Metabolism of perylene by monooxygenases of the skin and liver of Ambystoma tigrinum

The prevalence of dermal neoplasia among neotenic tiger salamanders (Ambystoma tigrinum) collected from the Reese Air Force Base sewage lagoon far exceeded that among salamanders from nearby uncontaminated lagoons. Perylene was the predominant pglycyclic aromatic hydrocarbon contaminant in this lagoon. Perylene was shown to be a substrate for monooxygenases in skin and liver homogenates and formed DNA-binding metabolites. Perylene exposure appeared to augment subsequent perylene metabolism by dermal enzymes but it was not a strong inducer of hepatic monooxygenases. Aroclor 1254 induced benzo(a)pyrene and perylene metabolism by both skin and liver enzymes. However, perylene apparently was not activated by salamander enzymes, as suggested by its lack of in vitro mutagenicity and failure to induce tumors.     

Evidence for gas accumulation associated with diapirism and gas hydrates at the head of the Cape Fear Slide

Single-channel seismic reflection profiles show evidence for areas of significant gas accumulation at the head of the Cape Fear Slide on the continental rise off North Carolina. Gas accumulation appears to occur beneath a gas hydrate seal in landward-dipping strata and in domed strata associated with diapirism. In addition, gas venting may have occurred near diapirs located at the head of the slide.     

Vibrations of a simply supported plate carrying an elastically mounted concentrated mass

A large number of papers and technical reports are available on the technically important problem of structural elements executing transverse vibrations and carrying concentrated masses. In general it is assumed that the attachment is perfectly rigid. On the other hand, a rather limited amount of published work is available when the mass is elastically connected to the structure. The system then exhibits a more complex behavior than in the case of rigid attachment. The present study deals with the solution of the title problem using the well-known normal mode, sinusoidal eigenfunction expansions.     

Validation of a finite difference method for the simulation of vortex-induced vibrations on a circular cylinder

The Karman Vortex Street generated by a circular cylinder is investigated by the numerical solution of the compressible Navier–Stokes equations in the incompressible Mach number range (Mach<0.3) using the Beam and Warming implicit scheme. The agreement with the fully incompressible projection method (Chorin, 1968) is fairly good while convergence time is very much better. The investigation suggests that the compressible Navier–Stokes equations may be used as an efficient alternative to study incompressible flows as well. Mach numbers just below 0.3 are enough to simulate incompressible flow behavior and at the same time do not cause numerical ill-conditioning in the solution. In addition, some relevant features of the vortices generated and carried by the wake of the cylinder could be fairly well captured.     

Benthic mineralization rates at two locations in the southern North Sea

Benthic oxygen uptake, sulphate reduction and benthic bacterial production were measured at two contrasting locations in the southern North Sea: the shallow and turbulent Broad Fourteens area in the Southern Bight, and the deeper Oyster Grounds, a deposition area, where thermohaline stratification occurs during summer. Oxygen uptake and sulphate reduction showed a clear seasonal pattern in the Broad Fourteens area, indicating a supply of carbon to the benthic system that is closely related to the standing stock of carbon in the water column. This close benthic-pelagic coupling is probably due to the influence of the tide in this part of the North Sea, which keeps the water column permanently mixed. At the Oyster Grounds, no seasonal pattern was observed. Peaks in oxygen uptake and sulphate reduction were found in winter. Irregularly occurring events, such as storms and fishery-related activities, are likely to affect the benthic mineralization patterns in this area. Annual benthic carbon mineralization rates estimated from oxygen uptake rates were 44 gC·m⁻² at the Broad Fourteens, and 131 gC·m⁻² at the Oyster Grounds, of which 26 and 28%, respectively, could be attributed to sulphate reduction (assuming an annual sulphide reoxidation rate of 100%). Although sulphate reduction rates in the southern North Sea are higher than previously suggested, aerobic respiration is the most important pathway for benthic carbon mineralization at the stations visited. Production rates of benthic bacterial carbon measured with labelled leucine were much higher than carbon mineralization rates based on oxygen uptake or sulphate reduction. This may either imply a very high bacterial carbon conversion efficiency, or point to shortcomings in the accuracy of the techniques. A critical evaluation of the techniques is recommended.     

Weakly non-linear free oscillations in a basin of variable depth

Weakly non-linear free oscillations in a basin of variable depth filled with non-viscous fluid are investigated in terms of the long waves theory using the perturbation technique. Solutions to the initial two approximations for the horizontal velocity component and free surface departure are numerically derived. An attempt is made to determine the area of applicability of the linear theory by applying a parabolic bottom profile to the basin.Translated by V. Puchkin.     

The role of marine spatial planning in sea use management: The Belgian case

The expansion of offshore activities and the increasing need to meet international and national commitments to biodiversity conservation have led to an enhanced interest in marine spatial planning (MSP) as a tool for sea use management. Several European countries, on their own initiative or driven by European legislation and policy, have taken global leadership in implementing MSP. This article will discuss the Belgian experiences with MSP. It will give a short historical overview based on legal developments and review the implementation process of a ‘Master Plan’ as a spatial management policy for the Belgian Part of the North Sea. Additionally, this article will reflect on the research that has been done in Belgium to apply a land-use planning approach to the marine environment. The MSP process in Belgium shows that a spatial approach to sea use management is possible despite the lack of a legal zoning framework. However, it concludes that a legal basis for MSP, in addition to the current permit system, would provide a more strategic and integrated framework for ecosystem-based, sea use management.     

Field observations of waves generated by passing ships: A note

This short contribution reports the results of a field study on the nearshore characteristics of waves generated by both conventional and high speed passenger ferries. The field observations took place in the late summer of 2005, at a beach close to the port of Mytilene (Island of Lesbos, Greece), and involved the visual observation of ship waves, using digital video recordings and image processing techniques. The results showed that passage of the fast ferry was associated with a longer, more complex and energetic nearshore event; this event not only did include higher nearshore waves (up to 0.74 m) and was organised in different wave packets, but it was also an order of magnitude longer (∼ 680 s) than the conventional ferry event. Regarding the effects on beach sediment dynamics, the fast ferry waves were estimated to be very efficient in mobilising the nearshore sediments in contrast to those of the conventional ferry. The fast ferry service appears to generate daily prolonged nearshore events, which contain waves with higher energy than those expected from the normal summer wind wave regime of the area; these events also include some high and very steep waves, which can be particularly erosive. Therefore, fast ferry wakes may have considerable impacts on the seasonal beach sediment dynamics/morphodynamics and the nearshore benthic ecology, as well as they may pose significant risks to bathers, affecting the recreational use of the beaches exposed to fast ferry traffic. Finally, the study has shown that satisfactory field observations of the nearshore characteristics of ship-generated (and wind) waves can be obtained using inshore deployments of calibrated poles, digital video cameras and appropriate image processing algorithms.     

Spatial and temporal variability of the ratios between the nitrate and phosphate concentrations in the Sea of Okhotsk

The relation between the nitrate and phosphate concentrations in the Sea of Okhotsk and the bordering waters of the Pacific Ocean were studied. The surveys were carried out in the autumn, spring, and summer of 2001–2002. For the deepwater part of the sea, the relation [NO^? ₃] = ((14.88 ± 0.07) × [PO^3? ₄] ? 5.46 ± 0.17) was found. The coefficients in the equation given are statistically different from those in the similar equation for the Pacific waters: [NO^? ₃] = (16.05 ± 0.15) × [PO^3? ₄]-(7.23 ± 0.36). In the northern part of the sea; on the shelf; in the slope area; and, especially, in the deep waters of the TINRO Depression, the linear dependence between the phosphate and nitrate concentrations was distorted. This feature was described in terms of nitrate deficiency. The maximum values of this deficiency were found in the near-bottom waters. The principal processes that might cause the nitrate deficiency were considered: the difference in the oxidation rates of the nitrogen and phosphorus organic compounds, the matter transfer between the continent and the sea, the different efficiency of the biogenic burial of nitrogen and phosphorus in the bottom sediments, and the denitrification in the upper layer of the bottom sediments. It was shown that the most probable cause of the nitrate deficiency was the denitrification. The loss of inorganic nitrogen owing to the supply of the waters of the Sea of Okhotsk to the Pacific Ocean was estimated as ～2.5 × 10¹¹ mol N/year.     

Photochemical models of the atmosphere and their application in ozonosphere and climate studies: A review

This review is devoted to problems in the photochemical modeling of atmospheric processes. The physicochemical and mathematical foundations underlying the construction of photochemical models are described, a classification of the atmospheric reactions is presented, and the features of photochemical modeling are considered under various irradiance conditions for various atmospheric layers and geographical regions. Atmospheric processes that are important to photochemical models are discussed. Applications involving photochemical models are outlined. Some results are presented to illustrate the capabilities of photochemical models. Special attention is given to relatively recent directions in photochemical modeling, such as data assimilation and inverse problems. The review can be used by experts in areas related to atmospheric chemistry as a basic source of knowledge on the subject and for the development of photochemical modules for atmospheric models.