Zircon geochronology reveals polyphase magmatism and crustal anatexis in the Buchan Block,NE Scotland: Implications for the Grampian Orogeny

The type locality for high-temperature,low-pressure regional metamorphism,the Buchan Block in NE Scotland,exhibits profound differences to the rest of the Grampian Terrane.These differences have led some to regard the Buchan Block as an exotic crustal fragment comprising Precambrian basement gneisses and cover rocks thrust into their current position during Grampian orogenesis.Although rocks of the Buchan Block are now generally correlated with Dalradian strata elsewhere,the origin of the gneisses and the cause of the high heat flow and associated magmatism is debated.We report SIMS U-Pb and LA-ICPMS Hf isotopic data in zircon from high-grade rocks from the northeast(Inzie Head Gneiss)and northwest(Portsoy)corners of the Buchan Block.Around Inzie Head,upper amphibolite to granulite facies metasedimentary gneisses coexist with diorite sheets that were emplaced contemporaneously with partial melting of their host rocks,at least locally.U-Pb geochronology indicates a crystallisation age for the diorite of 486±9 Ma.Highly-deformed diorites within the Portsoy Gabbro have a crystallisation age of 493±8 Ma.Ages of ca.490 Ma for magmatism and high-grade metamorphism,which are broadly contemporaneous with ophiolite obduction and the onset of orogenesis,are significantly older than the established peak of Grampian metamorphism(ca.470 Ma).We propose a new model for the Grampian Orogeny involving punctuated tectonothermal activity due to tectonic switching during accretionary orogenesis.Rollback of a NW-dipping subduction zone at ca.490 Ma produced a back-arc environment(the Buchan Block)with associated arc magmatism and high dT/dP metamorphism.Arrival of an outboard arc resulted in shortening(the initial phase of the Grampian Orogeny)at ca.488 Ma.Rollback of a NW-dipping subduction zone to the SE of the ca.488 Ma suture began at 473 Ma and led to lithospheric-scale extension,decompression melting and advective heating of the middle crust,producing the widespread ca.470 Ma Grampian(classic Barrovian and Buchan)regional metamorphism.Resumed hinge advance and the final phase of shortening cut off the heat supply at ca.465 Ma,marking the end of the Grampian Orogeny.     

Surface-bounded atmosphere of Europa

A 1-D collisional Monte Carlo model of Europa's atmosphere is described in which the sublimation and sputtering sources of H₂O molecules and their molecular fragments are accounted for as well as the radiolytically produced O₂. Dissociation and ionization of H₂O and O₂ by magnetospheric electron, solar UV-photon and photo-electron impact, and collisional ejection from the atmosphere by the low-energy plasma are taken into account. Reactions with the surface are discussed, but only adsorption and atomic oxygen recombination are included in this model. The size of the surface-bounded oxygen atmosphere of Europa is primarily determined by a balance between atmospheric sources from irradiation of the satellite's icy surface by the high-energy magnetospheric charged particles and atmospheric losses from collisional ejection by the low-energy plasma, photo- and electron-impact dissociation, and ionization and pick-up from the surface-bounded atmosphere. A range of sources rates for O₂ to H₂O are used with a larger oxygen-to-water ratio than suggested by laboratory measurements in order to account for differences in adsorption onto grains in the regolith. These calculations show that the atmospheric composition is determined by both the water and oxygen photochemistry in the near-surface region, escape of suprathermal oxygen and water into the jovian system, and the exchange of radiolytic water products with the porous regolith. For the electron impact ionization rates used, pick-up ionization is the dominant oxygen loss process, whereas photo-dissociation and atmospheric sputtering are the dominant sources of neutral oxygen for Europa's neutral torus. Including desorption and loss of water enhances the supply of oxygen species to the neutral torus, but hydrogen produced by radiolysis is the dominant source of neutrals for Europa's torus in these models.     

MaxEnt power spectrum estimation using the Fourier transform for irregularly sampled data applied to a record of stellar luminosity

The principle of maximum entropy is applied to the spectral analysis of a data signal with general variance matrix and containing gaps in the record. The role of the entropic regularizer is to prevent one from overestimating structure in the spectrum when faced with imperfect data. Several arguments are presented suggesting that the arbitrary prefactor should not be introduced to the entropy term. The introduction of that factor is not required when a continuous Poisson distribution is used for the amplitude coefficients. We compare the formalism for when the variance of the data is known explicitly to that for when the variance is known only to lie in some finite range. The result of including the entropic measure factor is to suggest a spectrum consistent with the variance of the data which has less structure than that given by the forward transform. An application of the methodology to example data is demonstrated.     

Rainfall intensity affects runoff responses in a semi-arid catchment

The source and hydrochemical makeup of a stream reflects the connectivity between rainfall, groundwater, the stream, and is reflected to water quantity and quality of the catchment. However, in a semi-arid, thick, loess covered catchment, temporal variation of stream source and event associated behaviours are lesser known. Thus, the isotopic and chemical hydrographs in a widely distributed, deep loess, semi-arid catchment of the northern Chinese Loess Plateau were characterized to determine the source and hydrochemical behaviours of the stream during intra-rainfall events. Rainfall and streamflow were sampled during six hydrologic events coupled with measurements of stream baseflow and groundwater. The deuterium isotope (²H), major ions (Cl⁻, SO₄²⁻, NO₃⁻, Ca²⁺, K⁺, Mg²⁺, and Na⁺) were evaluated in water samples obtained during rainfall events. Temporal variation of ²H and Cl⁻ measured in the groundwater and stream baseflow prior to rainfall was similar; however, the isotope compositions of the streamflow fluctuated significantly and responded quickly to rainfall events, likely due to an infiltration excess, overland dominated surface runoff during torrential rainfall events. Time source separation using ²H demonstrated greater than 72% on average, the stream composition was event water during torrential rainfall events, with the proportion increasing with rainfall intensity. Solutes concentrations in the stream had loglinear relationships with stream discharge, with an outling anomaly with an example of an intra-rainfall event on Oct. 24, 2015. Stream Cl⁻ behaved nonconservative during rainfall events, temporal variation of Cl⁻ indicated a flush and washout at the onset of small rainfall events, a dilution but still high concentration pattern in high discharge and old water dominated in regression flow period. This study indicates rainfall intensity affects runoff responses in a semi-arid catchment, and the stored water in the thick, loess covered areas was less connected with stream runoff. Solute transport may threaten water quality in the area, requiring further analysis of the performance of the eco-restoration project.     

Hillslope–channel sediment transfer in a slope failure event: Wet Swine Gill,Lake District,northern England

This paper describes and analyses a hillslope–channel slope failure event that occurred at Wet Swine Gill, Lake District, northern England. This comprised a hillslope slide (180 m³, c. 203 ± 36 t), which coupled with the adjacent stream, resulting in a channelized debris flow and fluvial flood. The timing of the event is constrained between January and March 2002. The hillslope failure occurred in response to a rainfall/snowmelt trigger, on ground recently disturbed by a heather moorland fire and modified by artificial drainage. Slide and flow dynamics are estimated using reconstructed velocity and discharge values along the sediment transfer path. There is a rapid downstream reduction in both maximum velocity, from 9·8 to 1·3 m s^?1; and maximum discharge, ranging from 33·5 to 2·4 m³ s^?1. A volumetric sediment budget quantified a high degree of coupling between the hillslope and immediate channel (～92%: 167 m³), but virtually all of the sediment was retained in the first‐order tributary channel. Approximately 44% (81 m³) of the slide volume was retained in the run‐up deposit, and termination of the debris flow prior to the main river meant that the remainder did not discharge into the fluvial system downstream. These results suggest poor transmission of sediment to the main river at the time of the event, but importantly an increase in available material for post‐event sediment transfer processes within the small upland tributary. Copyright © 2007 John Wiley & Sons, Ltd.     

The WOCE-era 3-D Pacific Ocean circulation and heat budget

To address questions concerning the intensity and spatial structure of the three-dimensional circulation within the Pacific Ocean and the associated advective and diffusive property flux divergences, data from approximately 3000 high-quality hydrographic stations collected on 40 zonal and meridional cruises have been merged into a physically consistent model. The majority of the stations were occupied as part of the World Ocean Circulation Experiment (WOCE), which took place in the 1990s. These data are supplemented by a few pre-WOCE surveys of similar quality, and time-averaged direct-velocity and historical hydrographic measurements about the equator.An inverse box model formalism is employed to estimate the absolute along-isopycnal velocity field, the magnitude and spatial distribution of the associated diapycnal flow and the corresponding diapycnal advective and diffusive property flux divergences. The resulting large-scale WOCE Pacific circulation can be described as two shallow overturning cells at mid- to low latitudes, one in each hemisphere, and a single deep cell which brings abyssal waters from the Southern Ocean into the Pacific where they upwell across isopycnals and are returned south as deep waters. Upwelling is seen to occur throughout most of the basin with generally larger dianeutral transport and greater mixing occurring at depth. The derived pattern of ocean heat transport divergence is compared to published results based on air–sea flux estimates. The synthesis suggests a strongly east/west oriented pattern of air–sea heat flux with heat loss to the atmosphere throughout most of the western basins, and a gain of heat throughout the tropics extending poleward through the eastern basins. The calculated meridional heat transport agrees well with previous hydrographic estimates. Consistent with many of the climatologies at a variety of latitudes as well, our meridional heat transport estimates tend toward lower values in both hemispheres.     

Inferring air–water temperature relationships from river and catchment properties

Water temperature (Tw) is a key determinant of freshwater ecosystem status and cause for concern under a changing climate. Hence, there is growing interest in the feasibility of moderating rising Tw through management of riparian shade. The Loughborough University Temperature Network (LUTEN) is an array of 36 water and air temperature (Ta) monitoring sites in the English Peak District set‐up to explore the predictability of local Tw, given Ta, river reach, and catchment properties. Year 1 of monitoring shows that 84%–94% of variance in daily Tw is explained by Ta. However, site‐specific logistic regression parameters exhibit marked variation and dependency on upstream riparian shade. Perennial spring flows in the lower River Dove also affect regression model parameters and strongly buffer daily and seasonal mean Tw. The asymptote of the models (i.e. maximum expected Tw) is particularly sensitive to groundwater inputs. We conclude that reaches with spring flows potentially offer important thermal refuges for aquatic organisms against expected long‐term warming of rivers and should be afforded special protection. Copyright © 2013 John Wiley & Sons, Ltd.     

Feedbacks between erosion and sediment transport in experimental bedrock channels

Natural bedrock rivers flow in self‐formed channels and form diverse erosional morphologies. The parameters that collectively define channel morphology (e.g. width, slope, bed roughness, bedrock exposure, sediment size distribution) all influence river incision rates and dynamically adjust in poorly understood ways to imposed fluid and sediment fluxes. To explore the mechanics of river incision, we conducted laboratory experiments in which the complexities of natural bedrock channels were reduced to a homogenous brittle substrate (sand and cement), a single sediment size primarily transported as bedload, a single erosion mechanism (abrasion) and sediment‐starved transport conditions. We find that patterns of erosion both create and are sensitive functions of the evolving bed topography because of feedbacks between the turbulent flow field, sediment transport and bottom roughness. Abrasion only occurs where sediment impacts the bed, and so positive feedback occurs between the sediment preferentially drawn to topographic lows by gravity and the further erosion of these lows. However, the spatial focusing of erosion results in tortuous flow paths and erosional forms (inner channels, scoops, potholes), which dissipate flow energy. This energy dissipation is a negative feedback that reduces sediment transport capacity, inhibiting further incision and ultimately leading to channel morphologies adjusted to just transport the imposed sediment load. Copyright © 2007 John Wiley & Sons, Ltd.     

Fluid-pressure variations and fault creep in central California

Observations of the change of water level in wells near the San Andreas fault in centra California indicate that there are pore-pressure changes associated with the process of fault creep. The sense of water-level and pore-pressure changes may indicate the direction of creep propagation.