Estrogen in a karstic aquifer

Adverse impacts on the health of some fish populations, such as skewed sex distributions, have been noted in surface waters and in laboratory experiments with relatively low concentrations (above 25 ng/L) of natural estrogen (17 beta-estradiol--E2). Sources of E2 to surface and ground waters can include avian, human, and mammalian waste products. The Ozark Plateau Aquifer (OPA) is a karstic basin that receives a significant portion of its water through losing reaches of rivers. Thus, there is a direct connection between surface water and ground water. The OPA was targeted for an E2 study to assess the potential for adverse health effects to aquatic organisms living in the system. Eight springs, which drain the aquifer, were sampled quarterly. The concentrations of E2 in the OPA ranged from 13 to 80 ng/L. For any one sampling event, the concentrations of E2 at the spring waters were statistically similar; however, the concentrations of E2 at all springs varied throughout the year. At Maramec Spring, one of the larger springs, the E2 concentration, was correlated with discharge. Based on the correlation between discharge and E2 concentration, aquatic organisms living in the plateau or in its discharged waters, including the threatened southern cavefish T. subterraneus, are exposed to concentration of E2 above 25 ng/L approximately 60% of the time. This implies that organisms living in karst basins throughout the OPA are likely exposed to E2 concentrations that may adversely impact their reproductive success for a significant portion of each year.     

Estimation of kinetic parameters of a grinding-liberation model

A method of parameter estimation is outlined for a two-component grinding-liberation model. The large number of model variables is reduced by using functional forms. The parameters for the functional forms are estimated using a modified Gauss-Newton algorithm. The technique is applied to both synthetic and real experimental data. Parameters estimated from wet grinding batch tests of Illinois No. 6 coal were used to predict mill output for a larger pilot-plant mill. The predictions were found to match the actual mill output within the limits of experimental error.     

Effect of sediment size on area of influence during groundwater remediation by air sparging: a laboratory approach

 Air sparging is a groundwater remediation technique, in which organic contaminants volatilize into air as it rises from the saturated to vadose zone. An unknown has been the relationship between sediment size and area affected by air. Laboratory experiments were performed on sediments to determine the area affected by air as a function of grain size. For average grain sizes of 1.1 and 1.3-mm diameter, air flow occurs in discrete meandering channels, with a maximum area of sediment column affected of 13%/m² for 1.1-mm and 14%/m² for 1.3-mm sediments. For average grain sizes of 1.84, 2.61 and 4.38-mm diameter, air flow is pervasive, forming a symmetrical cone of influence around the injection point. Maximum areas affected are15%/m² for 1.84-mm, 25%/m² for 2.61-mm, and 9%/m² for 4.38-mm sediments. Optimal sites for air sparging, may be those with grain diameters between about 2–3 mm. Received: 26 June 1998 · Accepted: 27 July 1998     

Hummock corridors in the south‐central sector of the Fennoscandian ice sheet,morphometry and pattern

Subglacial conditions strongly influence the flow of ice‐sheets, in part due to the availability of melt water. Contemporary ice sheets are retreating and are affected by increased melting as climate warms. The south Swedish uplands (SSU) were deglaciated during the relatively warm Bølling‐Allerød interval, and by studying the glacial landforms there it is possible to increase the understanding of the subglacial environment during this period of warming. Across the study area, vast tracts of hummocks have long been recognized. However, recent mapping shows a pattern of elongated zones of hummocks radially oriented, hereafter referred to as ‘hummock corridors’. Morphometric parameters were measured on the hummock corridors using a 2 m horizontal resolution digital elevation model. Corridor width varies between 0.2 and 4.9 km and their length between 1.5 and 11.8 km. A majority of hummock corridors are incised in drumlinised till surfaces. The pattern of hummock corridors shows a clear relation to the overall ice‐flow. Further, hummock corridors do not follow topographic gradients, and in at least one place an esker overlies hummocks on the corridor floor. The lateral spacing of hummock corridors and corridor morphology are similar to tunnel valleys, eskers and glaciofluvial corridors reported elsewhere. Such relationships support a subglacial genesis of the corridors in the SSU by water driven by the subglacial hydraulic gradient and that hummock corridors are forms that can be identified as tunnel valleys and glaciofluvial corridors (GFC). Ages were assigned to hummock‐corridor cross‐sections from a deglacial reconstruction of the Fennoscandian Ice Sheet. By comparing the frequency of corridors per age interval with climate variations from a Greenland ice core, we hypothesize that an increase in the number of corridors is related to the Bølling‐Allerød warming, indicating a higher rate of delivery of surface melt water to the bed at this time. Copyright © 2017 John Wiley & Sons, Ltd.     

Effects of hydrostatic pressure on microbial alteration of sinking fecal pellets

We used a new experimental device called PASS (PArticle Sinking Simulator) during MedFlux to simulate changes in in situ hydrostatic pressure that particles experience sinking from mesopelagic to bathypelagic depths. Particles, largely fecal pellets, were collected at 200 m using a settling velocity NetTrap (SV NetTrap) in Ligurian Sea in April 2006 and incubated in high-pressure bottles (HPBs) of the PASS system under both atmospheric and continuously increasing pressure conditions, simulating the pressure change experienced at a sinking rate of 200 m d⁻¹. Chemical changes over time were evaluated by measuring particulate organic carbon (POC), carbohydrates, transparent exopolymer particles (TEP), amino acids, lipids, and chloropigments, as well as dissolved organic carbon (DOC) and dissolved carbohydrates. Microbial changes were evaluated microscopically, using diamidinophenylindole (DAPI) stain for total cell counts and catalyzed reporter deposition-fluorescence in situ hybridization (CARD-FISH) for phylogenetic distinctions. Concentrations (normalized to POC) of particulate chloropigments, carbohydrates and TEP decreased under both sets of incubation conditions, although less under the increasing pressure regime than under atmospheric conditions. By contrast, dissolved carbohydrates (normalized to DOC) were higher after incubation and significantly higher under atmospheric conditions, suggesting they were produced at the expense of the particulate fraction. POC-normalized particulate wax/steryl esters increased only under pressure, suggesting biochemical responses of prokaryotes to the increasing pressure regime. The prokaryotic community initially consisted of 43% Bacteria, 12% Crenarchaea and 11% Euryarchaea. After incubation, Bacteria dominated (90%) the prokaryote community in all cases, with γ-Proteobacteria comprising the greatest fraction, followed by the Cytophaga–Flavobacter cluster and α-Proteobacteria group. Using the PASS system, we obtained chemical and microbial evidence that degradation by prokaryotes associated with fecal pellets sinking through mesopelagic waters is limited by the increasing pressure they experience.     

Quantifying nitrogen cycling beneath a meander of a low gradient,N‐impacted,agricultural stream using tracers and numerical modelling

In watersheds impacted by nitrate from agricultural fertilizers, nitrification and denitrification may be decoupled as denitrification in the hyporheic zone is not limited to naturally produced nitrate. While most hyporheic research focuses on the 1–2 m of sediment beneath the stream bed, there are a limited number of studies that quantify nitrogen (N) cycling at larger hyporheic scales (10s of metres to kms). We conducted an investigation to quantify N cycling through a single meander of a low gradient, meandering stream, draining an agricultural watershed. Chemistry (major ions and N species) and hydrologic data were collected from the stream and groundwater beneath the meander. Evidence indicates that nearly all the shallow groundwater flowing beneath the meander originates as stream water on the upgradient side of the meander, and returns to the stream on the downgradient side. We quantified the flux of water beneath the meander using a numerical model. The flux of N into and out of the meander was quantified by multiplying the concentration of the important N species (nitrate, ammonium, dissolved organic nitrogen (DON)) by the modelled water fluxes. The flux of N into the meander is dominated by nitrate, and the flux of N out of the meander is dominated by ammonium and DON. While stream nitrate varied seasonally, ammonium and DON beneath the meander were relatively constant throughout the year. When stream nitrate concentrations are high (>2 mg litre^?1), flow beneath the meander is a net sink for N as more N from nitrate in stream water is consumed than is produced as ammonium and DON. When stream nitrate concentrations are low (<2 mg litre^?1), the flux of N entering is less than exiting the meander. On an annual basis, the meander hyporheic flow serves as a net sink for N. Copyright © 2007 John Wiley & Sons, Ltd.     

The 2dF Galaxy Redshift Survey: the power spectrum and the matter content of the Universe

The 2dF Galaxy Redshift Survey has now measured in excess of 160 000 galaxy redshifts. This paper presents the power spectrum of the galaxy distribution, calculated using a direct Fourier transform based technique. We argue that, within the k -space region     , the shape of this spectrum should be close to that of the linear density perturbations convolved with the window function of the survey. This window function and its convolving effect on the power spectrum estimate are analysed in detail. By convolving model spectra, we are able to fit the power-spectrum data and provide a measure of the matter content of the Universe. Our results show that models containing baryon oscillations are mildly preferred over featureless power spectra. Analysis of the data yields 68 per cent confidence limits on the total matter density times the Hubble parameter     , and the baryon fraction     , assuming scale-invariant primordial fluctuations.