained with nine Regional Climate Models (RCM) all driven by the Hadley Centre atmospheric GCM. The seasonal mean response for 2m temperature and precipitation is investigated. For temperature, GCMs and RCMs behave similarly, except that GCMs exhibit a larger spread. However, during summer, the spread of the RCMs—in particular in terms of precipitation—is larger than that of the GCMs. This indicates that the European summer climate is strongly controlled by parameterized physics and/or high-resolution processes. The temperature response is larger than the systematic error. The situation is different for precipitation. The model bias is twice as large as the climate response. The confidence in PRUDENCE results comes from the fact that the models have a similar response to the IPCC-SRES A2 forcing, whereas their systematic errors are more spread. In addition, GCM precipitation response is slightly but significantly different from that of the RCMs.     

Projected climate change scenario over California by a regional ocean–atmosphere coupled model system

This study examines a future climate change scenario over California in a 10-km coupled regional downscaling system of the Regional Spectral Model for the atmosphere and the Regional Ocean Modeling System for the ocean forced by the global Community Climate System Model version 3.0 (CCSM3). In summer, the coupled and uncoupled downscaled experiments capture the warming trend of surface air temperature, consistent with the driving CCSM3 forcing. However, the surface warming change along the California coast is weaker in the coupled downscaled experiment than it is in the uncoupled downscaling. Atmospheric cooling due to upwelling along the coast commonly appears in both the present and future climates, but the effect of upwelling is not fully compensated for by the projected large-scale warming in the coupled downscaling experiment. The projected change of extreme warm events is quite different between the coupled and uncoupled downscaling experiments, with the former projecting a more moderate change. The projected future change in precipitation is not significantly different between coupled and uncoupled downscaling. Both the coupled and uncoupled downscaling integrations predict increased onshore sea breeze change in summer daytime and reduced offshore land breeze change in summer nighttime along the coast from the Bay area to Point Conception. Compared to the simulation of present climate, the coupled and uncoupled downscaling experiments predict 17.5 % and 27.5 % fewer Catalina eddy hours in future climate respectively.     

Volcanic emissions and the early Earth atmosphere

Despite uncertainties in our understanding of early Earth volcanism and atmospheric composition, thermodynamic modelling is able to offer estimates of the global production of reactive trace species (NO, OH, SO₃, Cl, Br and I) from early Earth volcanism, and thereby to shed light on processes which may have been different in Earth’s early atmosphere. Model results show that thermal decomposition of magmatic H₂O, CO₂ and SO₂ in high-T mixtures of magmatic and atmospheric gases (at T > 1400 °C) generate high levels of reactive trace gas species. Production of these reactive trace species is insensitive to atmospheric CO₂ in mixtures where the atmospheric gas is the minor component and will hence continue during periods of low atmospheric CO₂. Fluxes of NO, OH, Cl, Br and I from early Earth volcanism are predicted to exceed those from modern Earth volcanism as the higher temperature of early Earth emissions compensates for lower levels of O₂ in the atmosphere, compared to the modern Earth. Under certain conditions, the volcanic NO flux from early Earth volcanism is found to be comparable to other sources of reactive N such as lightning NO and photochemical HCN. This is one possible source of fixed nitrogen which may alleviate any postulated Archean nitrogen crisis. Our thermodynamic model reveals that production of SO₃ (a potential precursor for near-source volcanic sulphate and hence ‘primary’ volcanic aerosol) is likely to be significantly lower from early Earth volcanism. Uncertainty in the pathway to near-source sulphate in modern volcanism (i.e., the reaction of SO₃ with water or direct emission) introduces a large uncertainty into the production rate of near-source volcanic sulphate on the early Earth.     

The importance of iron speciation (Fe+2/Fe+3) in determining mineral assemblages: an example from the high‐grade aluminous metapelites of southeastern Madagascar

Metapelitic granulites from the Anosyen domain of southeastern Madagascar are exposed in three intercalated formations: the Amparihy, Bakika and Ihosy formations. Although mineralogically distinct from each other, the rocks from these formations show very similar bulk‐rock compositions when measured on a Fe_T basis. The preserved mineral assemblages thus do not reflect differences in the ratios of the main rock‐forming oxides (i.e. Al₂O₃:Fe_T:MgO), but instead reflect variations in the pre‐metamorphic oxidation state of the protolith rocks. These differences in oxidation state are manifested via differences in iron speciation – either Fe⁺² or Fe⁺³. The relatively reduced rocks of the Amparihy Formation preserve the assemblage bi–sp–sill–g–cd, which contrasts markedly with the mostly garnet and spinel‐absent bi–cd–sill–mt assemblages preserved in the strongly oxidized rocks of the Ihosy Formation. Compositionally intermediate rocks of the Bakika Formation are garnet bearing, but sillimanite‐absent, and contain the assemblage sp–g–cd–mag. Modelling of these rocks in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O system suggests that they evolved along a heating and cooling P–T path with only limited decompression accompanying cooling on the retrograde path. Peak temperatures and pressures of ～880–920 °C and 6–6.5 kbar are inferred for the majority of the Anosyen domain, with slightly lower peak temperatures (～840 °C) estimated in the extreme northwest of the area. The high‐temperature and relatively low‐pressure nature of metamorphism suggests high geothermal gradients existed during orogenesis, which in southern Madagascar is related to the amalgamation of Gondwana (580–520 Ma). Although metamorphic temperatures may have been augmented via thermal advection from the emplacement of the syn‐ to post‐tectonic Ambalavao suite, the high geothermal gradients nevertheless suggest thin and consequently hot lithosphere existed prior to orogenesis.     

Investigation into Factors Affecting Roadway Deformation in the Selby Coalfield

The introduction of roofbolting in the UK coal mining industry has been well documented and is an example of reinforcement design utilizing a design by measurement or observational approach. This has involved detailed monitoring of rock strata movements and rockbolt loads at a large number of sites. Analysis of roadway deformation monitoring information from across the Selby coalfield provided an ideal opportunity of assessing how geological and stress variations affect the stability of reinforced coal mine roadways. Statistical analysis of this data has confirmed the detrimental effects of maximum horizontal stress direction and relatively weak roof geology on the magnitude of roof deformation. Further analysis has led to the development of a roof lithology index for assessing the quality of the immediate roof geology and the use of geological hazard analysis for providing useful information for the development of a stability index for assessing support requirements of existing and future roadways. This investigation has also verified previous observations regarding mechanisms controlling roadway deformational behaviour and highlights the importance of the site-specific nature of reinforcement design.     

Data on the tectonic and metamorphic evolution of the central Sierra De Los Filabres,Betic Cordilleras,se Spain

Within the area investigated three tectonic units are distinguished which can be referred to the Nevado-Filabride, Ballabona-Cucharón, and Alpujarride complex, respectively. During the Alpine orogeny the rocks considered were subjected to various phases of folding and overthrusting. This tectonic evolution was accompanied by a metamorphism of a plurifacial character. The relation between tectonic events and metamorphic recrystallization is schematically outlined for each of the tectonic units distinguished. The units show marked differences in their degree of metamorphic recrystallization, caused by differences between the metamorphic conditions in each of the units during the earlier stages of metamorphism. The younger stages of metamorphism postdate important overthrust movements and have affected the whole pile of tectonic units. The Palaeozoic (and older?) rock sequences do not yield conclusive evidence of prealpine metamorphism, and definite proof of pre-alpine deformation is wanting. Consequently the difference in metamorphic grade between the Palaeozoic (and older?) and the Permo-Triassic rocks of the Alpujarride complex has to be explained by differences in metamorphism of Alpine age.