Bioavailability of arsenic in the soil horizon: a laboratory column study

Groundwater contaminated with arsenic (As), when extensively used for irrigation, causes potentially long-term detrimental effects to surface soils. Such contamination can also directly affect human health when irrigated crops, such as rice, vegetable and fruits, are used for human consumption. Therefore, an understanding of the leaching behavior of As in surface soils is of high importance, because such behavior may increase the bioavailability of As in the soil horizon. In this study, we have investigated the role of phosphate ions in leaching and bioavailability of As in the soil horizon, where drinking groundwater contains elevated levels of As (≥50 μg/L). Soil and groundwater samples were characterized in the laboratory and measured for physical and chemical constituents. The soils are generally neutral to slightly alkaline in character (pH range 7.5–8.1) with low to moderate levels of free Fe₂O₃, Al₂O₃, CaCO₃, organic carbon, and clay content. The measured electrical conductivity (mean 599 μS/cm) of the soils demonstrates their non-saline nature. The Eh values (range −37 to −151 mV) of the groundwater indicate anoxic condition with low to moderate levels of bicarbonate (range 100–630 mg/L) and phosphate (range 0.002–4.0 mg/L). The arsenic content (range 50–690 μg/L; mean 321 μg/L) in groundwater has exceeded both WHO recommended guideline values (10 μg/L) and the National safe drinking water limit (50 μg/L). Regression analyses demonstrate that the bioavailability of As in the soil horizon is mainly controlled by the composition of free Fe₂O₃ and CaCO₃ content of the soils. However, application of P could increase bioavailability of As in the soil horizon and become available to plants for uptake.     

Experimental and petrological constraints on lunar differentiation from the Apollo 15 green picritic glasses

Abstract— Phase equilibrium experiments on the most magnesian Apollo 15C green picritic glass composition indicate a multiple saturation point with olivine and orthopyroxene at 1520°C and 1.3 GPa (about 260 km depth in the moon). This composition has the highest Mg# of any lunar picritic glass and the shallowest multiple saturation point. Experiments on an Apollo 15A composition indicate a multiple saturation point with olivine and orthopyroxene at 1520°C and 2.2 GPa (about 440 km depth in the moon). The importance of the distinctive compositional trends of the Apollo 15 groups A, B, and C picritic glasses merits the reanalysis of NASA slide 15426,72 with modern electron microprobe techniques. We confirm the compositional trends reported by Delano (1979, 1986) in the major element oxides SiO₂, TiO₂, Al₂O₃, Cr₂O₃, FeO, MnO, MgO, and CaO, and we also obtained data for the trace elements P₂O₅, K₂O, Na₂O, NiO, S, Cu, Cl, Zn, and F. Petrogenetic modeling demonstrates that the Apollo 15 A‐B‐C glass trends could not have been formed by fractional crystallization or any continuous assimilation/fractional crystallization (AFC) process. The B and C glass compositional trends could not have been formed by batch or incremental melting of an olivine + orthopyroxene source or any other homogeneous source, though the A glasses may have been formed by congruent melting over a small pressure range at depth. The B compositional trend is well modeled by starting with an intermediate A composition and assimilating a shallower, melted cumulate, and the C compositional trend is well modeled by a second assimilation event. The assimilation process envisioned is one in which heat and mass transfer were separated in space and time. In an initial intrusive event, a picritic magma crystallized and provided heat to melt magma ocean cumulates. In a later replenishment event, the picritic magma incrementally mixed with the melted cumulate (creating the compositional trends in the green glass data set), ascended to the lunar surface, and erupted as a fire fountain. A barometer created from multiple saturation points provides a depth estimate of other glasses in the A‐B‐C trend and of the depths of assimilation. This barometer demonstrates that the Apollo 15 A‐B‐C trend originated over a depth range of ?460 km to ?260 km within the moon.     

Cylindrical Zakharov–Kuznestov equation for ion-acoustic waves with electrons featuring non-extensive distribution

Cylindrical Zakharov–Kuznestov equation for ion-acoustic waves comprising of ions and electrons featuring non-extensive distribution are derived from the fluid equations through reductive perturbation technique. System of first order ordinary differential equations is obtained from Zakharov–Kuznestov equation through dynamical system approach and ultimately it is solved using numerical method. It is found that the electron to positron ratio parameter and the non-extensive distributed parameter due to electron play crucial role on the solution.     

Overtaking collision of two ion acoustic soliton in a plasma with a q-nonextensive electron and thermal positrons

Theoretically the propagation of two ion acoustic soliton interaction in a three component collisionless unmagnetized plasma which consists of electrons, positrons and cold ions, has been investigated here by employing reductive perturbation technique. In this study, q distributed electrons and Maxwell-Boltzmann distributed positrons are considered and Korteweged-de Vries (KdV) equation is derived. The KdV equation is solved to get two soliton solution by using Hirota bilinear method. The effects of the q distributed electrons on the profiles of two soliton structures and the corresponding phase shifts are investigated. It is observed that both the nonextensive parameter (q) and the ratio of positrons density and electron density (p=n _p0/n _e0), play a significant role in the formation and existence of two soliton and also in the nature of their phase shifts.     

On Magnetic Coupling Between the Two Hemispheres in Solar Dynamo Models

By introducing an asymmetry between the two hemispheres, we study whether the solar dynamo solutions in the two hemispheres remain coupled with each other. Our calculations are based on the solar dynamo code SURYA, which incorporates the helioseismically-determined solar-rotation profile, a Babcock–Leighton α effect concentrated near the surface, and a meridional circulation. When the magnetic coupling between the hemispheres is enhanced by either increasing the diffusion or introducing an α effect distributed throughout the convection zone, we find that the solutions in the two hemispheres evolve together with a single period even when we make the meridional circulation or the α effect different in the two hemispheres. On the other hand, when the hemispheric coupling is weaker for other values of parameters, an asymmetry between the hemispheres can make solutions in the two hemispheres evolve independently with different periods.     

Changes in Ellipticals Due to Collisions with Spirals and Their Consequences

A study of collisions between spiral and elliptical galaxies (approximated as composite spherical masses) is made to assess the changes undergone by the elliptical. Results indicate that unless the spiral is extremely massive compared to the elliptical, the elliptical is almost unaffected, while the spiral is strongly affected. For the frequent type of collision between equally massive spiral and elliptical galaxies, the elliptical is negligibly affected, while disruptive effects set in the spiral. However, the stellar pattern of the elliptical is changed and the stars are found to crowd in faint shells after the collision. The consequences of these results are explored in the context of the morphology-density relationship and the elliptical companions of ring galaxies.