Preparation of integrative cubes as a novel biological permeable reactive barrier medium for the enhancement of in situ aerobic bioremediation of nitrobenzene-contaminated groundwater

Recent studies have indicated that in situ aerobic bioremediation is one of the most effective methods for remediating groundwater contaminated with nitrobenzene (NB). Aerobic bioremediation is largely dependent on the maintenance of adequate dissolved oxygen (DO) levels in the groundwater. Traditional in situ aeration has various disadvantages, such as high operational costs and nonuniform aeration. In this study, integrative cubes were prepared and utilized as a novel biological permeable reactive barrier (bio-PRB) medium to enhance the aerobic bioremediation of NB-contaminated groundwater. The results revealed an NB removal rate greater than 98.68% after 15–20 days of continuous oxygen release from the bio-PRB medium. DO concentrations reached 8.0 mg/L during treatment, and NB-degrading bacteria were able to tolerate a range of pH conditions. This multifaceted bio-PRB medium can simultaneously adsorb and biodegrade NB, release oxygen, and neutralize the pH with phosphate buffer. The results of this study suggest that this bio-PRB medium represents a highly effective in situ bioremediation method for NB-contaminated groundwater.     

An experimental study on variation of <Emphasis Type="Italic">b</Emphasis> value during deformation of rock samples with different structural models

A preliminary study of b value of rocks with two kinds of structural models has been made on the base of a new acoustic emission recording system. It shows that b value of the sample decreases obviously when the sample with compressive en echelon faults changes into a tensile one after interchange occurs between stress axis σ ₁ and σ ₂. A similar experiment is observed when the sample with tensile en echelon faults changes into that with a bend fault after two segments of the en echelon fault linking up. These facts indicate that the variation of b value may contain the information of the regional dominant structural model. Therefore, b-value analyses could be a new method for studying regional dominant structural models.     

Spatial and Temporal Variations of Sound Speed at the PN Section

Gridded sound speed data were calculated using Del Grosso's formulation from the temperature and salinity data at the PN section in the East China Sea covering 92 cruises between February 1978 and October 2000. The vertical gradients of sound speed are mainly related to the seasonal variations, and the strong horizontal gradients are mainly related to the Kuroshio and the upwelling. The standard deviations show that great variations of sound speed exist in the upper layer and in the slope zone. Empirical orthogonal function analysis shows that contributions of surface heating and the Kuroshio to sound speed variance are almost equivalent. This revised version was published online in July 2006 with corrections to the Cover Date.     

Assessment and Management Flash Flood in Najran Wady Using GIS and Remote Sensing

Flash flood assessment and management are necessary for municipal, urban growth planning and emergency action plans. By using the Hydrologic Engineering Centers River Analysis System software, we can model flash flood events and calculate water surface profiles over the length of the modeled stream. After collecting elevation points by using GPS method, the digital elevation model can be calculated for the study area. Najran city has main flood stream passes beside King Abdullah Road based on facts and previous works. A small study area including the mainstream of Wady Najran and King Abdullah Road has chosen as test site. The used methodology has also been proved efficiently for identifying flood inundation maps. Water extent area overlapped by 52–86% for both used methods. At discharge Q = 15 m³/s, the road needs to be protected from the flood.     

Defense community perspectives on uncertainty and confidence judgments

In 2007, the CNA Military Advisory Board (MAB), an expert panel composed of 11 retired admirals and generals from the United States, identified climate change as a “threat multiplier” for instability in some of the most volatile regions of the world. (CNA MAB National security and the threat of climate change 2007)The Department of Defense reached a similar conclusion in last year’s Quadrennial Defense Review–a legislatively mandated analysis of the Defense Department’s strategy and priorities. This document frames the long-term course for policy decision-making at the highest levels. The reports demonstrate that climate change and energy are now mainstream elements of national security planning, and can be assessed within the frameworks used to evaluate other threats, risks, and responses. However, the exact magnitude of the threat posed by climate change is difficult to calibrate in part because the language used by scientists to predict uncertainty and the confidence levels of judgments is not sufficiently clear. The defense community has a vast amount of experience exploring and dealing with uncertainty. Scientists trying to better describe the effects of climate change may be able to draw lessons from the defense community’s approach to uncertainty including how to better communicate findings to wide audiences including policy-makers.     

Evaluation of the removal of heavy metals in a natural wetland impacted by mining activities in Mexico

This research is focused on evaluating heavy metals (Cd, Cu, Fe, Mn, Pb, and Zn) uptake and removal by Eleocharis ovata, Cyperus manimae, Typha dominguensis, and Pteridium aquilinum in a natural wetland impacted by mining activities. We analyzed heavy metals content and distribution in native plants, soils, and water of a semipermanent natural wetland in Taxco de Alarcón, Guerrero, and we also determined the physicochemical characteristics of the water. Translocation factor (TF) and bioconcentration factor (BCF) were evaluated. Results showed that physical and chemical conditions are favorable for plants development. Correlation analysis showed a good and positive relation (0.95) between Cu and Pb in soils and plants. In the analyzed matrices: Zn (0.62–2.20 mg/L) exceeded the permissible limits in water, high concentrations of Pb and Zn (26.57–525.67 and 266.67–983.33 mg/kg, respectively) were detected in the studied soils, and Pb exceeded the normal range for E. ovata and P. aquilinum in the analyzed plants. Uptake of heavy metals in the tissues of different species was found in the following order: root > leaf. Data of TF and BCF showed that E. ovata is a tolerant plant with respect to heavy metals exposure since TF value was greater than 1. This study showed that E. ovata could be considered as a bioaccumulator of heavy metals in contaminated soils.     

Silver in Tokyo Bay estuarine waters and Japanese rivers

Dissolved and particulate concentrations of silver in Tokyo Bay estuarine waters and Japanese rivers were determined in this study. The dissolved silver concentrations in the surface water of Tokyo Bay range from 5.9 to 15.1 pmol kg⁻¹, which is comparable to those in the surface water of the Japan Sea, but two or three times higher than those in the surface water of the open ocean. However, elevated concentrations of dissolved silver are not found in Tokyo Bay compared with those in other highly urbanized estuaries, such as San Francisco Bay (20∼243 pmol kg⁻¹). In the Tokyo Bay estuary, silver typically exhibits non-conservative mixing behavior, which is a common feature in the other estuaries reported previously. Dissolved silver concentrations decrease with salinity from the rivers to the mouth of Tokyo Bay. Silver is efficiently scavenged by suspended particulates, as evidenced by the high conditional distribution coefficients for silver throughout the estuary (log K_d > 5.0 ± 0.6). The silver fluxes into Tokyo Bay via inflowing rivers and atmospheric deposition were estimated as 83 kg y⁻¹ and 15 kg y⁻¹, respectively. A simple budget calculation shows that the silver supplied from rivers and atmosphere must be rapidly scavenged within the Tokyo Bay estuary.     

New insights into the high-pressure polymorphism of SiO<Subscript>2</Subscript> cristobalite

Single-crystal X-ray diffraction experiments with SiO₂ α-cristobalite reveal that the well-known reversible displacive phase transition to cristobalite-II, which occurs at approximately 1.8 GPa, can be suppressed by rapid pressure increase, leading to an overpressurized metastable state, persisting to pressure as high as 10 GPa. In another, slow pressure increase experiment, the monoclinic high-pressure phase-II was observed to form at ~1.8 GPa, in agreement with earlier in situ studies, and its crystal structure has been unambiguously determined. Single-crystal data have been used to refine the structure models of both phases over the range of pressure up to the threshold of formation of cristobalite X-I at ~12 GPa, providing important constraints on the feasibility of the two competing silica densification models proposed in the literature, based on quantum mechanical calculations. Preliminary diffraction data obtained for cristobalite X-I reveal a monoclinic unit cell that contradicts the currently assumed model.     

Residual drift demands in moment‐resisting steel frames subjected to narrow‐band earthquake ground motions

This paper presents the main results of the evaluation of residual inter‐story drift demands in typical moment‐resisting steel buildings designed accordingly to the Mexican design practice when subjected to narrow‐band earthquake ground motions. Analytical 2D‐framed models representative of the study‐case buildings were subjected to a set of 30 narrow‐band earthquake ground motions recorded on stations placed in soft‐soil sites of Mexico City, where most significant structural damage was found in buildings as a consequence of the 1985 Michoacan earthquake, and scaled to reach several levels of intensity to perform incremental dynamic analyses. Thus, results were statistically processed to obtain hazard curves of peak (maximum) and residual drift demands for each frame model. It is shown that the study‐case frames might exhibit maximum residual inter‐story drift demands in excess of 0.5%, which is perceptible for building's occupants and could cause human discomfort, for a mean annual rate of exceedance associated to peak inter‐story drift demands of about 3%, which is the limiting drift to avoid collapse prescribed in the 2004 Mexico City Seismic Design Provisions. The influence of a member's post‐yield stiffness ratio and material overstrength in the evaluation of maximum residual inter‐story drift demands is also discussed. Finally, this study introduces response transformation factors, T_p, that allow establishing residual drift limits compatible with the same mean annual rate of exceedance of peak inter‐story drift limits for future seismic design/evaluation criteria that take into account both drift demands for assessing a building's seismic performance. Copyright © 2013 John Wiley & Sons, Ltd.     

Microtopography,water storage and flow patterns in a fine‐textured soil under agricultural use

Agricultural use of soils implies tillage and often compaction and therefore influences processes on soil surface and affects infiltration of water into the subsoil. Although many studies on soil surface processes or flow patterns in soils exist, works relating both are rare in literature. We did two tracer experiments with Brilliant Blue FCF on a tilled and compacted plot and a non‐tilled one to investigate water storage on the soil surface during simulated rainfall and changes of soil microtopography, to analyse the associated flow patterns in the soil and to relate both to tillage and compaction. Our results show that storage was larger on the tilled and compacted plot than on the non‐tilled one. After tillage, transport processes above the plough pan were partly disconnected from those underneath because macropores were disrupted and buried by the tillage operation. However, preferential flow along cracks occurred on both plots and the macropores buried below the tillage pan still functioned as preferential flow paths. Therefore, we conclude that the studied soil is susceptible to deep vertical solute propagation at dry conditions when cracks are open, irrespective of tillage and compaction. Copyright © 2012 John Wiley & Sons, Ltd.