Variations in shear wave velocity and soil site class in Kolkata city using regression and sensitivity analysis

The detrimental effects of an earthquake are strongly influenced by the response of soils subjected to dynamic loading. The behavior of soils under dynamic loading is governed by the dynamic soil properties such as shear wave velocity, damping characteristics and shear modulus. Worldwide, it is a common practice to obtain shear wave velocity (V _s in m/s) using the correlation with field standard penetration test (SPT) N values in the absence of sophisticated dynamic field test data. In this paper, a similar but modified advanced approach has been proposed for a major metro city of eastern India, i.e., Kolkata city (latitudes 22°20′N–23°00′N and longitudes 88°04′E–88°33′E), to obtain shear wave velocity profile and soil site classification using regression and sensitivity analyses. Extensive geotechnical borehole data from 434 boreholes located across 75 sites in the city area of 185 km² and laboratory test data providing information on the thickness of subsoil strata, SPT N values, consistency indices and percentage of fines are collected and analyzed thoroughly. A correlation between shear wave velocity (V _s) and SPT N value for various soil profiles of Kolkata city has been established by using power model of nonlinear regression analysis and compared with existing correlations for other Indian cities. The present correlations, having regression coefficients (R ²) in excess of 0.96, indicated good prediction capability. Sensitivity analysis predicts that significant influence of soil type exists in determining V _s values, for example, typical silty sand shows 30.4 % increase in magnitude of V _s as compared to silt of Kolkata city. Moreover, the soil site classification shows Class D and Class E category of soil that exists typically in Kolkata city as per NEHRP (Recommended provisions for seismic regulations for new buildings and other structures—Part 1: Provisions. Prepared by the Building Seismic Safety Council for the Federal Emergency Management Agency (Report FEMA 450), Washington, DC, 2003) guidelines and thereby highlighting the seismic vulnerability of the city. The results presented in this study can be utilized for seismic microzonation, ground response analysis and hazard assessment for Kolkata city.

     

Estimation of near surface soil moisture in a sloping terrain of a Himalayan watershed using ENVISAT ASAR multi‐incidence angle alternate polarisation data

Soil moisture is one of the important input variables in hydrological and water erosion models. The extraction of information on near surface soil moisture from synthetic aperture radar (SAR) is well established mostly for flat terrain and using low incidence angle single polarisation data. The ENVISAT advanced SAR (ASAR) data available in multiple incidence angles and alternate polarisation modes were investigated in this study for soil moisture estimation in sloping terrain. The test site was Sitla Rao watershed in the Lesser Himalayas of northern India. Empirical models were developed to estimate near surface soil moisture in bare agricultural fields using alternate polarisation ASAR data. Both soil moisture and surface roughness field measurements were performed during the satellite passes. Backscatter from medium incidence angle (IS‐4) and vertical‐vertical (VV) polarisation signal is correlated better with volumetric soil moisture content compared to other incidence angles. The model parameters were further improved, and soil moisture estimation was refined by combining medium incidence angle (IS4) vertical‐horizontal polarisation response as another variable along with VV polarisation response. The effect of slope on the radar backscatter was minimized by incorporating local incidence angles derived from an ASTER DEM. Copyright © 2012 John Wiley & Sons, Ltd.     

Riddle of arsenic in groundwater of Bengal Delta Plain—role of non-inland source and redox traps

In the Bengal Delta Plain (BDP) the primary arsenic sourcing appears to be different from the global scenario. Here, the Terminal Pleistocene–Holocene depositional platform, the interactive early Holocene depositional morphology with fluvio-estuarine and marine incursions played a crucial role for arsenic sourcing and enrichment. The lenticular silt-fine sand layer between anoxic clay beds favoured entrapment of dissolved organic carbon with decayed phyto-planktons debris. The Terminal Pleistocene–Holocene transgression and regression processes may have acted as major events in the BDP. Interestingly, at the end of the last glacial maxima, the Pleistocene delta had undergone block movements, wherein some parts of the platform were raised above the level of Holocene deposition. Those blocks were found to be free from arsenic in the groundwater. The sea, during re-emerging inundation (10–7 ka BP), has witnessed a monsoon-induced environment in the BDP with the resultant oscillation of sea level leading to higher upsurge towards the north. This might have resulted in the marine incursion and inundation in pre-existing land depressions. Meanwhile arsenic entrapments through marine incursion as well as enrichment in the presence of organic carbon/DOC and/or Fe/Mn/Al catalytic agents could have developed into localised redox traps. It may be of relevance that due to the repetitive transgressive–regressive phases in Holocene, resulting in periodic exposure and weathering of iron-bearing minerals and consequent iron enrichment in the aquifer system. The iron, thus present, had free charge to host arsenic as a sink. It appears that arsenic, wherever found, would likely be of atypical localised exhaustible phenomenon, both in horizontal and vertical context. It also rationalises the cause of the absence of arsenic in the other nearby Pleistocene platform, which has not come across Holocene interaction and marine incursion, as to the likely limiting condition for the search for arsenic in the BDP or beyond.     

Thermodynamic mixing properties of Mg(Al,Cr)2O4 spinel crystalline solution at high temperatures and pressures

Three Al-Cr exchange isotherms at 1,250°, 1,050°, and 796° between Mg(Al, Cr)₂O₄ spinel and (Al, Cr)₂O₃ corundum crystalline solutions have been studied experimentally at 25 kbar pressure. Starting from gels of suitable bulk compositions, close approach to equilibrium has been demonstrated in each case by time studies. Using the equation of state for (Al, Cr)₂O₃ crystalline solution (Chatterjee et al. 1982a) and assuming that the Mg(Al, Cr)₂O₄ can be treated in terms of the asymmetric Margules relation, the exchange isotherms were solved for Δ G ^*, and . The best constrained data set from the 1,250° C isotherm clearly shows that the latter two quantities do not overlap within three standard deviations, justifying the choice of asymmetric Margules relation for describing the excess mixing properties of Mg(Al, Cr)₂O₄ spinels. Based on these experiments, the following polybaric-polythermal equation of state can be formulated: , P expressed in bars, T in K, G _m ^ex and W _G,i ^Sp in joules/mol. Temperature-dependence of G _m ^ex is best constrained in the range 796–1,250° C; extrapolation beyond that range would have to be done with caution. Such extrapolation to lower temperature shows tentatively that at 1 bar pressure the critical temperature, T _c, of the spinel solvus is 427° C, with dT_c/dP≈1.3 K/kbar. The critical composition, X _c, is 0.42 , and changes barely with pressure. Substantial error in calculated phase diagrams will result if the significant positive deviation from ideality is ignored for Al-Cr mixing in such spinels.     

Heat capacity of wadeite-type K2Si4O9 and the pressure-induced stable decomposition of K-feldspar

The heat capacity of synthetic, stoichiometric wadeite-type K₂Si₄O₉ has been measured by DSC in the 195≤T(K)≤598 range. Near the upper temperature limit of our data, the heat capacity observed by DSC agrees with that reported by Geisinger et al. (1987) based on a vibrational model of their infrared and Raman spectroscopic data. However, with decreasing temperature, the Cp observed by DSC is progressively higher than that predicted from the vibrational model, suggesting that the standard entropy of K₂Si₄O₉ is likely to be larger than 198.9 ± 4.0 J/K · mol computed from the spectroscopic data. A fit to the DSC data gave: Cp(T) = 499.13 (±1.87) − 4.35014 · 10³(±3.489 · 10¹) · T ^−0.5, with T in K and average absolute percent deviation of 0.37%. The room-temperature compressibilities of kalsilite and leucite, hitherto unknown, have been measured as well. The data, fitted to the Murnaghan equation of state, gave K _o = 58.6 GPa, K _o ^′ = 0.1 for kalsilite and K _o = 45 GPa, K _o ^′ = 5.7 for α-leucite. Apart from the above mentioned data on the properties of the individual phases, we have also obtained reaction-reversals on four equilibria in the system K₂O-Al₂O₃-SiO₂. The Bayesian method has been used simultaneously to process the properties of 13 phases and 15 reactions between them to derive an internally consistent thermodynamic dataset for the K₂O-Al₂O₃-SiO₂ ternary. The enthalpy of formation of K₂Si₄O₉ wadeite is in perfect agreement with its revised calorimetric value, the standard entropy is 232.1 ± 10.4 J/K · mol, ∼15% higher than that implied by vibrational modeling. The phase diagram, generated from our internally consistent thermodynamic dataset, shows that for all probable P-T trajectories in the subduction regime, the stable pressure-induced decomposition of K-feldspar will produce coesite + kalsilite rather than coesite + kyanite + K₂Si₄O₉ (cf. Urakawa et al. 1994). Received: 11 June 1997 / Accepted: 2 December 1997     

Lithogeochemistry as an indicator of uranium and tin mineralization, South Mountain Batholith, Nova Scotia, Canada

Uranium and tin occurrences in the South Mountain Batholith are preferentially found in or near a para-intrusive rock suite which is characterized by strong granophile element enrichments. Furthermore, bodies which show a Th-enrichment trend with increasing differentiation appear to be more favorable exploration targets than spatially associated bodies in which Th is depleted.     

The Bayesian approach to an internally consistent thermodynamic database: theory, database, and generation of phase diagrams

An internally consistent thermodynamic dataset has been derived for 148 endmember phases (145 solids and 3 fluids) comprising the elements Li, Na, K, Be, Mg, Ca, Ti, Cr, Mn, Fe, Zn, Al, Si, C, H, and O. This has been achieved by simultaneous treatment of phase property (like standard enthalpy of formation, standard entropy, molar heat capacity, molar volume, thermal expansivity, bulk modulus etc.) and reaction reversal data by the Bayesian method. The theory underlying the approach, and the computational methods involved, are briefly outlined. (For the benefit of readers unfamiliar with inference statistics, the basic concepts of the Bayes method are also presented in such a way that they can be grasped intuitively.) Although not yet addressed, this method can be extended to refine the thermodynamic mixing properties of crystalline solutions. The sources of the input data, culled from the literature, are summarized in the Appendix. The resulting database is succinctly documented in this paper. It includes the enthalpies of formation and entropies, their uncertainties, and the correlation among them. The database allows calculation of P-T, T-X _CO2, P-X _CO2, and T-f _O2 sections, with error propagation into the computed phase diagrams on a routine basis. A user-friendly computer program has been written to generate such phase diagrams. It is public domain software. The software and the thermodynamic database (which includes a complete documentation of the thermodynamic data above and beyond those listed (Table 2, here) may be downloaded from the web site http://homepage.ruhr-uni-bochum.de/niranjan.chatterjee/Index.htm. Examples of computed phase diagrams are given to illustrate the quality of the data and the capabilities of the software. Received: 11 March 1998 / Accepted: 11 June 1998     

Experimental and thermodynamic study of heterogeneous and homogeneous equilibria in the system NaAlSiO4-SiO2

Internally consistent thermodynamic datasets available at present call for a further improvement of the data for nepheline (Holland and Powell 1988; Berman 1991). Because nepheline is a common rock-forming mineral, an attempt has been made to improve on the present state of knowledge of its thermodynamic properties. To achieve that goal, two heterogeneous reactions involving nepheline, albite, jadeite and a-quartz in the system NaAlSiO₄-SiO₂ have been reversed bylong duration runs in the range 460 ≤ T(°C) ≤ 960 and 10 ≤ P(kbar) ≤ 22. Given sufficiently long run times, thealbite run products approach internal equilibrium with respect to their Al,Si order-disorder states. Using appropriate thermochemical, thermophysical, and volumetric data, Landau expansion for albite, and the relevant reaction reversals, a refined thermodynamic dataset (Δ_fH_i⁰ and S_i⁰) has been derived for nepheline, jadeite, a-quartz, albite, and monalbite. Our refined data agree very well with theircalorimetric counterparts, but have smaller uncertainties. The refined dataset for Δ_fH_i⁰ and S_i⁰, including their uncertainties and correlation, help generate the NaAlSiO₄-SiO₂ phase diagram including 2a confidence interval for eachP-T curve (Fig. 5). Editorial responsibility: W. Schreyer     

Dwellers’ perception toward the Urban services of Panskura Municipality,India: an application of importance-performance models

The provision of urban service and citizens’ satisfaction is an important key issue in urban planning. Importance-performance analysis (IPA) is an effective and widely applicable technique to explore consumer’s satisfaction. IPA helps to prioritize the management strategies for urban services using the IPA. Purpose of the present study is to assess the performance of urban services and citizen’s satisfaction level of Panskura municipality using IPA models and improvement index. A total of 629 valid household responses are collected with the help of the door-to-door primary survey technique. The study reveals that all the selected seven urban services have significant importance-performance gap except water supply. Residents of the Panskura municipality are very much satisfied with the water supply service because of the very minimum improvement score. The combined result of IPA matrices and improvement index suggests residents are dissatisfied to a great extent with the performance of four urban services, i.e. health, economy, transportation and sanitation. These urban services require a problem-solving urgent action for restoration of the performance status. The improvement and prioritization of urban service are also required to fulfil the demand of target groups.