Variation in surface turbulence and the gas transfer velocity over a tidal cycle in a macro-tidal estuary

The gradient flux technique, which measures the gas transfer velocity (k), and new observational techniques that probe turbulence in the aqueous surface boundary layers were conducted over a tidal cycle in the Plum Island Sound, Massachusetts. Efforts were aimed at testing new methods in an estuarine system and to determine if turbulence created by tidal velocity can be responsible for the short-term variability ink. Measurements were made during a low wind day, at a site with tidal excursions of 2.7 m and a range in tidal velocity of nearly 1 m s⁻¹. Estimates ofk using the gradient flux technique were made simultaneously with the Controlled Flux Technique (CFT), infrared imagery, and high-resolution turbulence measurements, which measure the surface renewal rate, turbulent scales, and the turbulent dissipation rate, respectively. All measurements were conducted from a small mobile catamaran that minimizes air- and water-side flow distortions. Infrared imagery showed considerable variability in the turbulent scales that affect air-water gas exchange. These measurements were consistent with variation in the surface renewal rate (range 0.02 to 2 s⁻¹), the turbulent dissipation rate (range 10⁻⁷ to 10⁻⁵ W kg⁻¹), andk (range 2.2 to 12.0 cm hr⁻¹). During this low wind day, all variables were shown to correlate with tidal speed. Taken collectively our results indicate the promise of these methods for determining short-term variability in gas transfer and near surface turbulence in estuaries and demonstrate that turbulent transport associated with tidal velocity is a potentially important factor with respect to gas exchange in coastal systems.     

Comparing palaeolimnological and instrumental evidence of climate change for remote mountain lakes over the last 200 years

This paper compares the palaeolimnological evidence for climate change over the last 200 years with instrumental climate data for the same period at seven European remote mountain lakes. The sites are Øvre Neådalsvatn (Norway), Saanajärvi (Finland), Gossenköllesee (Austria), Hagelseewli (Switzerland), Jezero v Ledvici (Slovenia), Estany Redó (Spain, Pyrenees), and Niné Terianske Pleso (Slovakia). We used multiple regression analysis to transfer homogenised lowland air temperature records to each of the sites, and these reconstructions were validated using data from on-site automatic weather stations. These data showed that mean annual temperature has varied over the last 200 years at each site by between 1 and 2 °C, typical of the high frequency variability found throughout the Holocene, and appropriate, therefore, to test the sensitivity of the various proxy methods used. Sediment cores from each site were radiometrically dated using ²¹⁰Pb, ¹³⁷Cs and ²⁴¹Am and analysed for loss-on-ignition, C, N, S, pigments, diatoms, chrysophytes, Cladocera and chironomids. Comparisons between the proxy data and the instrumental data were based on linear regression analysis with the proxy data treated as response variables and the instrumental data (after smoothing using LOESS regressions) as predictor variables. The results showed few clear or consistent patterns with generally low or very low r² values. Highest values were found when the data were compared after smoothing using a broad span, indicating that some of the proxy data were capturing climate variability but only at a relatively coarse time resolution. Probable reasons for the weak performance of the methods used include inaccurate dating, especially for earlier time periods, the influence of confounding forcing factors at some sites e.g., air pollution, earthquakes, and the insensitivity of some methods to low amplitude climate forcing. Nevertheless, there were trends in some proxy records at a number of sites that had a relatively unambiguous correspondence with the instrumental climate records. These included organic matter and associated variables (C and N) and planktonic diatom assemblages at the majority of sites and chrysophytes and chironomids at a few sites. Overall for longer term studies of the Holocene, these results indicate the need to be cautious in the interpretation of proxy records, the importance of proxy method validation, the continuing need to use reinforcing multi-proxy approaches, and the need for careful site and method selection.     

Initiation of Run-Out Flows on Venus by Oblique Impacts

A hypervelocity oblique impact results in a downrange-moving vapor cloud, a significant fraction of which is derived from the projectile. Since the vapor cloud expands to great extent and becomes very tenuous quickly on a planet with a thin or no atmosphere, it does not leave a well-defined geologic expression. The thick atmosphere of Venus, however, is sufficient to contain such a rapidly expanding vapor cloud. As a result of atmospheric interactions, impact vapor condenses and contributes to run-out flows around craters on Venus. Previous results of both laboratory experiments and simple semi-analytical calculations indicate that an impact-vapor origin can account for the morphology of run-out flows on Venus most consistently. However, the detailed dynamics and geologic record of downrange-moving impact vapor clouds in Venus's atmosphere are not understood quantitatively. To approach these problems, we carried out two-dimensional hydrocode calculations. Parametric studies of these hydrocode calculations yield simple scaling laws for both the total downrange travel distance and the final temperature of impact vapor clouds under conditions on Venus. Under typical impact conditions, impact vapor clouds travel downrange more than a crater radius prior to the completion of crater formation. Furthermore, the scaling law for the total travel distance is compared with observations for the downrange offset of the source regions of run-out flows around oblique craters. The results of this comparison suggest that energy/momentum-partitioning processes other than pure shock coupling may play important roles in hypervelocity impact at planetary scales. The results of hydrocode calculations also indicate that the terminal temperature of the impact vapor is close to the condensation temperatures of silicates, suggesting that two scenarios are possible for expected range of impact conditions: 1. Impact vapor condenses and forms run-out flows. 2. Impact vapor fails to condense and leaves no run-out flows. Consequently, natural variation in impact angle, velocity, and projectile composition may account for partial occurrence of run-out flows around impact craters on Venus.     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Spatial and temporal variability of ground water recharge in central Australia: a tracer approach

Two environmental tracer methods are applied to the Ti-Tree Basin in central Australia to shed light on the importance of recharge from floodouts of ephemeral rivers in this arid environment. Ground water carbon-14 concentrations from boreholes are used to estimate the average recharge rate over the interval between where the ground water sample first entered the saturated zone and the bore. Environmental chloride concentrations in ground water samples provide estimates of the recharge rate at the exact point in the landscape where the sample entered the saturated zone. The results of the two tracer approaches indicate that recharge rates around one of the rivers and an extensive floodplain are generally higher than rates of diffuse recharge that occurs in areas of lower topographic relief. Ground water 2H/1H and 18O/16O compositions are all depleted in the heavier isotopes (delta2H = -67 per thousand to -50 per thousand; delta18O = -9.2 per thousand to -5.7%o) compared with the long-term, amount-weighted mean isotopic composition of rainfall in the area (delta2H = -33.8 per thousand; delta18O = -6.3 per thousand). This indicates that recharge throughout the basin occurs only after intense rainfall events of at least 150 to 200 mm/month. Finally, a recharge map is developed to highlight the spatial extent of the two recharge mechanisms. Floodout recharge to the freshest ground water (TDS <1,000 mg/L) is approximately 1.9 mm/year compared with a mean recharge rate of approximately 0.2 mm/year to the remainder of the basin. These findings have important implications for management of the ground water resource.     

A UT1-Like Quantity from Analysis of GPS Orbit Planes

This paper discusses a UT1-like quantity, UTGPS, determined daily from Earth-referenced GPS satellite orbits from the International GPS Service (IGS). For each satellite considered, the observed relation between the satellite's IGS orbit and a model of its orbit plane in inertial space is used to estimate UT1. This modeled orbit plane is initialized using the satellite's IGS orbit and the actual UT1 at an initial time. It is then propagated using standard models of gravitational forces and an empirical model representing the orbit-normal radiation pressure observed during several years of in-flight experience with the satellite. To estimate UT1, an a-priori transformation from terrestrial to true-of-date celestial coordinates is applied to the satellite's IGS orbit. The geocentric angular deviations of points of the resulting transformed orbit from the modeled orbit plane are analyzed, giving the angle between the ascending nodes of the satellite's transformed and modeled orbit planes. To this observed angle between nodes, converted to a UT1 difference, is added the a-priori UT1 value used in the transformation. From the result is subtracted a model of the angle, again converted to a UT1 difference, between the ascending nodes of the actual and modeled orbit planes. The final result is the estimate of UT1 from this satellite, and the median of the UT1 estimates from all satellites considered is UTGPS. The root-mean-square difference between UTGPS-UT1 at the beginning and at the end of an interval of one to four weeks is approximately 30 s times the square root of the interval's duration in weeks.This revised version was published online in October 2005 with corrections to the Cover Date.     

Multi-wavelength observations of the 1998 September 27 flare spray

We report on observations of a large eruptive event associated with a flare that occurred on 27 September 1998 made with the Richard B. Dunn Solar Telescope at Sacramento Peak Observatory (several wave bands including off-line-center H), in soft and hard X-rays (GOES and BATSE), and in several TRACE wave bands (including Feix/x 171 Å, Fexii 195 Å, and Civ 1550 Å). The flare initiation is signaled by two H foot-point brightenings which are closely followed by a hard X-ray burst and a subsequent gradual increase in other wavelengths. The flare light curves show a complicated, three-component structure which includes two minor maxima before the main GOES class C5.2 peak after which there is a characteristic exponential decline. During the initial stages, a large spray event is observed within seconds of the hard X-ray burst which can be directly associated with a two-ribbon flare in H. The emission returns to pre-flare levels after about 35 min, by which time a set of bright post-flare loops have begun to form at temperatures of about 1.0–1.5 MK. Part of the flare plasma also intrudes into the penumbra of a large sunspot, generally a characteristic of very powerful flares, but the flare importance in GOES soft X-rays is in fact relatively modest. Much of the energy appears to be in the form of a second ejection which is observed in optical and ultraviolet bands, traveling out via several magnetic flux tubes from the main flare site (about 60° from Sun center) to beyond the limb.     

Products and Mechanism of the Gas Phase Reaction of Ozone with β-Pinene

Gas phase ozonolysis of -pinene was performedin a 570 l static reactor at 730 Torr and 296 K insynthetic air and the products were analysed by acombination of gas phase FTIR spectroscopy, HPLC andIC analyses of gas phase and aerosol samples,respectively. The reaction mechanism was investigatedby adding HCHO, HCOOH and H₂O as Criegeeintermediate scavenger and cyclohexane as OH radicalscavenger. Main identified products (yields inparentheses) in the presence of cyclohexane as OHradical scavenger were HCHO (0.65 ± 0.04),nopinone (0.16 ± 0.04), 3-hydroxy-nopinone (0.15± 0.05), CO₂ (0.20 ± 0.04), CO (0.030± 0.002), HCOOH (0.020 ± 0.002), the secondaryozonide of -pinene (0.16 ± 0.05), andcis-pinic acid (0.02 ± 0.01). The decompositionof the primary ozonide was found to yieldpredominantly the excited C₉-Criegee intermediateand HCHO (0.84 ± 0.04) and to a minor extent theexcited CH₂OO intermediate and nopinone (0.16± 0.04). Roughly 40% of the excitedC₉-Criegee intermediate becomes stabilised andcould be shown to react with HCHO, HCOOH and H₂O. The atmospherically important reaction of thestabilised C₉-Criegee intermediate with H₂Owas found to result in a nopinone increase of (0.35± 0.05) and in the formation of H₂O₂(0.24 ± 0.03). Based on the observed products,the unimolecular decomposition/isomerisationchannels of the C₉-Criegee intermediate arediscussed in terms of the hydroperoxide and esterchannels. Subsequent reactions of the nopinonylradical, formed in the hydroperoxide channel, lead tomajor products like 3-hydroxy-nopinone but also tominor products like cis-pinic acid. A mechanismfor the formation of this dicarboxylic acid isproposed and its possible role in aerosol formationprocesses discussed.     

Sediment contamination in floodplains and alluvial terraces as an historical record of gold exploitation in the Carmo River basin,Southeast Quadrilátero Ferrífero,Minas Gerais,Brazil

This paper describes the geochemistry of sediment samples placed in floodplains and alluvial terraces downstream from gold mines in the Carmo River basin, Quadrilátero Ferrífero, Minas Gerais, Brazil. The geochemistry signature Na₂O, K₂O, SiO₂, CaO, MgO, Al₂O₃, Fe₂O₃, TiO₂, P₂O₅, Mn, As, Cu, Zn, Ba, Ni, Cr, S, Co were analyzed in different facies from stratigraphic profiles. As, Cu, Zn, and Mn anomalies are mainly associated with the clayed facies deposited in floodplains and oxbow lakes, and with coarse‐sediment facies deposited in the channel. The facies were accumulated by the gold exploitation activity in the region. The contamination of As, Cu, and Zn was controlled by minerals such as iron oxides and hydroxides (hematite, magnetite, and mainly goethite), manganese oxides, and sulfide‐rich minerals. The As‐bearing sediments of the region characterize one of the most As contaminated area of Brazil. Their main source is associated with gold exploration in the last three centuries.