Gold and associated trace elements in Newfoundland lake sediment: their application to gold exploration

Lake sediments were collected from four glaciated areas, three of which include significant Au mineralization. Neutron activation analyses for Au successfully delineate known mineralization and suggest areas for further follow-up. Gold is the only universal indicator although Sb gives a broader dispersion pattern at the Hope Brook deposit. Copper, Pb and Zn have above-background content down-ice from some mineralized zones. Gold values above 8.0 ppb in these study areas indicate the presence of Au mineralization. Gold analyses of site duplicates and analytical splits reproduce satisfactorily above 3.0 ppb.     

The dependence of the Fe2+-Mg cation-partitioning between olivine and basaltic liquid on pressure,temperature and composition

The equilibrium partitioning of Fe²⁺ and Mg between olivine and liquid along a liquid line of descent has been determined for a calc-alkaline system, ranging in composition from picritic to andesitic. Experiments were conducted between 1000–1450° C and 1 bar to 30 kbar. Within the compositional range investigated and , the compositional dependence of the Fe²⁺ and Mg partitioning is a function of the Mg-content of the liquid. The Mg-content of the liquid correlates strongly with temperature. The variation of the Fe²⁺ and Mg partitioning were therefore evaluated individualy as functions of composition and temperature alone. The composition dependence of the cation-partitioning coefficients (Kd) is given by the following two equations:

57Fe-Moessbauer spectra,electronic and crystal structure of members of the CuS2-FeS2 solid solution series

Members of the (Cu, Fe)S₂ solid solution crystallize in the pyrite structure type, space group Pa 3, Cu and Fe being statistically distributed on the metal sites. Within this series, a semiconductor to metal transition can be detected between 25 and 38 mole% CuS₂. Compositional dependent ⁵⁷Fe-Moessbauer spectra reveal Fe²⁺ in low-spin configuration. A minimum of the quadrupole splitting and the slope in the ⁵⁷Fe-isomer shift in the intermediate part of the system, near 30 mole% CuS₂, can be correlated with the onset of metallic conductivity, whereas the structural parameters are not influenced by this transition. The analysis of the compositional dependency of the quadrupole splitting, in comparison to the isotypic system (Co, Fe)S₂, leads to the conclusion that Cu in solid (Cu, Fe)S₂ compounds is Cu⁺ with an Ar -3 d¹⁰ electronic configuration.     

Field Comparison of Micropurging vs. Traditional Ground Water Sampling

Micropurge sampling of ground water wells has been suggested as a possible replacement to traditional purge and sample methods. To compare methods, duplicate ground water samples were collected at two field sites using iraditional and micropurge methods. Samples were analyzed for selected organic and inorganic constituents, and the results were compared statistically. Analysis of the data using the nonparametric sign test indicates that within a 95 percent confidence interval, there was no significant difference between the two methods for the site contaminants and the majority of analytes. These analytical results were supported by visual observations with the colloidal borescope, which demonstrated impacts on the flow system in the well when using traditional sampling methods. Under selected circumstances, the results suggest replacing traditional sampling with micropurging based on reliability, cost, and waste minimization.     

A probability-weighted moment test to assess simple scaling

We present a statistically robust approach based on probability weighted moments to assess the presence of simple scaling in geophysical processes. The proposed approach is different from current approaches which rely on estimation of high order moments. High order moments of simple scaling processes (distributions) may not have theoretically defined values and consequently, their empirical estimates are highly variable and do not converge with increasing sample size. They are, therefore, not an appropriate tool for inference. On the other hand we show that the probability weighted moments of such processes (distributions) do exist and, hence, their empirical estimates are more robust. These moments, therefore, provide an appropriate tool for inferring the presence of scaling. We illustrate this using simulated Levystable processes and then draw inference on the nature of scaling in fluctuations of a spatial rainfall process.     

Prediction of the seismic capacity of RC structural walls by non-parametric multidimensional regression

The use of a non-parametric multidimensional regression is suggested for the prediction of the seismic capacity of reinforced concrete structural walls. This capacity is expressed in terms of the shear strength, drift, ductility and failure mode of the walls. For the application of the method a data base is needed which contains data on the results of tests performed on the structural elements under consideration. The data base used in the study was compiled from the available literature, and includes data from laboratory tests carried out on 262 structural walls. The method was validated by comparing the predicted and test results. A comparison with some available closed-form empirical predictions has been made. The results show that the accuracy of the predictions obtained by the proposed method is, on average, higher than that provided by existing formulae. The proposed method has several advantages when compared to closed-form empirical expressions based on standard linear regression: (1) The relationship between the input and output variables is not selected a priori by a prediction law. (2) It takes into account the currently available data base, which can be updated when new information becomes available. (3) An arbitrary number of input and output variables can be taken into account using the same data base. (4) The method can be applied directly to similar problems in structural and earthquake engineering, wherever a suitable data base is available.     

Gravel transport and morphological change in braided sunwapta river,Alberta, Canada

The relation between morphological change and patterns of variation in bedload transport rate in braided streams was observed by repeated, daily topographic surveys over a 25 day study period in a 60 m reach of the proglacial Sunwapta River, Alberta, Canada. There are two major periods of morphological change, each lasting several days and each involving the complete destruction and reconstruction of bar complexes. Bar complex destruction was caused by redirection of the flow and by downstream extension of the confluence scour zone upstream. Reconstruction involved accretion of unit bars on bar head, flank and tail and in one case was initiated by disection of a large, lobate unit bar. High rates of sediment movement, measured from net scour and fill of the cross-sections, coincided with these morphological changes. Sediment was supplied from both bed and bank erosion, and patterns and distances of transfer were highly variable. Rates of transport estimated by matching upstream erosional volumes with downstream deposition were much greater than those estimated from either a step-length approach or a sediment budget. Measurements of scour and fill and observations of morphological change indicate that step lengths (virtual transport distances) were typically 40–100m during a diurnal discharge cycle. Shorter step lengths occurred when transfer was confined to a single anabranch and longer steps involved channel changes at the scale of the entire reach. Sediment budgeting was used to describe the spatial patterns of sediment transport associated with the morphological changes and to estimate minimum daily reach-averaged transport rates. Mean bedload transport rates correlate with discharge, but with considerable scatter. The largest deviations from the mean relation can be tied to phases of channel incision, bank erosion, scour hole migration, bar deposition and channel filling apparently controlled by changes and fluctuations in sediment supply from upstream, independent of discharge. These are interpreted as field evidence of ‘autopulses’ or ‘macropulses’ in bedload transport, previously observed only in laboratory models of braided streams.     

Reply: Bulk sampling of coarse clastic sediments for particle-size analysis

The work of Gale and Hoare (1992) provides a guide to the minimum mass of bulk sample required to obtain a reproducible measure of the complete particle-size distribution of coarse clastic sediments such as till, fluvial gravel and beach gravel. Dunkerley (1994) makes a number of criticisms and misrepresentations of this procedure. These are systematically refuted and corrected here, and further data obtained from till and beach gravel are provided to support the criterion adopted by Gale and Hoare (1992) for sample reliability. The procedure of Gale and Hoare (1992) is confirmed as a practical guide to the mass of bulk sample required to obtain a reliable measure of the particle-size distribution of coarse clastic sediment.     

Rock-magnetic proxies of climate change in the loess-palaeosol sequences of the western Loess Plateau of China

Results of the first detailed study of the climate proxy record in the loess-palaeosol sequence at Xining-one of the few palaeoclimate sites in the currently arid western Loess Plateau of China-illustrate the importance of making many types of rock-magnetic measurements other than susceptibility. A multiparameter approach yielded confirmation that here, as elsewhere in the Loess Plateau, the susceptibility enhancement in palaeosols was caused primarily by ultrafine magnetite and maghaemite. Nevertheless, magnetic enhancement was caused not exclusively by changes in relative grain size, but also by variations in concentration and mineralogy of the magnetic fraction.
The effects of concentration variations were removed through normalization of susceptibility and anhysteretic remanence with saturation magnetization and saturation remanence, respectively. the resulting signal was ascribed more confidently to variation in magnetic grain size, which in turn was interpreted as a better proxy of pedogenesis than simple susceptibility. Variations in magnetic mineralogy were also determined to constrain interpretations further. the data were then used to discuss climate history at Xining. Finally, results from Xining were compared with other western sites and contrasted with eastern sites.
In summary: (1) data is presented from a new Loess Plateau site which also appears to yield a global climate signal; (2) a demonstration is made of a more rock-magnetically robust way to separate concentration, composition and grain-size controls on susceptibility and other magnetic parameters; and (3) models are provided for inter-regional comparisons of palaeoclimate proxy records.