Trend analysis using discrete wavelet transform (DWT) for long-term precipitation (1851–2006) over India

This study is an attempt to determine the trends in monthly, annual and monsoon total precipitation series over India by applying linear regression, the Mann-Kendall (MK) test and discrete wavelet transform (DWT). The linear regression test was applied on five consecutive classical 30-year climate periods and a long-term precipitation series (1851–2006) to detect changes. The sequential Mann-Kendall (SQMK) test was applied to identify the temporal variation in trend. Wavelet transform is a relatively new tool for trend analysis in hydrology. Comparison studies were carried out between decomposed series by DWT and original series. Furthermore, visualization of extreme and contributing events was carried out using the wavelet spectrum at different threshold values. The results showed that there are significant positive trends for annual and monsoon precipitation series in North Mountainous India (zone NMI) and North East India (NEI), whereas negative trends were detected when considering India as whole.

EDITOR A. Castellarin ASSOCIATE EDITOR S. Kanae     

Textural characteristics,distribution pattern and provenance of heavy minerals in glacial sediments of Schirmacher Oasis,east Antarctica

Heavy minerals of twenty sediment samples, belonging to polar ice sheet, lake, mainland area and shelf region of Schirmacher Oasis, east Antarctica, have been studied for their textural characteristics, abundance and provenance determination. The heavy crop is represented by zircon, tourmaline, rutile, garnet, hypersthene, hornblende, chlorite, enstatite, lawsonite, kyanite, sillimanite, zoisite, andalusite, spinel, topaz and opaques. The assemblage, in general, is dominated by hornblende-hypersthene-garnet assemblage, followed by kyanite-sillimanite-andalusite and zircontourmaline-rutile. The high concentration of specific minerals of metamorphic origin reveals high-grade metamorphic terrain as the primary source. The ZTR ratio is low showing low mineralogical maturity. An attempt has also been made to compare the trends of heavy minerals of various sub glacial regions with those of the average values of entire area.     

Electrochemical interaction of Shewanella oneidensis MR-1 and its outer membrane cytochromes OmcA and MtrC with hematite electrodes

Bacterial metal reduction is an important biogeochemical process in anaerobic environments. An understanding of electron transfer pathways from dissimilatory metal-reducing bacteria (DMRB) to solid phase metal (hydr)oxides is important for understanding metal redox cycling in soils and sediments, for utilizing DMRB in bioremedation, and for developing technologies such as microbial fuel cells. Here we hypothesize that the outer membrane cytochromes OmcA and MtrC from Shewanella oneidensis MR-1 are the only terminal reductases capable of direct electron transfer to a hematite working electrode. Cyclic voltammetry (CV) was used to study electron transfer between hematite electrodes and protein films, S. oneidensis MR-1 wild-type cell suspensions, and cytochrome deletion mutants. After controlling for hematite electrode dissolution at negative potential, the midpoint potentials of adsorbed OmcA and MtrC were measured (−201 mV and −163 mV vs. Ag/AgCl, respectively). Cell suspensions of wild-type MR-1, deletion mutants deficient in OmcA (ΔomcA), MtrC (ΔmtrC), and both OmcA and MtrC (ΔmtrC–ΔomcA) were also studied; voltammograms for ΔmtrC–ΔomcA were indistinguishable from the control. When the control was subtracted from the single deletion mutant voltammograms, redox peaks were consistent with the present cytochrome (i.e., ΔomcA consistent with MtrC and ΔmtrC consistent with OmcA). The results indicate that OmcA and MtrC are capable of direct electron exchange with hematite electrodes, consistent with a role as terminal reductases in the S. oneidensis MR-1 anaerobic respiratory pathway involving ferric minerals. There was no evidence for other terminal reductases operating under the conditions investigated. A Marcus-based approach to electron transfer kinetics indicated that the rate constant for electron transfer k_et varies from 0.025 s⁻¹ in the absence of a barrier to 63.5 s⁻¹ with a 0.2 eV barrier.     

Evaluating the performance of climate models in reproducing the hydrological characteristics of rainfall events

ABSTRACT

Rainfall events largely control hydrological processes occurring on and in the ground, but the performance of climate models in reproducing rainfall events has not been investigated enough to guide selection among the models when making hydrological projections. We proposed to compare the durations, intensities, and pause periods, as well as depths of rainfall events when assessing the accuracy of general circulation models (GCMs) in reproducing the hydrological characteristics of observed rainfall. We also compared the sizes of design storm events and the frequency and severity of drought to demonstrate the consequences of GCM selection. The results show that rainfall and extreme hydrological event projections could significantly vary depending on climate model selection and weather stations, suggesting the need for a careful and comprehensive evaluation of GCM in the hydrological analysis of climate change. The proposed methods are expected to help to improve the accuracy of future hydrological projections for water resources planning.     

Latitudinal trends in morphological characteristics of <Emphasis Type="Italic">Neogloboquadrina pachyderma</Emphasis> (Ehrenberg) along a north–south transect in the south-western Indian Ocean

A total of 25 surficial sediment samples (Peterson grab, gravity and piston cores), collected during the Pilot Expedition to Southern Ocean (PESO) 2004 cruises 199C and 200 onboard the ORV Sagar Kanya along a N–S transect between 9.69°N and 55.01°S, and 80 and 40°E in the Indian Ocean sector of the Southern Ocean (SW Indian Ocean), have been investigated for various morphological features—test size, mean proloculus size and coiling direction (dextral/sinistral forms)—of the planktic indicator species Neogloboquadrina pachyderma (Ehrenberg). The results show that the coiling directions co-vary with temperature and salinity, the abundances of sinistrally coiled forms increasing towards higher latitudes (south of 40°S), whereas dextrally coiled forms show a reverse trend. Similarly, overall test and proloculus sizes depend largely on the physicochemical properties (salinity, temperature, nutrients, calcium saturation) of the ambient water masses. These observations suggest that, particularly at the boundaries between different water masses, variations in morphological features of N. pachyderma can meaningfully be used to reconstruct paleoceanographic conditions from Indian Ocean sediments.     

Laboratory experiments of Titan tholin formed in cold plasma at various pressures: implications for nitrogen-containing polycyclic aromatic compounds in Titan haze

Titan, the largest satellite of Saturn, has a thick nitrogen/methane atmosphere with a thick global organic haze. A laboratory analogue of Titan's haze, called tholin, was formed in an inductively coupled plasma from nitrogen/methane=90/10 gas mixture at various pressures ranging from 13 to 2300 Pa. Chemical and optical properties of the resulting tholin depend on the deposition pressure in cold plasma. Structural analyses by IR and UV/VIS spectroscopy, microprobe laser desorption/ionization mass spectrometry, and Raman spectroscopy suggest that larger amounts of aromatic ring structures with larger cluster size are formed at lower pressures (13 and 26 Pa) than at higher pressures (160 and 2300 Pa). Nitrogen is more likely to incorporate into carbon networks in tholins formed at lower pressures, while nitrogen is bonded as terminal groups at higher pressures. Elemental analysis reveals that the carbon/nitrogen ratio in tholins increases from 1.5-2 at lower pressures to 3 at 2300 Pa. The increase in the aromatic compounds and the decrease in C/N ratio in tholin formed at low pressures indicate the presence of the nitrogen-containing polycyclic aromatic compounds in tholin formed at low pressures. Tholin formed at high pressure (2300 Pa) consists of a polymer-like branched chain structure terminated with CH₃, NH₂, and CN with few aromatic compounds. Reddish-brown tholin films formed at low pressures (13-26 Pa) shows stronger absorptions (almost 10 times larger k-value) in the UV/VIS range than the yellowish tholin films formed at high pressures (160 and 2300 Pa). The tholins formed at low pressures may be better representations of Titan's haze than those formed at high pressures, because the optical properties of tholin formed at low pressures agree well with that of Khare et al. (1984a, Icarus 60, 127-137), which have been shown to account for Titan's observed geometric albedo. Thus, the nitrogen-containing polycyclic aromatic compounds we find in tholin formed at low pressure may be present in Titan's haze. These aromatic compounds may have a significant influence on the thermal structure and complex organic chemistry in Titan's atmosphere, because they are efficient absorbers of UV radiation and efficient charge exchange intermediaries. Our results also indicate that the haze layers at various altitudes might have different chemical and optical properties.     

Pan Sharpening for Hyper Spectral Imagery Using Spectral Mixing-Based Color Preservation Model

With nanometric spectral resolution and number of bands as high as 220, Hyper spectral sensors like Hyperion and AVIRIS are gaining wide appreciation. Narrow, continuous wavelength of bands upon a vast spectrum of electromagnetic wavelength enables better precision in identification of materials by distinguishing between their unique spectral signatures. However, their poor spatial resolution is a major impediment in realising the full potential of hyperspectral imaging. Efforts are being made worldwide to improve the spatial resolution of hyperspectral imagery by fusing them with registered panchromatic imagery of higher resolution. However, most of the conventional methods fail to preserve the spectral fidelity of the fused images due to severe color distortion. Here, we propose an efficient paradigm to sharpen hyperspectral imagery with high spatial information content and minimal color distortion using color normalization by Lαβ and intensity image generation using Spectral Mixture Analysis. Quantitative assessment indices have been calculated to prove that our method is superior in terms of minimization of color distortion and maximization of spatial details as compared to other methods.     

Signatures of different water masses in δ<Superscript>18</Superscript>O values,relative abundance of <Emphasis Type="Italic">G. Bulloides</Emphasis> and total planktonic foraminiferal assemblage across the Indian Ocean sector of the southern ocean: Initial results

Nineteen surface sediment samples, collected onboard ORV Sagar Kanya during the 199C and 200th (the pilot expedition to Southern Ocean) cruises along a north-south transect between 1.92° S to 55.01° S latitude and 67.88° E and 44.89° E longitude, were studied for total planktonic foraminiferal assemblage, relative abundance and the oxygen isotopic values of the indicator planktic species Globigerina bulloides. These profiles were compared with the latitudinal variations in the average salinity and nutrient (phosphate) contents of the top 100 meters water column. The initial results have traced the signatures of salinity linked variations of different water masses in the study region. The influence of Australian Mediterranean Water (AAMW) has been noticed in the present dataset.     

Extinction and scattering by several types of silicate sphere of radius 0.05–1.0μm,for the wavelength range 0.21–50μm

The exact calculation of scattering and absorption by various sub-micron sized silicate spheres is presented here, using accurately determined optical constants in the wavelength range from 50 m to 0.21 m. The extinction features near 10 m and 20 m for various samples are discussed. It is found that the ratio of peak extinction at 20 m to that at 10 m is constant for small particles up tor=0.4 m, but is less for particles of radius 1 m. The ratio of maximum extinction in the ultraviolet to that at 10 m decreases with increasing particle size.