Simulation Of Salt-Water Encroachment In A Multi-Layer Groundwater System,Bangkok, Thailand

Salt-water encroachment in the multi-layer groundwater system underlying the Bangkok metropolitan area was simulated with a quasi-three-dimensional flow and solute-transport model. The quasi-three-dimensional model used in this study is based on the model SUTRA. Accurate conceptualization of the initial state of the system with regard to the distribution of salt-water concentration is very important for modeling, especially in areas where localized zones of high salt concentration exist in the groundwater. Data adequacy and model results were evaluated by a geostatistical analysis. The model is capable of simulating the regional trend of potentiometric levels and salt concentration. However, lack of monitoring data in areas where localized zones of high salt concentration exist resulted in large model residuals. RÉSUMÉ: L'empiétement des eaux salées dans le système hydrologique multi-couche sous-jacent la zone métropolitaine de Bangkok a été simulé à l'aide d'un modèle quasi-tridimensionnel représentant l'écoulement des eaux et le transport d'éléments en solution. Le modèle quasi-tridimensionnel utilisé dans cette étude est basé sur le modèle SUTRA. Une conceptualisation exacte de l'état initial du système en ce qui concerne la répartition de la concentration des eaux salines est très important, particulièrement dans les endroits localisés où l'eau souterraine presente une forte concentration en sel. La qualité des donnés et des résultats a été estimée à l'aide d'une analyse géostatistique. Le modèle est capable de simuler la tendance régionale des niveaux potentiométriques et de la concentration en sel. Cependant, le manque de données de contrôle dans les endroits à forte concentration a donné lieu à des résiduels importants. RESUMEN: La intrusión de agua salina en el sistema multicapa bajo el área metropolitana de Bangkok se simuló mediante un modelo de flujo y transporte de solutos casi-tridimensional, basado en el modelo SUTRA. La conceptualizacián precisa de la distribución inicial de concentraciones de agua salina es muy importante para el modelo, especialmente en áreas donde existen zonas locales de alta concentración salina en el agua subterránea. La exactitud de los datos y del modelo se evaluaron mediante un análisis geoestadístico. El modelo permite simular la tendencia regional de los niveles piezométricos y la concentración de sales. Sin embargo, la falta de datos de muestreo en las zonas locales de alta salinidad resultaron en valores altos de los residuos calculados por el modelo.     

Influence of the spatial resolution of satellite-derived vegetation parameters on the biogenic Volatile Organic Compounds (VOC) emission modeling

Vegetation is a natural source of Volatile Organic Compounds (VOC) that plays an important role in atmospheric chemistry. The main objective of the current study is to implement a model to quantify process-based VOC emissions from plants that focuses on the relationship between the sensitivity of VOC emission estimates to spatial resolution data, based on scientific knowledge and vegetation dynamics derived from satellite observations. The Normalized Difference Vegetation Index (NDVI) and Leaf Area Index (LAI) were elected to examine this issue using different resolutions of satellite-derived products: 22m from the DEIMOS-1 satellite, and 250m and 1000m provided by MODIS. The study is focused on an area of 80×80km² in Portugal for 2011. Detailed land cover and meteorological data are also included in the emission quantification algorithm. The primary outcomes were determined using a multi-scale analysis showing spatial and temporal variations in the vegetation parameters and modeling results. The results confirm that the emissions model is highly sensitive to the spatial resolution of the satellite-derived data, resulting in about a 30% difference in total isoprene emissions for the study area.     

Mobility of rare earth elements in the system soils–plants–groundwaters: a case study of an arid area (Oman)

Groundwater samples from six wells and various species of plants from soils developed on ophiolites were collected from an arid area (AlKhod area, Oman) and analyzed for trace elements including rare earth elements (REEs). The distribution patterns of REEs in plants indicated an enrichment in middle REEs (MREEs?=?Sm to Dy) and heavy REEs (HREEs?=?Ho to Lu), when they are normalized to the REE composition of the Post Archean Australian Shale (PAAS), with a significant negative anomaly in Ce and a positive anomaly in Eu. Compared to Oman ophiolites, the REEs in different species of plants are depleted in Ce and enriched in MREEs and slightly enriched in light REE (LREE?=?from La to Nd). Relative to PAAS, the distribution of REEs in groundwaters revealed similar patterns to the REE distribution in plants. The distribution patterns of REEs in plants relative to those in waters are nearly flat. These patterns suggest that the transfer of REEs from soil solutions to the groundwaters in Oman occurs without any significant fractionation.     

Patterns of Nd and Sr isotopic ratios produced by magmatic and post-magmatic processes in the Shiant Isles Main Sill, Scotland

The Shiant Isles Main Sill of the British Tertiary Igneous Province is a classic example of a differentiated, alkaline basic sill. Four separate intrusions, each emplaced internally in rapid succession, form a 165-m-thick sill hosted by Lower Jurassic sedimentary rocks. Extensive Nd and Sr isotopic studies were conducted on samples from a vertical section through the sill where the relationships of samples to one another are well defined. The results illuminate patterns of modification of isotopic ratios and clarify the petrogenesis (magma sources, crustal contamination), magmatic processes (bulk mixing, interstitial liquid mixing), and post-magmatic alteration (hydrothermal effects on Sr and Nd). Overall, the whole-rock initial ⁸⁷Sr/⁸⁶Sr ratios range from ∼0.7037 to 0.7061 while initial ¹⁴³Nd/¹⁴⁴Nd ratios vary from ∼0.51243 to 0.51286 (ɛ_Nd∼−0.7 to +5.7) – values that contrast markedly with those of the country rock. Acid leaching (HCl) of the whole-rock samples that removes analcime indicates that most of the scatter in the ⁸⁷Sr/⁸⁶Sr is caused by the ubiquitous sub-solidus, aqueous alteration during which more-radiogenic Sr was introduced into the sill, especially along the margins, and also reveals magmatic isotopic ratios. In contrast, Nd was immobile during fluid interaction so that the sill ¹⁴³Nd/¹⁴⁴Nd ratios were not affected, even <1 m from the country-rock contact. Using leached rock values, ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd ratios are inversely correlated from magmatic processes. Magmas with two distinct isotopic compositions were involved: a more primitive one with ¹⁴³Nd/¹⁴⁴Nd ∼0.51285 and ⁸⁷Sr/⁸⁶Sr ∼0.7035 that produced the first two intrusions and a more evolved one (with 0.51252 and 0.7048) that produced the third intrusion. Mixing of the two magmas was very limited, restricted to near contacts between units, and apparently occurred by interstitial melt migration. The more evolved crinanitic magma was probably produced from a batch of the more primitive picritic melt by a small degree of crustal contamination and crystal fractionation during a short crustal residence prior to ascent and emplacement. Received: 20 December 1999 / Accepted: 5 May 2000     

Flory-Huggins' formulation,its validity and implications in retrieval of equilibrium temperature of binary and ternary systems at higher pressures,using liquid silicate data and 1 bar liquidus temperature

For a pure phase at equilibrium with a polycomponent melt, two sets of expressions can be derived; one expressing its activity as a function of enthalpy, entropy, heat capacity and temperature, and the other by coupling a Flory-Huggins' polymerisation model with the van Laar heat of mixing term. Interaction parameters for binary and ternary systems have been computed at 1 bar by equating these two expressions. Assuming the interaction parameter to be independent of temperature, equilibrium temperatures at higher pressures can be calculated by an iterative procedure. Such retrieval calculations were carried out in simple eutectic, volatile-free systems like CaAl₂Si₂O₈-CaMgSi₂O₆, Mg₂SiO₄-TiO₂, MgSiO₃-TiO₂, Mg₂SiO₄-CaMgSi₂O₆, NaAlSi₃O₈-SiO₂ and CaAl₂Si₂O₈-CaMgSi₂O₆-Mg₂SiO₄. The close agreement between the theoretically retrieved and the experimentally determined equilibrium temperatures testifies to the validity of the model at higher pressures. The successful application of the model to simple eutectic, binary and ternary systems involving vastly dissimilar phases without imposing added constraints implies that it can be possibly extended to hitherto unknown systems provided the thermodynamic parameters of the phases involved are known.     

四川盆地碳酸盐岩油气勘探实践与认识

四川盆地烃源十分丰富。但油气演化程度高,大多已进入高成熟和过成熟阶段,至今只在侏罗系发现有油藏,三叠系及其更老地层皆为气藏。储层主要为碳酸盐岩,其特点是低孔低渗,平均孔隙度仅1.7%,平均渗透率小于1×10~(-3)μm~2,但其中的“孔洞发育层段”平均孔隙度可达3%～6%。根据四十年的勘探经验,加强预探并争取新发现是四川盆地油气勘探发展的关键。预探中,按构造带规划大中型气田勘探目标,将成藏条件相似、地域上相邻的局部圈闭群作为一个整体勘探对象,实行稀井广探,少井高效。“八五”以来,在高陡构造带勘探技术、储层横向预探技术等方面有长足的进步,勘探成效不断提高,实现了资源序列的良性循环。     

Vague cognitive regions in geography and geographic information science

Cognitive regions are regions in the mind, reflecting informal ways individuals and cultural groups organize their understanding of earth landscapes. Cognitive region boundaries are typically substantially vague and their membership functions are substantially variable – the transition from outside to inside the region is imprecise or vague, and different places within the region are not equally strong or clear as exemplars of the region. Methods for assessing and cartographically depicting cognitive regions, as with other vague geographic regions, have traditionally implied an inappropriate level of boundary sharpness and membership uniformity, such as when boundaries are mapped as precise lines. Research in recent decades has explored methods for assessing and depicting boundary vagueness and membership variability, either within or across individuals, but has still assumed homogeneity and regularity in the vagueness and variability. In this article, we present two studies that assess the cognitive regions of ‘Northern’ and ‘Southern’ California, and, for comparison, ‘Northern’ and ‘Southern’ Alberta. The first study uses a standard boundary-drawing task; the second uses a novel task in which participants rate cells of a high-resolution grid laid over an outline map. This technique allows us to assess and depict vagueness and nonuniformity that is heterogeneous and irregular across different areas. Differences in the conceptualization of ‘Northern’ and ‘Southern’ regions in California, as compared to those in Alberta, point to thematic influences on cognitive regions in California but not in Alberta. As is often true with cognitive regions, Northern and Southern California are about attitude, not just latitude.     

On the Attractive Force of an Elliptical Gaussian Ring

Solar System Research - A numerical-analytical method for analyzing the orbital evolution of a planetary satellite under the influence of a perturbing body moving in an elliptical orbit is...