Polycyclic aromatic hydrocarbons in the atmospheres of Titan and Jupiter

Polycyclic aromatic hydrocarbons (PAHs) are important components of the interstellar medium and carbonaceous chondrites, but have never been identified in the reducing atmospheres of the outer solar system. Incompletely characterized complex organic solids (tholins) produced by irradiating simulated Titan atmospheres reproduce well the observed UV/visible/IR optical constants of the Titan stratospheric haze. Titan tholin and a tholin generated in a crude simulation of the atmosphere of Jupiter are examined by two-step laser desorption/multiphoton ionization mass spectrometry. A range of two- to four-ring PAHs, some with one to four alkylation sites are identified, with net abundance approximately 10(-4) g g-1 (grams per gram) of tholins produced. Synchronous fluorescence techniques confirm this detection. Titan tholins have proportionately more one- and two-ring PAHs than do Jupiter tholins, which in turn have more four-ring and larger PAHs. The four-ringed PAH chrysene, prominent in some discussions of interstellar grains, is found in Jupiter tholins. Solid state 13C NMR spectroscopy suggests approximately equal to 25% of the total C in both tholins is tied up in aromatic and/or aliphatic alkenes. IR spectra indicate an upper limit in both tholins of approximately equal to 6% by mass in benzenes, heterocyclics, and PAHs with more than four rings. Condensed PAHs may contribute at most approximately 10% to the observed detached limb haze layers on Titan. As with interstellar PAHs, the synthesis route of planetary PAHs is likely to be via acetylene addition reactions.     

Future changes in rainfall,temperature and reference evapotranspiration in the central India by least square support vector machine

Climate change affects the environment and natural resources immensely. Rainfall, temperature and evapotranspiration are major parameters of climate affecting changes in the environment. Evapotranspiration plays a key role in crop production and water balance of a region, one of the major parameters affected by climate change. The reference evapotranspiration or ET₀ is a calculated parameter used in this research. In the present study, changes in the future rainfall, minimum and maximum temperature, and ET₀ have been shown by downscaling the HadCM3 (Hadley Centre Coupled Model version 3) model data. The selected study area is located in a part of the Narmada river basin area in Madhya Pradesh in central India. The downscaled outputs of projected rainfall, ET₀ and temperatures have been shown for the 21st century with the HADCM3 data of A2 scenario by the Least Square Support Vector Machine (LS-SVM) model. The efficiency of the LS-SVM model was measured by different statistical methods. The selected predictors show considerable correlation with the rainfall and temperature and the application of this model has been done in a basin area which is an agriculture based region and is sensitive to the change of rainfall and temperature. Results showed an increase in the future rainfall, temperatures and ET₀. The temperature increase is projected in the high rise of minimum temperature in winter time and the highest increase in maximum temperature is projected in the pre-monsoon season or from March to May. Highest increase is projected in the 2080s in 2081–2091 and 2091–2099 in maximum temperature and 2091–2099 in minimum temperature in all the stations. Winter maximum temperature has been observed to have increased in the future. High rainfall is also observed with higher ET₀ in some decades. Two peaks of the increase are observed in ET₀ in the April–May and in the October. Variation in these parameters due to climate change might have an impact on the future water resource of the study area, which is mainly an agricultural based region, and will help in proper planning and management.     

Bianchi type-I cosmological models with time dependent q and Λ-term in general relativity

On getting motivation from increasing evidence for the need of a geometry that resembles Bianchi morphology to explain the observed anisotropy in the WMAP data, Einstein’s field equations with variable cosmological “constant” are considered in presence of perfect fluid for a homogeneous and anisotropic Bianchi type-I space-time. Einstein’s field equations are solved by considering a time dependent deceleration parameter which affords a late time acceleration in the universe. The cosmological constant Λ is found to be a decreasing function of time and it approaches a small positive value at the present epoch which is corroborated by consequences from recent supernovae Ia observations. From recently developed Statefinder pair, the behavior of different stages of the evolution of the universe has been studied. The physical significance of the cosmological models have also been discussed.     

Redox-linked conformation change and electron transfer between monoheme c-type cytochromes and oxides

Electron transfer between redox active proteins and mineral oxides is important in a variety of natural as well as technological processes, including electron transfer from dissimilatory metal-reducing bacteria to minerals. One of the pathways that could trigger electron transfer between proteins and minerals is redox-linked conformation change. We present electrochemical evidence that mitochondrial cytochrome c (Mcc) undergoes significant conformation change upon interaction with hematite and indium-tin oxide (ITO) surfaces. The apparent adsorption-induced conformation change causes the protein to become more reducing, which makes it able to transfer electrons to the hematite conduction band. Although Mcc is not a protein thought to be involved in interaction with mineral surfaces, it shares (or can be conformed so as to share) some characteristics with multiheme outer-membrane cytochromes thought to be involved in the transfer of electrons from dissimilatory iron-reducing bacteria to ferric minerals during respiration. We present evidence that a 10.1 kDa monohoeme cytochrome isolated and purified from Acidiphilium cryptum, with properties similar to those of Mcc, also undergoes conformation change as a result of interaction with hematite surfaces.     

Do changes in coiling directions in planktonic foraminifera correspond to dimorphic reproduction?

A total of 25 surface sediment samples, collected along a North-South transect (from 9.69° N to 55.01° S and from 80° E and 40° E) in the south western Indian Ocean, were used to study the coiling direction patterns in foraminifera planktonic species Neogloboquadrina pachyderma, Globigerinita glutinata and Globigerina bulloides. Comparison between the coiling direction and mean proloculus size (MPS) revealed that all these profiles along N-S transect were not in tandem and thus indicated non-existence of any relationship between the coiling direction and reproductive modes expressed in terms of mean proloculus size.     

Modeling of strong motion generation area of the Uttarkashi earthquake using modified semiempirical approach

The semiempirical approach based on envelope summation method given by Midorikawa (Tectonophysics 218:287–295, 1993) has been modified in this paper for modeling of strong motion generation areas (SMGAs). Horizontal components of strong ground motion have been simulated using modifications in the semiempirical approach given by Joshi et al. (Nat Hazard 71:587–609, 2014). Various modifications in the technique account for finite rupture source, layering of earth, componentwise division of energy and frequency-dependent radiation pattern. In this paper, SMGAs of the Uttarkashi earthquake have been modeled. Two different isolated wave packets in the recorded accelerogram have been identified from recorded ground motion, which accounts for two different SMGAs in the entire rupture plane. The approximate locations of SMGAs within the rupture plane were estimated using spatio-temporal variation of 77 aftershocks. Source parameters of each SMGA were calculated from theoretical and observed source displacement spectra computed from two different wave packets in the record. The final model of rupture plane responsible for the Uttarkashi earthquake consists of two SMGAs, and the same has been used to simulate horizontal components of acceleration records at different station using modified semiempirical technique. Comparison of the observed and simulated acceleration records in terms of root mean square error confirms the suitability of the final source model for the Uttarkashi earthquake.     

Phosphate bonding configuration on ferrihydrite based on molecular orbital calculations and XANES fingerprinting

Sorption of phosphate by Fe(III)- and Al(III)-(hydr)oxide minerals regulates the mobility of this potential water pollutant in the environment. The objective of this research was to determine the molecular configuration of phosphate bound on ferrihydrite at pH 6 by interpreting P K-edge XANES spectra in terms of bonding mode. XANES and UV-visible absorption spectra for aqueous Fe(III)-PO₄ solutions (Fe/P molar ratio = 0-2.0) provided experimental trends for energies of P(3p)-O(2p) and Fe(3d)-O(2p) antibonding molecular orbitals. Molecular orbitals for Fe(III)-PO₄ or Al(III)-PO₄ complexes in idealized monodentate or bidentate bonding mode were generated by conceptual bonding arguments, and Extended-Hückel molecular orbital computations were used to understand and assign XANES spectral features to bound electronic states. The strong white line at the absorption edge in P K-edge XANES spectra for Fe-PO₄ or Al-PO₄ systems is attributable to an electronic transition from a P 1s atomic orbital into P(3p)-O(2p) or P(3p)-O(2p)-Al(3p) antibonding molecular orbitals, respectively. For Fe-PO₄ systems, a XANES peak at 2-5 eV below the edge was assigned to a P 1s electron transition into Fe(4p)-O(2p) antibonding molecular orbitals. Similarly, a shoulder on the low-energy side of the white line for variscite corresponds to a transition into Al(3p)-O(2p) orbitals. In monodentate-bonded phosphate, Fe-O bonding is optimized and P-O bonding is weakened, and the converse is true of bidentate-bonded phosphate. These differences explained an inverse correlation between energies of P(3p)-O(2p) and Fe(3d)-O(2p) antibonding molecular orbitals consistent with a monodentate-to-bidentate transition in aqueous Fe(III)-PO₄ solutions. The intensity of the XANES pre-edge feature in Fe(III)-bonded systems increased with increasing number of Fe(III)-O-P bonds. Based on the similarity of intensity and splitting of the pre-edge feature for phosphate sorbed on ferrihydrite at 750 mmol/kg at pH 6 and aqueous Fe-PO₄ solutions containing predominantly bidentate complexes, XANES results indicated that phosphate adsorbed on ferrihydrite was predominantly a bidentate-binuclear surface complex.