Estimation of kinetic parameters of a grinding-liberation model

A method of parameter estimation is outlined for a two-component grinding-liberation model. The large number of model variables is reduced by using functional forms. The parameters for the functional forms are estimated using a modified Gauss-Newton algorithm. The technique is applied to both synthetic and real experimental data. Parameters estimated from wet grinding batch tests of Illinois No. 6 coal were used to predict mill output for a larger pilot-plant mill. The predictions were found to match the actual mill output within the limits of experimental error.     

Mixing and cycling of uranium,thorium and 210Pb in Puget Sound sediments

Activity profiles of excess ²³⁴Th, excess ²¹⁰Pb, ²³²Th, ²³⁰Th, ²³⁴U and ²³⁸U, and ^228/232Th ratios determined in eight box cores of sediment from six sites in central Puget Sound provide new insights into the dynamic nature of solid phase mixing in surface sediments, the exchange of ²²⁸Ra and other soluble species across the sediment-water interface, and the cycling of U, Th and ²¹⁰Pb in this coastal zone.Comparison of excess ²³⁴Th inventories in sediments with its production rate in the overlying water column indicates a mean residence time of at most 14 days for particles in the central Puget Sound water column.Surface sediment horizons with excess ²³⁴Th have no excess ²²⁸Th which might be used to ascertain sediment accumulation rates over the past decade. Instead, deficiencies of ²²⁸Th due to loss of soluble ²²⁸Ra from pore water to the overlying water persist to 20–30 cm, revealing that exchange of soluble chemicals between pore and overlying waters reaches these depths in the extensively bioturbated sediments of Puget Sound.Solid phase U isotope concentrations tend to increase by up to a factor of two with depth in sediments, as a result of dissolved U being biologically pumped down into sediments where it is partially removed when conditions become mildly reducing. ²³²Th and ²³⁰Th activities and ^230/232Th ratios are constant with depth in sediments, indicating constant detrital phase compositions and essentially no authigenic ²³⁰Th. Steady state ²¹⁰Pb depositional activities in and fluxes to Puget Sound sediments average only about onehalf those for sediments of the open Washington coast north of the Columbia River mouth, primarily because of a much lower supply of dissolved ²¹⁰Pb in sea waters adverting into Puget Sound.Excess ²³⁴Th profiles in sediments reveal much more detail about the depth dependency, dynamic nature and recent history of solid phase mixing processes than excess ²¹⁰Pb profiles. At least six of eight ²³⁴Th profiles show that mixing within the ²¹⁰Pb-defined surface mixed layer is depth dependent. In three profiles, ²³⁴Th-derived mixing rates are fastest several centimeters below the sediment-water interface, indicating greater macro-benthic activity at these depths. Depth dependent mixing coefficients derived from the best fit of a four layer, advection-diffusion-decay model to the ²³⁴Th data are consistent with ²¹⁰Pb profiles determined for the same sediments, strongly suggesting that ²³⁴Th and ²¹⁰Pb are mixed equivalently and in a multilayered manner.     

Effect of sediment size on area of influence during groundwater remediation by air sparging: a laboratory approach

 Air sparging is a groundwater remediation technique, in which organic contaminants volatilize into air as it rises from the saturated to vadose zone. An unknown has been the relationship between sediment size and area affected by air. Laboratory experiments were performed on sediments to determine the area affected by air as a function of grain size. For average grain sizes of 1.1 and 1.3-mm diameter, air flow occurs in discrete meandering channels, with a maximum area of sediment column affected of 13%/m² for 1.1-mm and 14%/m² for 1.3-mm sediments. For average grain sizes of 1.84, 2.61 and 4.38-mm diameter, air flow is pervasive, forming a symmetrical cone of influence around the injection point. Maximum areas affected are15%/m² for 1.84-mm, 25%/m² for 2.61-mm, and 9%/m² for 4.38-mm sediments. Optimal sites for air sparging, may be those with grain diameters between about 2–3 mm. Received: 26 June 1998 · Accepted: 27 July 1998     

Hummock corridors in the south‐central sector of the Fennoscandian ice sheet,morphometry and pattern

Subglacial conditions strongly influence the flow of ice‐sheets, in part due to the availability of melt water. Contemporary ice sheets are retreating and are affected by increased melting as climate warms. The south Swedish uplands (SSU) were deglaciated during the relatively warm Bølling‐Allerød interval, and by studying the glacial landforms there it is possible to increase the understanding of the subglacial environment during this period of warming. Across the study area, vast tracts of hummocks have long been recognized. However, recent mapping shows a pattern of elongated zones of hummocks radially oriented, hereafter referred to as ‘hummock corridors’. Morphometric parameters were measured on the hummock corridors using a 2 m horizontal resolution digital elevation model. Corridor width varies between 0.2 and 4.9 km and their length between 1.5 and 11.8 km. A majority of hummock corridors are incised in drumlinised till surfaces. The pattern of hummock corridors shows a clear relation to the overall ice‐flow. Further, hummock corridors do not follow topographic gradients, and in at least one place an esker overlies hummocks on the corridor floor. The lateral spacing of hummock corridors and corridor morphology are similar to tunnel valleys, eskers and glaciofluvial corridors reported elsewhere. Such relationships support a subglacial genesis of the corridors in the SSU by water driven by the subglacial hydraulic gradient and that hummock corridors are forms that can be identified as tunnel valleys and glaciofluvial corridors (GFC). Ages were assigned to hummock‐corridor cross‐sections from a deglacial reconstruction of the Fennoscandian Ice Sheet. By comparing the frequency of corridors per age interval with climate variations from a Greenland ice core, we hypothesize that an increase in the number of corridors is related to the Bølling‐Allerød warming, indicating a higher rate of delivery of surface melt water to the bed at this time. Copyright © 2017 John Wiley & Sons, Ltd.     

Joint Estimation of Gross Recharge,Groundwater Usage,and Hydraulic Properties within HydroSight

Groundwater management decisions are often founded upon estimates of aquifer hydraulic properties, recharge and the rate of groundwater usage. Too often hydraulic properties are unavailable, recharge estimates are very uncertain, and usage is unmetered or infrequently metered over only recent years or estimated using numerical groundwater models decoupled from the drivers of drawdown. This paper extends the HydroSight groundwater time-series package ( http://peterson-tim-j.github.io/HydroSight/ ) to allow the joint estimation of gross recharge, transmissivity, storativity, and daily usage at multiple production bores. A genetic evolutionary scheme was extended from estimating time-series model parameters to also estimating time series of usage that honor metered volumes at each production bore and produces (1) the best fit with the observed hydrograph and (2) plausible estimates of actual evapotranspiration and hence recharge. The reliability of the approach was rigorously tested. Repeated calibration of models for four bores produced estimates of transmissivity, storativity, and mean recharge that varied by a factor of 0.22-0.32, 0.13-0.2, and 0.03-0.48, respectively, when recharge boundary effects were low and the error in monthly, quarterly, and biannual metered usage was generally <10%. Application to the 30 observation bores within the Warrion groundwater management area (Australia), produced a coefficient of efficiency of ≥0.80 at 22 bores and ≥0.90 at 12 bores. The aquifer transmissivity and storativity were reasonably estimated, and were consistent with independent estimates, while mean gross recharge may be slightly overestimated. Overall, the approach allows greater insights from the available data and provides opportunity for the exploration of usage and climatic scenarios.     

Effects of hydrostatic pressure on microbial alteration of sinking fecal pellets

We used a new experimental device called PASS (PArticle Sinking Simulator) during MedFlux to simulate changes in in situ hydrostatic pressure that particles experience sinking from mesopelagic to bathypelagic depths. Particles, largely fecal pellets, were collected at 200 m using a settling velocity NetTrap (SV NetTrap) in Ligurian Sea in April 2006 and incubated in high-pressure bottles (HPBs) of the PASS system under both atmospheric and continuously increasing pressure conditions, simulating the pressure change experienced at a sinking rate of 200 m d⁻¹. Chemical changes over time were evaluated by measuring particulate organic carbon (POC), carbohydrates, transparent exopolymer particles (TEP), amino acids, lipids, and chloropigments, as well as dissolved organic carbon (DOC) and dissolved carbohydrates. Microbial changes were evaluated microscopically, using diamidinophenylindole (DAPI) stain for total cell counts and catalyzed reporter deposition-fluorescence in situ hybridization (CARD-FISH) for phylogenetic distinctions. Concentrations (normalized to POC) of particulate chloropigments, carbohydrates and TEP decreased under both sets of incubation conditions, although less under the increasing pressure regime than under atmospheric conditions. By contrast, dissolved carbohydrates (normalized to DOC) were higher after incubation and significantly higher under atmospheric conditions, suggesting they were produced at the expense of the particulate fraction. POC-normalized particulate wax/steryl esters increased only under pressure, suggesting biochemical responses of prokaryotes to the increasing pressure regime. The prokaryotic community initially consisted of 43% Bacteria, 12% Crenarchaea and 11% Euryarchaea. After incubation, Bacteria dominated (90%) the prokaryote community in all cases, with γ-Proteobacteria comprising the greatest fraction, followed by the Cytophaga–Flavobacter cluster and α-Proteobacteria group. Using the PASS system, we obtained chemical and microbial evidence that degradation by prokaryotes associated with fecal pellets sinking through mesopelagic waters is limited by the increasing pressure they experience.     

Organic biomarkers in the twilight zone—Time series and settling velocity sediment traps during MedFlux

The transfer of material through the twilight zone of the ocean is controlled by sinking particles that contain organic matter (OM) and mineral ballast. During the MedFlux field program in the northwestern Mediterranean Sea in 2003, sinking particulate matter was collected in time series (TS) and settling velocity (SV) traps and analyzed for amino acids, lipids, and pigments (along with ballast minerals) [Lee, C., Armstrong, R.A., Wakeham, S.G., Peterson, M.L., Miquel, J.C., Cochran, J.K., Fowler, S.W., Hirschberg, D., Beck, A. Xue, J., 2009b. Particulate matter fluxes in time series and settling velocity sediment traps in the northwestern Mediterranean Sea. Deep-Sea Research II, this volume [doi:10.1016/j.dsr2.2008.12.003]]. The goal was to identify how organic chemical compositions of sinking particles varied as a function of their in-situ settling velocity. The TS record was used to define the biogeochemical character and temporal pattern in flux during the period of SV trap deployment. Temporal variations in organic and mineral compositions are consistent with particle biogeochemistry being driven by the seasonal succession of phytoplankton. Spring diatom bloom conditions led to a high flux of rapidly sinking aggregates and zooplankton fecal matter; summer oligotrophy followed and was characterized by a higher proportion of slowly sinking phytoplankton cells. Bacterial degradation is particularly important during the low-flux summer period. Settling velocity traps show that a large proportion of particulate organic matter sinks at 200–500 m d⁻¹. Organic compositions of this fast-sinking material mirrors that of fecal pellets and aggregated material that sinks as the spring bloom terminates. More-slowly sinking OM bears a stronger signature of bacterial degradation than do the faster-sinking particles. The observation that compositions of SV-sorted fractions are different implies that the particle field is compositionally heterogeneous over a range of settling velocities. Thus physical and biological exchange between fast-sinking and slow-sinking particles as they pass down the water column must be incomplete.     

Quantifying nitrogen cycling beneath a meander of a low gradient,N‐impacted,agricultural stream using tracers and numerical modelling

In watersheds impacted by nitrate from agricultural fertilizers, nitrification and denitrification may be decoupled as denitrification in the hyporheic zone is not limited to naturally produced nitrate. While most hyporheic research focuses on the 1–2 m of sediment beneath the stream bed, there are a limited number of studies that quantify nitrogen (N) cycling at larger hyporheic scales (10s of metres to kms). We conducted an investigation to quantify N cycling through a single meander of a low gradient, meandering stream, draining an agricultural watershed. Chemistry (major ions and N species) and hydrologic data were collected from the stream and groundwater beneath the meander. Evidence indicates that nearly all the shallow groundwater flowing beneath the meander originates as stream water on the upgradient side of the meander, and returns to the stream on the downgradient side. We quantified the flux of water beneath the meander using a numerical model. The flux of N into and out of the meander was quantified by multiplying the concentration of the important N species (nitrate, ammonium, dissolved organic nitrogen (DON)) by the modelled water fluxes. The flux of N into the meander is dominated by nitrate, and the flux of N out of the meander is dominated by ammonium and DON. While stream nitrate varied seasonally, ammonium and DON beneath the meander were relatively constant throughout the year. When stream nitrate concentrations are high (>2 mg litre^?1), flow beneath the meander is a net sink for N as more N from nitrate in stream water is consumed than is produced as ammonium and DON. When stream nitrate concentrations are low (<2 mg litre^?1), the flux of N entering is less than exiting the meander. On an annual basis, the meander hyporheic flow serves as a net sink for N. Copyright © 2007 John Wiley & Sons, Ltd.