Arctic hazes in summer over Greenland and the North American Arctic: II. Nature and concentrations of accumulation-mode and giant particles

Airborne measurements made during August 1985 over Greenland and its environs show that both accumulation-mode (0.1 m D2.0 m) and giant (D2 m) particles were present in relatively high concentrations in arctic haze layers and that the accumulation-mode particles dominated light scattering. Particles with diameters (D) between 1 and 4 m consisted predominately of mixed materials, small and dense inclusions, and probably organic compounds containing sulfur. Many of the particles from 0.1 to 1 m in diameter were also of mixed composition, with sulfuric acid, ammonium sulfate and organics probably the dominant constituents.     

First and second moments of non-linear least-squares estimators

The first two moments of non-linear and least-squares estimators are studied. Approximate expressions for the moments are derived and discussed. The results are compared with those ofJeudy [1988].     

The Antarctic circumpolar current and its influence on the Earth's rotation

Summary At least in case of semidiurnal tides, theirmotions contain most of their relative angular momentum. There are other periodic currents in the ocean with cycles of months to years which may influence the Earth's rotation within such time scales. These currents are mainly due to seasonal or climatic variations of the wind stress and the water mass distribution in the oceans. The main question is: how much of the oceanic angular momentum is temporarily stored within the oceans and what is the time scale of the transfer to the solid Earth. As an example, we have estimated the phase and the amplitude of the angular momentum which is stored in the Antarctic Circumpolar Current. Its phase resembles the one of the whole observed semiannual discrepancy in the angular momentum budget of the solid Earth plus the atmosphere; the amplitudes are comparable.

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Der Antarktische Ringstrom und sein Einfluß auf die Erdrotation

Zusammenfassung Zumindest im Fall der halbtägigen Gezeiten der Ozeane enthalten derenBewegungen den größten Teil ihres variablen Drehimpulses. Andere periodische Meeresströmungen mit Perioden von Monaten bis Jahren könnten die Erdrotation ebenfalls beeinflussen. Solche Strömungen werden vor allem durch jahreszeitliche oder klimatische Veränderungen der Schubspannung des Windes und der Wasserstände verursacht. Die Hauptfrage ist jedenfalls diese: Wieviel Drehimpuls ist in jeder Phase in den Ozeanen gespeichert, und in welcher Zeit wird er mit der festen Erde ausgetauscht. Als Beispiel haben wir Phase und Amplitude des Drehimpulses abgeschätzt, der im Antarktischen Ringstrom enthalten ist. Diese Werte wurden mit den entsprechenden der Diskrepanz verglichen, die in der Bilanz feste Erde plus Atmosphäre offen bleibt. Die Phasen stimmen gut überein, und die Amplituden sind vergleichbar.

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Le courant circumpolaire antarctique et son influence sur la rotation de la terre

Résumé Au moins dans le cas des marées semi-diurnes lesmouvements des océans «contiennent» la plus grande partie de la variabilité de la quantité de moment angulaire de la terre. D'autres courants océaniques périodiques dont la période varie du mois à l'année peuvent aussi avoir une influence sur la rotation de la terre. De tels courants sont avant tout provoqués par des variations saisonnières ou climatiques de la tension superficielle due aux vents et des niveaux d'eau dans les océans. La question principale est en tout cas la suivante: quelle est à chaque phase la quantité de moment angulaire stockée dans les océans et en combien de temps est-elle échangée avec la masse solide de la terre. A titre d'exemple, nous avons évalué la phase et l'amplitude de la quantité de moment angulaire stockée dans le courant circumpolaire antarctique. Ces valeurs furent comparées aux valeurs correspondantes de l'anomalie qui subsiste dans le bilan terre solide plus atmosphère. Les phases sont concordantes et les amplitudes sont comparables.

     

Halite and sylvite as solid inclusions in high-grade metamorphic rocks

Solid inclusions of halite and sylvite, formed during regional and contact metamorphism have been identified by microscopy and by electron microprobe analysis in rocks from Campolungo, Switzerland and Cornone di Blumone, Italy. The solid inclusions occur in several of the major minerals crystallized during metamorphism and have been observed as idiomorphic crystals and dendrites. The compositions measured in 100 analyses from Campolungo, Switzerland and 40 analyses from Cornone di Blumone, Italy extend across the two-phase region in the system, KCl-NaCl, indicating that the salt inclusions are high temperature precipitates. In both localities compositionally zoned and unzoned crystals have been found. Measured compositions on the temperature maximum of the two-phase region indicate at least 500° C which can be compared with 500°±20° C determined by Mercolli (1982) and Walther (1983) from the Mg content of calcites from Campolungo. The solid inclusions have been trapped apart from CO₂-rich and saline, H₂O-rich fluid inclusions which have been described by Mercolli (1982) as the earliest preserved fluid inclusions in the rocks. The early precipitation of salt minerals at Campolungo indicates that fluids were saturated with NaCl and KCl at 500° C and pressures of 2,000 bars or higher. Similar relationships exist between solid and fluid inclusions in the rocks of Cornone di Blumone which formed at temperatures as high as 800° C and pressures between 0.5 and 1 kilobar (Ulmer 1983). The entrapment of halite and sylvite as solid inclusions preserves the composition of the minerals which may therefore be useful as geothermometers.     

210Pb dating of scottish lake sediments,afforestation and accelerated soil erosion

Changes in the rate of soil erosion in lake catchments can be identified from changes in the rate of sediment accumulation in lakes. Here we compare recently afforested sites with non-afforested sites in the Galloway area of Southwest Scotland. We show that lakes with non-afforested catchments have slow, constant sediment accumulation rates, whereas lakes with recently afforested catchments have changes in accumulation that parallel the known history of afforestation. For Loch Grannoch the sediment accumulation rate increases from 0.1 cm yr^?1 to over 2 cm yr^?2 during the disturbance period. Data from L. Skerrow, however, suggest that the rate might decline to predisturbance levels after approximately 10 years as the forest canopy closes and drainage channels stabilize.     

Linear volcanoes along the Pacific-Cocos plate boundary, 9°N to the Galapagos triple junction

A Seabeam-based reconnaissance of the 500 km of the East Pacific Rise crest between 7°N and 2°40′N shows that the axial ridge is segmented by four 4–13 km non-transform offsets into an en echelon string of distinctively different linear volcanoes. These axial volcanoes are oriented orthogonal to relative plate motion, except where their overlapping ends veer 15° toward each other and where small intra-volcano offsets of their crestal rift zones create abrupt kinks. Longitudinal gradients of the crestlines are less than 5 m/km, except where they plunge at rift-zones' overlapped ends and where they rise locally to small axial peaks. Transverse profiles vary from trapezoidal to triangular, with a steep shield-shaped cross-section being most common. Conventional sounding data indicate that this pattern continues to the 140 km-offset Siqueiros transform fault system at 8.2°N. Within this fault system is a short spreadingcenter volcano contained in a rift valley that links two strike-slip fault zones. Immediately to the north is the shallow 9.0°–8.3°N axial volcano, with unusual relief mapped by a deeply towed instrument package. At the southern end of the plate boundary, as the rise crest enters the region of the Pacific-Cocos-Nazca triple junction, the axial ridge narrows, deepens, and acquires a more irregular long profile. South of 2°30′N the rise crest has a 15 km-wide rift valley that contains multiple volcanic ridges with north-south strikes. Structural hypotheses suggested or supported by these morphologic observations include a point-source magma supply to the spreading center from mantle diapirs, the along-strike continuity of axial magma chambers on fast-spreading rises, even across small rift-zone offsets, and the importance of magma intrusion as well as eruption for building the axial ridge. Hypotheses inconsistent with the new data include magma supply and long-distance dispersal from a few widely spaced plumes, primary control of the topographic, volcanic, and tectonic characteristics of the rise crest by distance from transform faults, and localization of triple junctions over major mantle upwellings.     

Some chemical structural features of coals of differing maceral distributions and stratigraphy

Six North American bituminous coals (four Carboniferous and two Cretaceous) and eight maceral concentrates from Carboniferous British seams have been heated with tetralin and hydrogen to 400°C. The hexane-soluble parts of the products were separated by column chromatography and the fractions were then analyzed by gas chromatography/mass spectrometry. In all cases the aromatic hydrocarbon fraction was a very complex mixture containing a number of alkylated biphenyls, diphenylmethanes and -ethanes, and polycyclic compounds. However single ioncchromatography (m/z = 142) showed that, in addition to these, the products from five of the six American coals contained homologous series of long chain n-alkylnapththalenes with alkyl groups extending to C₁₆. In other fractions from the American coals, homologous series of n-alkylfurans and alkylphenols were found to be major components, as also were many alkylcyclohexenones related to isophorone. Extensive homologous series of n-alkyl aromatics were not detected in products from any of six vitrinites from British seams, though series of n- and iso-alkylphenols were found in the products from two sporinite concentrates. A number of polycyclic ketones apparently related to sterols were found in the products from the British vitrinites but not from any American coals. Reasons for what appear to be systematic structural differences between the American and British coals are discussed. Differences in stratigraphy are noted and it seems not impossible that differences in source vegetation are significant.