Swimming with…Devonian fish

Armoured jawless fish, or 'ostracoderms', lived 450–360 million years ago, and display unusual morphologies, unlike any modern fish group. Since they left no living descendants, their mode of swimming has, until recently, remained speculative, although this is a crucial question as the first true pectoral fins evolved within the 'ostracoderms'. The discovery of the oldest-known fish trails, from the Early Devonian (400 million year old) 'Lower Old Red Sandstone' of south-east Wales offers new insights into the swimming behaviour of these early fish, notably the osteostracan 'ostracoderms' (or cephalaspids), whose horseshoe-shaped head and paddle-shaped pectoral fins have remained a functional riddle.     

Constraints on the formation of layered tektites from the excavation and analysis of layered tektites from northeast Thailand

Abstract— The size, shape, composition, and vesicle content of 6 kg of layered tektite fragments, excavated near the town of Huai Sai, Thailand, place some constraints on the formation of layered tektites. The mass, shape, and distribution of the fragments are not consistent with an origin as a “puddle” of impact melt but suggest that they were derived from a single equant block. The presence of vesicles up to 7 mm in mean diameter within the tektite fragments suggests that the material was too viscous to allow for significant gravity-driven flow. These results suggest that layered tektites may be analogous to lava bombs, which may have been stretched and deformed in flight but underwent little flow after landing. Rather than being a product of “unusual circumstances,” such as multiple impacts, layered tektites may differ from splash-form tektites only in initial temperature of formation, speed of ejection, and small differences in initial composition.     

Application of precise 142Nd/144Nd analysis of small samples to inclusions in diamonds (Finsch,South Africa) and Hadean Zircons (Jack Hills,Western Australia)

¹⁴⁶Sm–¹⁴²Nd and ¹⁴⁷Sm–¹⁴³Nd systematics were investigated in garnet inclusions in diamonds from Finsch (S. Africa) and Hadean zircons from Jack Hills (W. Australia) to assess the potential of these systems as recorders of early Earth evolution. The study of Finsch inclusions was conducted on a composite sample of 50 peridotitic pyropes with a Nd model age of 3.3 Ga. Analysis of the Jack Hills zircons was performed on 790 grains with ion microprobe ²⁰⁷Pb/²⁰⁶Pb spot ages from 3.95 to 4.19 Ga. Finsch pyropes yield 100 × ?¹⁴²Nd = ? 6 ± 12 ppm, ?¹⁴³Nd = ? 32.5, and ¹⁴⁷Sm/¹⁴⁴Nd = 0.1150. These results do not confirm previous claims for a 30 ppm ¹⁴²Nd excess in South African cratonic mantle. The lack of a ¹⁴²Nd anomaly in these inclusions suggests that isotopic heterogeneities created by early mantle differentiation were remixed at a very fine scale prior to isolation of the South African lithosphere. Alternatively, this result may indicate that only a fraction of the mantle experienced depletion during the first 400 Myr of its history. Analysis of the Jack Hills zircon composite yielded 100 × ?¹⁴²Nd = 8 ± 10 ppm, ?¹⁴³Nd = 45 ± 1, and ¹⁴⁷Sm/¹⁴⁴Nd = 0.5891. Back-calculation of this present-day ?¹⁴³Nd yields an unrealistic estimate for the initial ?¹⁴³Nd of ? 160 ?-units, clearly indicating post-crystallization disturbance of the ¹⁴⁷Sm–¹⁴³Nd system. Examination of ^146,147Sm–^142,143Nd data reveals that the Nd budget of the Jack Hills sample is dominated by non-radiogenic Nd, possibly contained in recrystallized zircon rims or secondary subsurface minerals. This secondary material is characterized by highly discordant U–Pb ages. Although the mass fraction of altered zircon is unlikely to exceed 5–10% of total sample, its high LREE content precludes a reliable evaluation of ¹⁴⁶Sm–¹⁴²Nd systematics in Jack Hills zircons.     

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A community-wide intercomparison exercise for the determination of dissolved iron in seawater

The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.