Bromine species fluxes from Lake Constance’s catchment, and a preliminary lake mass balance

Bromine was historically termed a cyclic salt in terrestrial freshwater environments due to its perceived conservative cycling between the oceans and the continents. This basic assumption has been challenged recently, with evidence that bromine is involved in dynamic chemical cycles in soils and freshwaters. We present here a study on dissolved bromine species (bromide, organically bound bromine, DOBr) concentrations and fluxes as well as sediment trap bromine levels and fluxes in Lake Constance, a large lake in southern Germany. Water samples were obtained from all major and some minor inflows and outflows over one year, where-after dissolved bromine species were measured by a combination of ICP-MS and ion chromatography coupled to an ICP-MS (IC-ICP-MS). Sediment traps were deployed at two locations for two years with Br, Ti and Zr levels being measured by μ-XRF.190 t yr⁻¹ of total dissolved bromine (TDBr) was delivered to the lake via 14 rivers and precipitation, with the rivers Alpenrhein (84 t TDBr yr⁻¹) and the Schussen (50 t TDBr yr⁻¹) providing the largest sources. The estimated particulate bromine flux contributed an extra 24-26 t Br yr⁻¹. In comparison, only 40 t TDBr yr⁻¹ was deposited to the lake’s catchment by precipitation, and thus ∼80% of the riverine TDBr flux came from soils and rocks. Bromide was the dominant species accounting for, on average, 78% of TDBr concentrations and 93% of TDBr flux to the lake. Despite some high concentrations in the smaller lowland rivers, DOBr was only a minor component of the total riverine bromine flux (∼12 t yr⁻¹, 7%), most of which came from the rivers Schussen, Bregenzer Ach and Argen. In contrast, most of the bromine in the sediment traps was bound to organic matter, and showed a clear seasonal pattern in concentrations, with a maximum in winter and minimum in summer. The summer minimum is thought to be due to dilution of a high Br autochthonous component by low bromine mineral and organic material from the catchment, which is supported by Ti, Zr and Br/C_org data. In the lake bromine was irreversibly lost to the sediments, with best flux estimates based on mass-balance and sediment trap data of +50-90 μg Br m⁻² d⁻¹. Overall, it appears that bromine is not simply a cyclic salt in the case of Lake Constance, with a clear geological component and dynamic lacustrine biogeochemistry.     

The SMART-1 AMIE experiment: implication to the lunar opposition effect

The lunar surface reveals a sharp opposition effect, which is to be explained by the shadowing and coherent backscattering mechanisms. Generalizing the radiative transfer theory via Monte Carlo methods, we are carrying out studies of backscattering in regolith-like scattering media. We have also started systematic laboratory measurements of structural simulators of lunar regolith. The SMART-1 AMIE and D-CIXS/XSM experiments provide us a unique opportunity for a simultaneous multiwavelength study of the lunar regolith close to opposition, since the SMART-1 spacecraft will pass over several different types of lunar surface at zero phase angles. Results of our theoretical and laboratory investigations can be used as a basis to interpret the SMART-1 AMIE and D-CIXS/XSM experiments. In particular, it seems to be possible to estimate regional variations of regolith particle volume fraction and their size. A short review of observational, experimental and theoretical works is also presented here.     

The profile of Saturn's ring a as derived from stellar occultations

Stellar occultations behind Saturn's ring A reveal sharp-edged gaps in its outer parts. Observed fluctuations in stellar brightness during one observation can be interpreted as Fresnel's diffraction zones. According to this the sharpness of the edges of the gap are estimated to be under 700 m, which also means that the thickness of ring A in that part cannot exceed a few hundred metres. A further conclusion is that particle size must be a lot less than a few hundred metres.     

Bidirectional reflectance spectrometry of gravel at the Sjökulla test field

The Sjökulla test site is used for testing and calibrating aerial images. The permanent test field is made of four types of gravel (dark gabbro, grey granite, red granite, white limestone) in two sizes (diameters 8–16 mm and 4–8 mm) set in various patterns. The bidirectional reflection properties of the targets together with their temporal changes must be known in order to carry out radiometric and spectral evaluation and calibration.The bidirectional reflectance distribution functions (BRF) of the gravel have been measured several times in the test fields using portable field goniospectrometers belonging Finnish Geodetic Institute (FGI), and once using the European Goniometic Facility (EGO) of the Joint Research Centre (JRC) at Ispra, Italy. Detailed BRFs have been obtained, showing features typical to particulate media, e.g. a small bowl shape, strong backscattering, and smooth wavelength dependence. Temporal range measurements over several years show that the black gabbro and red granite are fairly stable, while the grey granite has changed somewhat over the years and the white limestone has experienced dramatic darkening effects, requiring action to be taken.The measured BRF data have increased the usability of the test field considerably. The results are also useful in the development and validation of scattering models for particulate media. The site has proved to be a good test bench for goniospectrometric instruments, too.     

Karstological study of the new Kunming airport building area (Yunnan, China)

In Kunming area (6.8 mio population), two big interventions are in progress: construction of a new airport, the 23 km² area of which will extend across karst terrain northeast of the city, and extensive uptake of water from karst aquifers for drinking and agricultural use. In the study, an interdisciplinary approach was utilized to demonstrate the need for holistic karstology studies prior to performing extensive interferences in the karst environment. This study included survey of surface karst features and microscopic analyses of rock samples in the area of the new airport location, accompanied by hydrogeological studies and microbiological analyses of two karst drinking water sources in its vicinity (Qinglongdong, Huanglongdong). Results showed the specific characteristics of the subsoil stone forest that indicated a high level of karstification. The direction and characteristics of groundwater flow from the sinking Qiaotou Stream at the margin of the new airport area toward the Huanglongdong Spring were defined with a single tracer test. Additional information about hydrogeological characteristics of the karst aquifer was obtained by individual measurements of physical and chemical parameters of the springs and sinking stream. Selected chemical and bacteriological parameters showed substantial pollution of both springs due to various types of human activities in the catchments. The results of the study pointed to the necessity of taking immediate measures for the springs’ protection and showed the importance of interdisciplinary research when planning anthropogenic activities in the karst.     

An historical empirical line method for the retrieval of surface reflectance factor from multi-temporal SPOT HRV,HRVIR and HRG multispectral satellite imagery

SPOT satellites have been imaging Earth's surface since SPOT 1 was launched in 1986. It is argued that absolute atmospheric correction is a prerequisite for quantitative remote sensing. Areas where land cover changes are occurring rapidly are also often areas most lacking in situ data which would allow full use of radiative transfer models for reflectance factor retrieval (RFR). Consequently, this study details the proposed historical empirical line method (HELM) for RFR from multi-temporal SPOT imagery. HELM is designed for use in landscape level studies in circumstances where no detailed overpass concurrent atmospheric or meteorological data are available, but where there is field access to the research site(s) and a goniometer or spectrometer is available. SPOT data are complicated by the ±27° off-nadir cross track viewing. Calibration to nadir only surface reflectance factor (ρ_s) is denoted as HELM-1, whilst calibration to ρ_s modelling imagery illumination and view geometries is termed HELM-2. Comparisons of field measured ρ_s with those derived from HELM corrected SPOT imagery, covering Helsinki, Finland, and Taita Hills, Kenya, indicated HELM-1 RFR absolute accuracy was ±0.02ρ_s in the visible and near infrared (VIS/NIR) bands and ±0.03ρ_s in the shortwave infrared (SWIR), whilst HELM-2 performance was ±0.03ρ_s in the VIS/NIR and ±0.04ρ_s in the SWIR. This represented band specific relative errors of 10–15%. HELM-1 and HELM-2 RFR were significantly better than at-satellite reflectance (ρ_SAT), indicating HELM was effective in reducing atmospheric effects. However, neither HELM approach reduced variability in mean ρ_s between multi-temporal images, compared to ρ_SAT. HELM-1 calibration error is dependent on surface characteristics and scene illumination and view geometry. Based on multiangular ρ_s measurements of vegetation-free ground targets, calibration error was negligible in the forward scattering direction, even at maximum off-nadir view. However, error exceeds 0.02ρ_s where off-nadir viewing was ≥20° in the backscattering direction within ±55° azimuth of the principal plane. Overall, HELM-1 results were commensurate with an identified VIS/NIR 0.02ρ_s accuracy benchmark. HELM thus increases applicability of SPOT data to quantitative remote sensing studies.     

Mapping Meaning: Critical Cartographies for Participatory Water Management in Taita Hills,Kenya

Participation of local people is often neglected in natural resource management, which leads to failure to understand the social aspects and historical construction of environmental problems. Participatory mapping can enhance the communication of local spatial knowledge for management processes and challenge the official maps and other spatial representations produced by state authorities and scientists. In this study, we analyze what kind of social meanings can be revealed through a multimethod participatory mapping process focusing on water resources in Taita Hills, Kenya. The participatory mapping clearly complicates the simplified image of the physical science mappings, typically depicting natural water supply, by addressing the impacts of contamination, inadequate infrastructure, poverty, distance to the sources, and restrictions in their uses on people's access to water. Moreover, this shared exercise is able to trigger discussion on issues that cannot always be localized but still contribute to place making. Local historical accounts reveal the social and political drivers of the current water-related problems, making explicit the political ecology dynamics in the area.     

The east-west asymmetry of Saturn's rings: New measurements

Measurements made during 1976–1979 at the Aarne Karjalainen Observatory show slight east-west asymmetry of Saturn's ring B.     

Confusion limit resulting from galaxies: using the Infrared Array Camera on board SIRTF

Recent ISO data have allowed, for the first time, observationally based estimates for source confusion in mid-infrared surveys. We use the extragalactic source counts from ISOCAM in conjunction with K -band counts to predict the confusion resulting from galaxies in deep mid-infrared observations. We specifically concentrate on the near-future Space Infrared Telescope Facility ( SIRTF ) mission, and calculate expected confusion for the Infrared Array Camera (IRAC) on board SIRTF . A defining scientific goal of the IRAC instrument will be the study of high-redshift galaxies using a deep, confusion-limited wide-field survey at 3–10 μm . A deep survey can reach 3-μJy sources with reasonable confidence in the shorter wavelength IRAC bands. Truly confusion-limited images with the 8 μm will be difficult to obtain because of practical time constraints, unless infrared galaxies exhibit very strong evolution beyond the deepest current observations. We find L * galaxies to be detectable to z =3–3.5 at 8 μm, which is slightly more pessimistic than found in 1999 by Simpson & Eisenhardt.