Lower riphean low-carbonaceous shales in the southern urals: Raw material for the manufacture of porous rubble

A property of swelling on heating to yield firm lightweight granules has first been revealed for lowcarbonaceous shales (LCS) from the Riphean stratotype in the Bashkirian Megaanticlinorium, Southern Urals. These granules possess all technological properties of “keramzite” or claydite (an artificial, expanded clayey material) and can successfully substitute this material. Moreover, the procedure of their manufacture, analogous to the manufacture of “shungizite” (an artificial carbonaceous-clayey material) from Lower Proterozoic clayey rocks of Karelia, is more economical than that for keramzit. Productive beds of the homogeneous LCS make up extended bodies tens of meters thick. At the present time, they can be used as cover rocks during the exploitation of the Bakal siderite deposits. The LCS represent fine-grained quartz-chlorite-sericite aggregates (with variable relationships between the major components), bearing fine-dispersed shungite in amounts of 0.5–1.0%. High-quality raw material of this kind is characterized by a fine-dispersed admixture of a mixed-layer clayey material bearing montmorillonite and vermiculite. Geological, lithological, mineralogical, and chemical prognostic criteria have been developed for the shungizite raw material. It has been concluded that this construction material, new for the Urals, is promising for industrial use     

Soil geochemistry of Mother Lode-type gold deposits in the Hodson mining district, central California, U.S.A.

The Hodson mining district is in the westernmost foothills of the Sierra Nevada in California, about 17 km west of the town of Angels Camp. This district is part of the West Gold Belt, which lies about 12–16 km west of, and generally parallel to, the better known Mother Lode Gold Belt in central California. The district produced several million dollars worth of Au between about 1890 and 1940.     

Fe-rich tholeiitic liquids and their cumulate products in the Pleasant Bay layered intrusion, coastal Maine

Fe-rich tholeiitic liquids are preserved as chilled pillows and as the chilled base of a 27 meter thick macrorhythmic layer in the Pleasant Bay mafic-silicic layered intrusion. The compositions of olivine (Fo₁) and plagioclase (An₁₃₋₈) in these extremely fine grained rocks suggest that they represent nearly end stage liquids that formed by fractionation of tholeiitic basalt. Their major element compositions (∼17.5 wt% FeO_T and 54 wt%SiO₂) closely resemble highly evolved glasses in the Loch Ba ring dike and some recent estimates of end-stage liquids related to the Skaergaard layered intrusion, and are consistent with recent experimental studies of tholeiite fractionation. Their trace element compositions are consistent with extensive earlier fractionation of plagioclase, olivine, clinopyroxene, ilmenite, magnetite and apatite. The mineral assemblage of the chilled rocks (olivine, clinopyroxene, quartz, ilmenite and magnetite), apatite saturation temperatures, and very low Fe³⁺/Fe²⁺indicate conditions of crystallization at temperatures of about 950 °C and f _{O 2} about two log units below FMQ. Cumulates that lie about 3 meters above the chilled base of the macrorhythmic layer contain cumulus plagioclase, olivine, clinopyroxene, ilmenite, apatite and zircon. This mineral assemblage and the Fe-Mg ratio in clinopyroxene cores suggest that this cumulate was in equilibrium with a liquid having a composition identical to that of the chilled margin which lies directly beneath it. The high FeO_T and low SiO₂ concentrations of this cumulate (23.3 and 45.8 wt%, respectively) are comparable to those in late stage cumulates of the Skaergaard and Kiglapait intrusions. This association of a chilled liquid and cumulate in the Pleasant Bay intrusion suggests that late stage liquids in tholeiitic layered intrusions may have been more SiO₂-rich than field-based models suggest and lends support to recent experimental studies of tholeiite fractionation at low f _O2 which indicate that saturation of an Fe-Ti oxide phase should cause FeO_T to decrease in the remaining liquid. Received: 17 January 1997 / Accepted: 10 June 1997     

Carbon,oxygen and sulphur isotope variations in concretions from the Upper Lias of N.E. England

Carbon, oxygen and sulphur isotope data for transects across two pyrite-bearmg carbonate concretions, and their host sediments, from the Upper Lias of N.E. England show symmetrical zonation. δ¹³C_PDB values of the calcite cement (?12.9 to ?15.4%.) indicate that most of it originated from organic matter by bacterial reduction of sulphate, augmented with marine and, to a lesser extent, fermentation derived carbonate. Organic carbon (δ¹³C_PDB = ?26.1 to ?37.0%.). reflects the admixture of allochtho-nous terrestrial organic matter with marine material and the selective preservation of isotopically light organic material through microbiological degradation.Two phases of pyrite are present in each concretion. The earlier framboidal pyrite formed throughout the sediment prior to concretionary growth and has δ³⁴S_CD values of ?22 to ?26%. indicating formation by open system sulphate reduction. The later euhedral phase is more abundant and reaches values of ? 2.5 to ? 5.5%. at concretion margins. This phase of sulphate reduction provided the carbonate source for concretionary growth and occurred in a partially closed system. The δ¹³C and δ³⁴S data are consistent with mineralogical and chemical evidence which suggest that both concretions formed close to the sediment surface. The δ₁₈O values of the calcite in one concretion (δ¹⁸O_PDB = 2.3 to ?4.8%.) indicate precipitation in pore waters whose temperature and isotopic composition was close to that of overlying seawater. The other concretion is isotopically much lighter (δ¹⁸O_PDB?8.9 to ?9.9%.) and large δ¹⁸O differences between concretions in closely-spaced horizons imply that local factors control the isotopic composition of pore waters.