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141.
ABSTRACT. Recent attempts by U.S. politicians to reform the nation'sschools have shifted the goal of education to school accountability as assessed in standardized testing. Such an emphasis undermines geographical education in schools because of geography'ssuperficial representation in tests and in the social studies curriculum. Fieldwork done in the classroom can point to means of circumventing this dilemma. Collaborative fieldwork between college faculty members and public‐school teachers has the potential for adding geography to the social studies curriculum in a substantive way. Work conducted jointly by Hartwick College and the Oneonta (New York) Middle School exemplifies such a partnership.  相似文献   
142.
The photodegradation of naphthalene (NPH), chosen as a model of polynuclear aromatic pollutants, has been studied in the presence of a layer of four water-insoluble inorganic solids which can be found in the troposphere (TiO2, Fe2O3, muscovite, and a fly ash sample). Direct photolysis of NPH is negligible at >340 nm. Dark adsorption of NPH on TiO2 (mainly anatase, nonporous, 50 m2 g–1) at 293 K corresponds to a surface coverage ofca. 50% at equilibrium. Under these conditions (saturated surface), the stationary-state photocatalytic degradation reaches 0.4 molecule nm–2 h–1 (>340 nm, radiant fluxca. 22 mW cm–2). Dioxygen is required and its partial pressure in air is such that the degradation is zero order in O2. Water vapor markedly increases the rate. The other particulates have also an effect, less important than that of TiO2, however quite noticeable with respect to surface area unit for the fly ash sample which contains 3.2% Fe2O3. Apart from 1,4-naphthoquinone, which is the main intermediate product in all cases, 2-naphthol, phthalide, phthaldialdehyde, phthalic acid, acetophenone, benzaldehyde, benzoic acid are also formed on dry TiO2. Depending on their volatility, these compounds are transferred to the gas phase or remain principally adsorbed on the solid particles where they are further transformed. For instance, phthalic acid (or anhydride) and benzoic acid are generated from 1,4-naphthoquinone. Degradation mechanisms are briefly discussed.  相似文献   
143.
There is a growing concern that countries should reduce their dependence on fossil fuels for electricity generation and look to other cleaner technologies. Hydroelectricity is one such option. However, given that hydropower is dependent on rainfall and associated runoff for power generation, it is susceptible to both the positive and negative impacts of climate change, such as increases in temperature and changes in precipitation and runoff. In this paper, impacts on hydropower generation have been organised as either changes in long-term trends or short-term variability and shocks. These impacts could either manifest themselves as direct impacts on hydropower generation potential or as indirect impacts (or ancillary impacts) such as increased competition for water. Citing examples from around the world, this paper investigates the scale of these projected impacts, and the potential cost implication of inaction. It concludes by making recommendations for possible adaptive options to build resilience in response to local impacts.  相似文献   
144.
The chemical composition of fogwater has been studied in the city of Strasbourg (France) from 1990 to 1999. During these years, fogwater samples have been collected and analysed for major ions and trace metals. This paper reports on the analysis of the collected dataset. The analysis revealed a significant decrease in acidity of approximately one pH unit over the course of the study. This decrease in acidity appears to be linked to a decrease in SO2(g) and the resulting SO42−. Trace metal concentrations have also strongly decreased over the 10-year period. Pb concentrations, following the elimination of leaded gasoline, decreased by more than one order of magnitude.  相似文献   
145.
The material of Hispanomys decedens (Rodentia, Cricetodontinae) from La Grive-Saint Alban (France) is described in detail for the first time. H. decedens, which is one of the oldest species of the genus, shows the primitive character states that are typical of the Aragonian congeneric species, such as the mesolophs and labial cingula surrounding the upper molar valleys. The detailed examination of the teeth of H. decedens shows that this taxon is a good candidate ancestor for H. aragonensis.  相似文献   
146.
Mineralogy, major, trace and rare earth elements of a weathering profile developed on tertiary greenstone belt in the extreme North Cameroon are reported. The aim of which was to investigate mineralogical evolution and element mobilization and redistribution during weathering under dry tropical climate. The weathering profile consists of four main horizons: (1) a spheroidal weathering zone constituted by a corestone–shell complex, (2) a C horizon, (3) a Bw horizon and an Ah horizon. The results indicate that nontronite, a Fe-rich smectite, is the exclusive clay mineral formed in the exfoliated shells and the C horizon. It is associated with kaolinite in the upper horizons. The coexistence of these two clay minerals induced a decrease of CEC and pH which becomes neutral. The weathering index (WI) values reveal that weathering becomes more and more intensive from the corestone up to Bw horizon, which is the most weathered horizon in the weathering profile. Mass balance calculations, using Th as immobile element, indicate that Ti is quite mobile and that Al and Fe are relatively enriched at the bottom and strongly leached at the top of the profile. Alkalis and alkaline earth elements are strong leached through out the profile, except Ca which displays similar trend as Al and Fe. The same goes for LILE (Cs, Sr), TTE (Cr, Co, Ni) and HSFE (Y, Nb, Hf). In opposite, REE are depleted at the bottom and enriched in the upper horizons, with more enrichment for LREE than for HREE. It appears that weathering of greenstone belt causes a fractionation of HREE and induces a concentration of LREEs. Ce and Eu anomalies display opposite behaviour.  相似文献   
147.
The sedimentary record of aeolian sand systems extends from the Archean to the Quaternary, yet current understanding of aeolian sedimentary processes and product remains limited. Most preserved aeolian successions represent inland sand‐sea or dunefield (erg) deposits, whereas coastal systems are primarily known from the Cenozoic. The complexity of aeolian sedimentary processes and facies variability are under‐represented and excessively simplified in current facies models, which are not sufficiently refined to reliably account for the complexity inherent in bedform morphology and migratory behaviour, and therefore cannot be used to consistently account for and predict the nature of the preserved sedimentary record in terms of formative processes. Archean and Neoproterozoic aeolian successions remain poorly constrained. Palaeozoic ergs developed and accumulated in relation to the palaeogeographical location of land masses and desert belts. During the Triassic, widespread desert conditions prevailed across much of Europe. During the Jurassic, extensive ergs developed in North America and gave rise to anomalously thick aeolian successions. Cretaceous aeolian successions are widespread in South America, Africa, Asia, and locally in Europe (Spain) and the USA. Several Eocene to Pliocene successions represent the direct precursors to the present‐day systems. Quaternary systems include major sand seas (ergs) in low‐lattitude and mid‐latitude arid regions, Pleistocene carbonate and Holocene–Modern siliciclastic coastal systems. The sedimentary record of most modern aeolian systems remains largely unknown. The majority of palaeoenvironmental reconstructions of aeolian systems envisage transverse dunes, whereas successions representing linear and star dunes remain under‐recognized. Research questions that remain to be answered include: (i) what factors control the preservation potential of different types of aeolian bedforms and what are the characteristics of the deposits of different bedform types that can be used for effective reconstruction of original bedform morphology; (ii) what specific set of controlling conditions allow for sustained bedform climb versus episodic sequence accumulation and preservation; (iii) can sophisticated four‐dimensional models be developed for complex patterns of spatial and temporal transition between different mechanisms of accumulation and preservation; and (iv) is it reasonable to assume that the deposits of preserved aeolian successions necessarily represent an unbiased record of the conditions that prevailed during episodes of Earth history when large‐scale aeolian systems were active, or has the evidence to support the existence of other major desert basins been lost for many periods throughout Earth history?  相似文献   
148.
We present a structural, AMS, microstructural and kinematic study of the Aston gneiss dome (French Pyrenees), which consists of a core made up of orthogneiss and paragneiss intruded by numerous sills of Carboniferous peraluminous granite. The orthogneiss corresponds to a former Ordovician granitic laccolith. Four Variscan events have been evidenced in this gneiss dome: (i) D1 deformation observed only as relics in the orthogneisses and their country-rocks located above the sillimanite isograd, and characterized by a NS to NE–SW non coaxial stretch associated to top to the south motions (NS convergence); (ii) D2-a deformation observed in the orthogneisses and their country-rocks, mainly migmatitic paragneisses, located below the sillimanite isograd and in the peraluminous granites whatever their structural level, and characterized by an EW to N120°E stretch associated to a top to the east flat shearing (lateral flow in the hot middle crust in a transpressive regime); (iii) D2-b deformation characterized by EW-trending megafolds corresponding to the domes in the middle crust and by EW-trending tight folds with subvertical axial planes in the metasedimentary upper crust; (iv) subvertical medium-temperature mylonitic bands developed by the end of the transpression.The Aston massif is a good example of decoupling between a cold upper crust and a hotter middle crust overheated by a thermal event originated in the upper mantle. This decoupling allowed the lateral flow of the migmatitic middle crust along a direction at high angle with respect to the more or less NS-trending direction of convergence. We suggest that the HT-LP metamorphism developed before the formation of the domes during D2-a, coevally with the emplacement of numerous sills of peraluminous granite, whereas the emplacement of the large calc-alkaline plutons in the upper crust occurred by the end of D2-b. Our data invalidate the previous geodynamical models based on either early or late extensional regime to explain the development of the HT-LP metamorphism. This new interpretation of the dynamics of the Variscan crust of the Pyrenees is consistent with recent studies conducted in Archaean and Palaeoproterozoic hot continental crusts having undergone oblique convergence, and characterized by a competition between vertical thickening and lateral flow induced by the important rheological contrast between two thermally different levels.  相似文献   
149.
This paper reports the results of an investigation of the Weichselian Upper Pleniglacial loess sequences of Nussloch (Rhine Valley, Germany) based on stratigraphy, palaeopedology, sedimentology, palynology, malacology and geochemistry (δ13C), supported by radiocarbon, TL and OSL dating. Grain-size and magnetic susceptibility records are taken at 5 cm intervals from the Upper Pleniglacial (UPG) loess. The data indicate cyclic variations in loess deposition between ca 34 and 17 ka, when the sedimentation rate is especially high (1.0–1.2 m per ka for more than 10 m). The grain-size index (GSI: ratio of coarse silt versus fine silt and clay) shows variations, which are assumed to be an indirect measurement of wind intensity. The sedimentation rate, interpreted from the profiles, indicates high values in loess (Loess events LE-1 to LE-7) and low or negligible values in tundra gley horizons G1 to G8. OSL ages from the loess and 14C dates from organic matter in the loess show that loess deposition was rapid but was interrupted by shorter periods of reduced aeolian sedimentation. Comparison between the data from Nussloch and other European sequences demonstrates a progressive coarsening of the loess deposits between ca 30 and 22 ka. This coarsening trend ends with a short but major grain-size decrease and is followed by an increase to a new maximum at 20 ± 2 ka (“W” shape). Correlation between the loess GSI and the Greenland ice-core dust records, suggests a global connection between North Atlantic and Western European global atmospheric circulation and wind regimes. In addition, the typical Upper Pleniglacial loess deposition begins at ca 30–31 ka, close to Heinrich event (HE) 3, and the main period of loess sedimentation at about 25 ± 2 ka is coeval to HE 2. Correlation of magnetic susceptibility and grain-size records shows that the periods, characterised by high GSI, coincide with an increase in the amount of ferromagnetic minerals reworked from the Rhine alluvial plain. They suggest enhancement in the frequency of the storms from N–NW. These results are integrated within a palaeogeographical model of dust transport and deposition in Western Europe for the Weichselian Upper Pleniglacial (or Late Pleniglacial).  相似文献   
150.
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