A comet in the lab

What have Stardust samples told us about the early solar system? Phil A Bland, Anton T Kearsley, P J Wozniakiewicz, M J Burchell, M Gounelle, M E Zolensky and Matt J Genge have some of the answers – and a few more questions.     

Solvent extraction followed by ultraviolet detection for investigation of tetramethylthiuram disulfide at soil-water interface

Tetramethylthiuram disulfide is a widely used pesticide and a soil treatment agent in the agricultural sector. Consequently, its detection in the environment and investigation of the distribution between the aqueous and soil phases would be of highly importance. In this study, the detection of tetramethylthiuram disulfide in CHCl₃ was successfully achieved through absorbance measurements at 280 nm, which resulted in linear calibration curves. This detection method was extended for the determination of the partition coefficient (K_D) of tetramethylthiuram disulfide between CHCl₃ and H₂O phases at ambient temperature. The partition coefficient was subsequently used to determine the apparent partition coefficient (K_D) of tetramethylthiuram disulfide between sieved soil of diamater < 2.0 mm used for agricultural practices and water where by the quantification of tetramethylthiuram disulfide in water after adsorption equilibrium with soil was achieved through a solvent extraction step of tetramethylthiuram disulfide-contaminated water into CHCl₃. The K_D determined for an initial tetramethylthiuram disulfide concentration ranging from 3.00 ppm to 10.00 ppm showed a decreasing trend, which leveled off at high concentrations, indicating the strong irreversible adsorption behavior of tetramethylthiuram disulfide on soil at low concentrations. The proposed detection method would have the potential to determine the extent of adsorption of tetramethylthiuram disulfide in soil or its levels in water when tetramethylthiuram disulfide is introduced to soil systems for agricultural practices.     

Information technology changes corporate office activity

Corporate office activity is concentrated close to head offices in South Eastern England. It is often argued that information technology could change the location of offices by reducing the cost of provincial workplaces. The reorganisation of office functions associated with the introduction of information technology could also provide an opportunity to decentralise administrative structures.Two case studies in offices in manufacturing industry suggest that information technology can in fact be used to support either the centralisation or decentralisation of office work. The impact of the technology varies between corporate structures. In Unilever, a decentralised organisation, information technology has encouraged the decentralisation of routine administrative functions. In the more tightly-controlled Ford accounting function the mechanisation of accounts has been associated with the centralisation of administration at key sites. In both corporate structures it seems that information technology is being used to centralise important management functions.     

Volcanic threat in developing countries of the Asia�CPacific region: probabilistic hazard assessment, population risks, and information gaps

The importance of disaster reduction has gained increased awareness within the international development community and thereby highlighted a need for a preliminary assessment of natural hazard risk in developing countries of the Asia?CPacific, including that for volcanic eruption. In this paper, we present a key component of such an assessment, which involved qualifying the frequency and potential consequences of large??Volcanic Explosivity Index of four or more??volcanic eruptions. The frequencies of large eruptions from volcanoes grouped by region were determined from frequency?Cmagnitude plots using data provided by the Smithsonian Institution??s Global Volcanism Program. However, calculated frequencies represent only minimum values due to an incomplete eruption record. Unfortunately, limited data precluded the calculation of eruption frequencies for the Solomon Islands, Fiji and Samoa. A first-order analysis of the populations potentially impacted by large volcanic eruptions suggest that (1) volcanic disasters affecting populations of >100,000 can be expected at least every decade in Indonesia and once every few decades in the Philippines and (2) a volcanic disaster impacting >1% of the population can be expected twice a century in Vanuatu, twice a millennium for Indonesia and the Philippines, and around every millennium in Papua New Guinea and Tonga.     

Asteroid (101955) 1999 RQ36: Spectroscopy from 0.4 to 2.4 μm and meteorite analogs

We present reflectance spectra from 0.4 to 2.4 μm of Asteroid (101955) 1999 RQ36, the target of the OSIRIS-REx spacecraft mission. The visible spectral data were obtained at the McDonald Observatory 2.1-m telescope with the ES2 spectrograph. The infrared spectral data were obtained at the NASA Infrared Telescope Facility using the SpeX instrument. The average visible spectrum is combined with the average near-infrared wavelength spectrum to form a composite spectrum. We use three methods to constrain the compositional information in the composite spectrum of Asteroid (101955) 1999 RQ36 (hereafter RQ36). First, we perform a least-squares search for meteorite spectral analogs using 15,000 spectra from the RELAB database. Three most likely meteorite analogs are proposed based on the least-squares search. Next, six spectral parameters are measured for RQ36 and their values are compared with the ranges in parameter values of the carbonaceous chondrite meteorite classes. A most likely meteorite analog group is proposed based on the depth of overlap in parameter values. The results of the least-squares search and the parametric comparisons point to CIs and/or CMs as the most likely meteorite analogs for RQ36, and COs and CHs as the least likely. RQ36 has a spectrally “blue” continuum slope that is also observed in carbonaceous chondrites containing magnetite. We speculate that RQ36 is composed of a “CM1”-like material. Finally, we compare RQ36 to other B-type asteroids measured by Clark et al. (Clark, B.E. et al. [2010]. J. Geophys. Res. 115, E06005). The results of this comparison are inconclusive. RQ36 is comparable to Themis spectral properties in terms of its albedo, visible spectrum, and near-infrared spectrum from 1.1 to 1.45 μm. However, RQ36 is more similar to Pallas in terms of its near-infrared spectrum from 1.6 to 2.3 μm. Thus it is possible that B-type asteroids form a spectral continuum and that RQ36 is a transitional object, spectrally intermediate between the two end-members. This is particularly interesting because Asteroid 24 Themis was recently discovered to have H₂O ice on the surface (Rivkin, A., Emery, J. [2010]. Nature 464, 1322–1323; Campins, H. et al. [2010a]. Nature 464, 1320–1321).