基于DEA_Malmquist的河北省县级粮食生产效率评价

运用DEA模型结合Malmquist指数,从粮食生产"全要素效率"、"技术效率"、"技术进步效率"、"纯技术效率"和"规模效率"5方面对河北省138个县粮食生产效率进行了实证分析.结果表明:1)研究期内河北省粮食生产效率提升很快,各项粮食生产效率相关程度较高,"技术效率"对粮食生产"全要素效率"影响较大,"规模效率"对"技术效率"存在一定影响,其相关系数分别为0.59、0.72.2)省域范围内粮食生产效率空间分布趋势明显,"全要素效率"在东西方向上呈倒"U"型分布趋势,"技术效率"呈一阶分布趋势.3)研究区内138个县粮食生产效率空间分布差异显著,"全要素效率"优势区主要分布在石家庄、衡水等中东部地区,非优势区主要分布在北部地区.河北省未来粮食生产应通过提高农业科技发展水平、增加农民收入、进行有序有效的土地整理等措施,提高粮食生产效率,保证区域粮食安全.     

Decomposition of algal lipids in clay-enriched marine sediment under oxic and anoxic conditions

A series of laboratory incubation experiments were conducted to examine the decomposition of algal organic matter in clay-enriched marine sediment under oxic and anoxic conditions. During the 245-day incubation period, changes in the concentrations of TOC, major algal fatty acid components (14:0, 16:0, 16:1, 18:1 and 20:5), and n-alkanes (C₁₆–C₂₃) were quantified in the samples. Our results indicate that the organic matters were degraded more rapidly in oxic than anoxic conditions. Adsorption of fatty acids onto clay minerals was a rapid and reversible process. Using a simple G model, we calculated the decomposition rate constants for TOC, n-alkanes and fatty acids which ranged from 0.017–0.024 d⁻¹, 0.049–0.103 d⁻¹ and 0.011 to 0.069 d⁻¹, respectively. Algal organic matter degraded in two stages characterized by a fast and a slow degradation processes. The addition of clay minerals montmorillonite and kaolinite to the sediments showed significant influence affecting the decomposition processes of algal TOC and fatty acids by adsorption and incorporation of the compounds with clay particles. Adsorption/association of fatty acids by clay minerals was rapid but appeared to be a slow reversible process. In addition to the sediment redox and clay influence, the structure of the compounds also played important roles in affecting their degradation dynamic in sediments.     

Assimilation of ASAR data with a hydrologic and semi-empirical backscattering coupled model to estimate soil moisture

The most promising approach for studying soil moisture is the assimilation of observation data and computational modeling.However,there is much uncertainty in the assimilation process,which affects the assimilation results.This research developed a one-dimensional soil moisture assimilation scheme based on the Ensemble Kalman Filter(EnKF)and Genetic Algorithm(GA).A two-dimensional hydrologic model-Distributed Hydrology-Soil-Vegetation Model(DHSVM)was coupled with a semi-empirical backscattering model(Oh).The Advanced Synthetic Apertture Radar(ASAR)data were assimilated with this coupled model and the field observation data were used to validate this scheme in the soil moisture assimilation experiment.In order to improve the assimilation results,a cost function was set up based on the distance between the simulated backscattering coefficient from the coupled model and the observed backscattering coefficient from ASAR.The EnKF and GA were used to re-initialize and re-parameterize the simulation process,respectively.The assimilation results were compared with the free-run simulations from hydrologic model and the field observation data.The results obtained indicate that this assimilation scheme is practical and it can improve the accuracy of soil moisture estimation significantly.     

塔里木盆地巴麦地区石炭系低速异常碳酸盐岩的解释

巴麦地区即塔西南巴楚隆起-麦盖提斜坡,具有台地边缘-斜坡的古构造和古地理背景,这种台地边缘和典型的浅滩沉积暗示了该区具有发育生物礁的环境特征。区内先巴扎（XBZ）600 km²三维地震探区石炭系发育了巴楚组（C₁b）生屑灰岩及标准灰岩、小海子组（C₂x）3套灰岩,其中小海子组发现特殊响应碳酸盐岩,主要表现为厚度增大、频率增高、多出一条波峰同相轴的地震响应特征。通过差异厚度法、底面拉平法、地震属性法、正反演模型法,结合野外露头、岩心、镜下观察、录井、沉积相等综合分析,可初步推测该低速异常体为厚度增加、孔隙度增大的近东西向台地边缘障壁礁所致。礁体东西走向延伸超过25 km,礁核区小海子组灰岩最厚62 m,礁外的小海子组50 m。台缘斜坡南倾,坡度陡,水平宽度1~2 km。礁后生屑滩北倾,坡度缓,水平宽度3~6 km。受色力布亚断裂带遮挡,该生物礁储层可以形成有利圈闭,面积约为42 km²,厚约45 m。     

南水北调西线TBM掘进下隧洞围岩损伤研究

为研究隧洞掘进机（tunnel boring machine,TBM）掘进下隧洞围岩的损伤特征,选取南水北调西线工程为背景工程,针对隧洞围岩TBM掘进后的损伤进行了系统的研究与分析。根据板岩在室内试验中表现出来的脆性和屈服后强度特性,提出了以黏聚力弱化-摩擦角强化（cohesion weakening and frictional strengthening,CWFS）脆性模型为基础考虑岩体屈服后损伤的本构模型,通过VC++编译dll动态链接库,并将其植入FLAC3D程序中。应用神经网络和遗传方法等优化算法对本构模型中的参数进行了反演分析,并以室内三轴压缩试验为依据,对该本构模型进行了验证。结果表明,提出的考虑损伤的CWFS模型可以较好地反映板岩的弹性特征、屈服后的强化特征、脆性破坏特征和破坏后残余强度特征。以该模型为基础,模拟了南水北调西线隧洞在TBM掘进条件下隧洞围岩的变形特性、应力发展规律及其损伤演化特征,并与基于Mohr-Coulomb本构关系的计算结果进行了对比分析。提出的考虑损伤的CWFS模型能更好地反映隧洞掘进后围岩损伤特征,即损伤沿着弱势区域发展的规律     

我国原位地应力测量与地应力场分析研究进展

随着我国交通、能源和水利水电等行业快速发展,在复杂地形地貌和地质条件下兴建大量岩土工程,尤其是深埋长隧道,原位地应力测量及其相关研究逾加重要。我国自20世纪60年代首次成功进行原位地应力实测以来,在地应力测量及相关研究方面已取得了长足进展。文中扼要介绍了我国地应力测量的发展历程,着重总结了在钻孔应力解除法、水压致裂法和其他常用原位地应力测量法及工程区初始地应力场分析研究方面所取得的进展,并结合我国区域构造应力环境和岩土工程的特点,对地应力测量和工程区初始地应力场研究方面的展望阐述了一点认识。     

Removal of Ni(II) from Aqueous Solutions by Nanoscale Magnetite

Magnetite nanoparticles were applied to remove Ni(II) from aqueous solutions as a function of pH, contact time, supporting electrolyte concentration, and analytical initial Ni(II) concentration. The highly crystalline nature of the magnetite structure with diameter of around 10 nm was characterized with transmission electron microscopy (TEM) and X‐ray diffractometry (XRD). The surface area was determined to be 115.3 m²/g. Surface chemical properties of magnetite at 25°C in aqueous suspensions were investigated. The point of zero charge (pHzpc) was found to be 7.33 and the intrinsic acidity constants (${\rm p}K_{{\rm a}1}^{{\rm s}} $ and ${\rm p}K_{{\rm a}2}^{{\rm s}} $ ) were found to be 9.3 and 5.9, respectively. The surface functional groups were investigated with Fourier transform‐infrared spectroscopy (FTIR) as well. Batch experiments were carried out to determine the adsorption kinetics and mechanism of Ni(II) by these magnetite nanoparticles. The adsorption process was found to be pH dependent. In NaCl solutions, Ni(II) adsorption increased with increasing ionic strength while in NaClO₄ solutions, Ni(II) adsorption exhibited little dependence on the ionic strength of the solution. The adsorption process better followed the pseudo‐second order equation and Freundlich isotherm.     

一种修正的Drucker-Prager屈服准则

Drucker-Prager（以下简称D-P）屈服准则因其形式简单、物理意义明确而得到广泛的应用,然而经过多年的应用和研究,其缺点逐渐显现出来,如拉剪区偏大、不具有应力角效应等,针对这些不足,提出了修正的D-P屈服准则。在拉剪区用圆球面和横截面的组合方式代替原来的圆锥面,从而不改变D-P屈服准则压剪区的形式,在考虑岩石实际的拉伸强度的同时,也满足该屈服准则经过单轴抗拉强度点的条件;为考虑岩石在三轴压缩和三轴拉伸状态下不同的强度特性,即应力角效应,引入了一种角隅模型;为保证屈服准则始终通过岩石的单轴抗压强度点,建议了一种材料参数k值的取值方法。为验证屈服准则修正后的适用性和正确性,将修正屈服准则与真三轴试验结果进行了拟合,同时与Mohr-Coulomb（以下简称M-C）准则进行对比,结果表明,修正屈服准则可以很好地描述试验现象,且比M-C准则更接近真实结果。     

基于节理网络有限元的柱状节理岩体等效变形模量结构效应研究

因其特殊的地质成因,柱状节理成为一种具有强烈非连续性及各向异性的特殊岩体结构。以白鹤滩水电工程设计、建设中所遇到的柱状节理玄武岩体为背景,针对柱状节理岩体的等效变形模量问题,在探讨了其结构效应表征参数的基础上,利用节理网络有限元为工具,研究各结构效应表征参数对柱状节理岩体等效变形模量的影响。研究结果表明：在柱轴线横向平面上,对于柱体不规则程度,当柱体完全不规则相对于完全规则情况,等效模量提高大约10%左右;在其他条件不变情况下,当柱体平均边长从0.1 m增加至0.5 m时,等效模量从5.36 GPa增加至23.4 GPa;对不同加载方向的研究结果表明,柱状节理在柱轴横向平面上可以视作各向同性;当节理刚度线性递增时,相应的岩体等效模量也基本符合线性递增的规律。在平行柱体轴线平面,节理组2间距越大,柱状节理岩体的等效变形模量越大;随着错距比的增加,柱状节理岩体的等效变形模量呈现先增加后减少的趋势,当错距比为50%时,节理岩体的等效变形模量取最大值;对于节理刚度的影响,与柱轴横向平面类似的,随柱体轴线平面上节理刚度的线性增加,相应的岩体模量也基本符合线性递增的规律。该研究成果与已有的现场研究成果及三维数值模型成果相比,吻合良好。说明了文中提供的研究结论具有较好的可信度及参考价值。     

基体差异对电感耦合等离子体质谱法测定过程中Ba氧化物产率的影响及其对Eu测定结果校正的研究

电感耦合等离子体质谱（ICP-MS） 测定地质样品中稀土元素的过程中,尤其对于高Ba基体的地质样品,由Ba形成 的氧化物和氢氧化物离子对Eu元素会产生质谱峰的重叠干扰,严重影响Eu测定结果的准确度和精确度。通过标准溶液的 条件实验,测定Ba干扰项相对Ba总量的比例（干扰率） 并进行相应的Eu扣除,是一种解决干扰导致Eu测定结果偏高的思 路。然而该干扰率在不同基质溶液中是否一致,且随着Ba含量变化是否稳定目前尚不明确。本文通过对不同基体溶液中Ba 对Eu干扰率的测定（低分辨模式测定）,发现随着溶液中Ba浓度的变化,同一基体溶液中该干扰率较为恒定,而不同基体 溶液中干扰率有明显的差别。这说明在对Eu测定结果进行干扰扣除时,需要利用匹配的基体溶液来获取准确的Ba干扰 率。应用这种方法扣除得到的Eu结果与质谱的高分辨模式（R=10000） 下的测定结果较为一致,数据的重现性也较为理 想。因此,利用基体匹配的方式来进行Ba对Eu的数学扣除是一种可行的方法。