Biosorption of methylene blue from aqueous solutions by Typha angustata phytomass

The objective of this study was to investigate the biosorption of an azo dye (Methylene blue) by a wetland phytomass (Typha angustata) under post-phytoremediation scenario. Thus, the phytomass was used without any chemical modification. The batch adsorption experiments were conducted to evaluate the effects of contact time and temperatures (25–45 °C) on the adsorption of methylene blue (MB) from aqueous solution by cattail phytomass (CP). More than 80 % of MB dye was removed from the aqueous solution within first 10 min of the experiment. Langmuir isotherm was modeled to describe the monolayer adsorption of MB dye (R ² = 0.995) with the maximum adsorption capacity of 8.1 mg/g at 25 °C. Pseudo-second-order kinetic model adequately described the kinetics of absorption process (R ² = 0.999). The adsorption of MB on the cattail phytomass was a spontaneous and endothermic process that was governed by chemisorption. Hence, CP could be applied as a potential low cost biosorbent to treat dyeing wastewater.     

Crustal structure of the Ordovician Macquarie Arc,Eastern Lachlan Orogen,based on seismic‐reflection profiling

In the Eastern Lachlan Orogen, the mineralised Molong and Junee‐Narromine Volcanic Belts are two structural belts that once formed part of the Ordovician Macquarie Arc, but are now separated by younger Silurian‐Devonian strata as well as by Ordovician quartz‐rich turbidites. Interpretation of deep seismic reflection and refraction data across and along these belts provides answers to some of the key questions in understanding the evolution of the Eastern Lachlan Orogen—the relationship between coeval Ordovician volcanics and quartz‐rich turbidites, and the relationship between separate belts of Ordovician volcanics and the intervening strata. In particular, the data provide evidence for major thrust juxtaposition of the arc rocks and Ordovician quartz‐rich turbidites, with Wagga Belt rocks thrust eastward over the arc rocks of the Junee‐Narromine Volcanic Belt, and the Adaminaby Group thrust north over arc rocks in the southern part of the Molong Volcanic Belt. The seismic data also provide evidence for regional contraction, especially for crustal‐scale deformation in the western part of the Junee‐Narromine Volcanic Belt. The data further suggest that this belt and the Ordovician quartz‐rich turbidites to the east (Kirribilli Formation) were together thrust over ?Cambrian‐Ordovician rocks of the Jindalee Group and associated rocks along west‐dipping inferred faults that belong to a set that characterises the middle crust of the Eastern Lachlan Orogen. The Macquarie Arc was subsequently rifted apart in the Silurian‐Devonian, with Ordovician volcanics preserved under the younger troughs and shelves (e.g. Hill End Trough). The Molong Volcanic Belt, in particular, was reworked by major down‐to‐the‐east normal faults that were thrust‐reactivated with younger‐on‐older geometries in the late Early ‐ Middle Devonian and again in the Carboniferous.     

Experimental evidences and numerical modelling of debris flow initiated by channel runoff

Debris flow initiation by channel bed mobilization is a common process in high mountainous areas. Initiation is more likely to occur at the outlet of small, steeply sloping basins where concentrated overland flow feeds an ephemeral channel incised in slope deposits. Such geological conditions are typical of the Dolomite region (Italian Alps), which is characterized by widespread debris flow activity triggered by severe summer thunderstorms. Real-time data and field observations for one of these catchments (Acquabona catchment, Belluno, Italian Alps) were used to characterize the hydrological response of the initiation area to rainfalls of varying intensity and duration. The observed behaviour was then reproduced by means of a simple hydrological model, based on the kinematic wave assumption, to simulate the generation of channel runoff. The model is capable of predicting the observed hydrological response for a wide range of rainfall impulses, thus providing a physical basis for the understanding of the debris flow triggering threshold.     

Benthic Carbon Mineralization and Nutrient Turnover in a Scottish Sea Loch: An Integrative In Situ Study

Based on in situ microprofiles, chamber incubations and eddy covariance measurements, we investigated the benthic carbon mineralization and nutrient regeneration in a ~65-m-deep sedimentation basin of Loch Etive, UK. The sediment hosted a considerable amount of infauna that was dominated by the brittle star A. filiformis. The numerous burrows were intensively irrigated enhancing the benthic in situ O₂ uptake by ~50 %, and inducing highly variable redox conditions and O₂ distribution in the surface sediment as also documented by complementary laboratory-based planar optode measurements. The average benthic O₂ exchange as derived by chamber incubations and the eddy covariance approach were similar (14.9 ± 2.5 and 13.1 ± 9.0 mmol m^?2 day^?1) providing confidence in the two measuring approaches. Moreover, the non-invasive eddy approach revealed a flow-dependent benthic O₂ flux that was partly ascribed to enhanced ventilation of infauna burrows during periods of elevated flow rates. The ratio in exchange rates of ΣCO₂ and O₂ was close to unity, confirming that the O₂ uptake was a good proxy for the benthic carbon mineralization in this setting. The infauna activity resulted in highly dynamic redox conditions that presumably facilitated an efficient degradation of both terrestrial and marine-derived organic material. The complex O₂ dynamics of the burrow environment also concurrently stimulated nitrification and coupled denitrification rates making the sediment an efficient sink for bioavailable nitrogen. Furthermore, bioturbation mediated a high efflux of dissolved phosphorus and silicate. The study documents a high spatial and temporal variation in benthic solute exchange with important implications for benthic turnover of organic carbon and nutrients. However, more long-term in situ investigations with like approaches are required to fully understand how environmental events and spatio-temporal variations interrelate to the overall biogeochemical functioning of coastal sediments.     

Evaluation of three waterborne polymers as stabilizers for sandy soil

This study reports on waterborne polymer emulsion systems that were used for structural modification of sandy soils. The first emulsion used was a styrene-acrylic, copolymer emulsion; the second and third were vinyl-acrylic, copolymer-based emulsions. Specimens were prepared by adding different polymer emulsions to the sand and water in prescribed amounts. The performance of the different emulsion systems as sand stabilizers was estimated through measurement of the hydraulic conductivity and compressive strength. Measurements of hydraulic conductivity were conducted in a flexible membrane test apparatus. The hydraulic conductivity for the three emulsions decreased at different rates, with an increase in polymer content up to 3 wt. (i.e., % by weight). Additional increase of polymer content did not introduce significant decrease in hydraulic conductivity, and, at 5 wt.%, the three emulsions had essentially the same effect. Measurements made on dry cylindrical specimens disclosed remarkable enhancement in the mechanical behavior of the system. The compressive strength and modulus of elasticity of the examined emulsions increased with a higher concentration of polymer. Scanning electron microscope (SEM) revealed that the reduction in the permeability and the improved mechanical properties can be attributed to three dominant structural changes: the development of interconnecting ties between the sand particles, the development of adhesion between neighboring sand particles in contact, and the covering of the sand particles with a thin polymer film.     

Semi-Analytic Modelling of Subsidence

This paper presents a forward model for subsidence prediction caused by extraction of hydrocarbons. The model uses combinations of analytic solutions to the visco-elastic equations, which approximate the boundary conditions. There are only a few unknown parameters to be estimated, and, consequently, calculations are very fast. The semi-analytic model is applicable to a uniform and layer-cake stratigraphy, with visco-elastic parameters changing per layer, and an arbitrary depletion pattern. By its capabilities to handle a multi-layered visco-elastic subsurface, the semi-analytic model fills the gap between the analytic single-layered elastic models available to date and the more elaborate numerical, e.g. finite element, models.     

Conditions of Quaternary magmatism at Spitsbergen Island

Petrological and geochemical data obtained on the Quaternary lavas of volcanoes at Spitsbergen Island indicate that the rocks were produced via the deep-seated crystallization of parental alkaline magmas at 8–10 kbar. The character of clinopyroxene enrichment in incompatible elements indicates that the mineral crystallized from more enriched melts than those inferred from the composition of the host lavas. These melts were close to the parental melts previously found as veinlets in mantle hyperbasite xenoliths in the lavas. According to the character of their enrichment in Pb and Sr radiogenic isotopes and depletion in Nd, the basalts from Spitsbergen Island define a single trend with the weakly enriched tholeiites of the Knipovich Ridge, a fact suggesting the closeness of the enriched sources beneath the continental margin of Spitsbergen and beneath the spreading zone. Magmatic activity at Spitsbergen was related to the evolution of the Norwegian-Greenland basin, which evolved in pulses according to the shift of the spreading axes. The most significant of the latter events took place in the Neogene, when the Knipovich Ridge obtained its modern position near the western boundary of Spitsbergen. Early in the course of the evolution, the emplacement of alkaline melts generated at Spitsbergen into the oceanic mantle could form the enriched mantle, which was later involved in the melting process beneath the spreading zone.     

Stable carbon-isotopic compositions of lipids isolated from the ammonia-oxidizing chemoautotroph Nitrosomonas europaea

For the ammonia-oxidizing bacterium Nitrosomonas europaea, grown autotrophically using semicontinuous culturing, average biomass was depleted in ¹³C relative to CO₂ dissolved in the medium by ca. 20‰ and the total-lipid extract was depleted in ¹³C relative to biomass by 3.7‰. The n-alkyl lipids (weighted average of fatty acids) and isoprenoid lipids (weighted average of hopanoids) were both depleted in ¹³C relative to biomass by about 9‰. The large depletion in the isoprenoid lipids seems to indicate that isotopic fractionations associated with the biosynthesis of methylerythritol phosphate (MEP) affected at least two carbon positions in each isoprene unit. Among the fatty acids, trans-9-hexadecenoic acid was most depleted (13.0‰ relative to biomass), followed by cis-9- hexadecenoic acid (9.6‰) and hexadecanoic acid (6.9‰). Isotopic relationships between the three acids suggest that significant isotope effects were associated with the desaturation and cis to trans isomerization of fatty acids. Given these observations, hopanoids produced by ammonia-oxidizing bacteria growing in natural waters are likely to be depleted in ¹³C by 26–30‰ relative to dissolved CO₂. Since CO₂ at aquatic oxyclines is often depleted in ¹³C, the range of δ values expected for hopanoids is ca. −34‰ to −55‰. The δ values of geohopanoids observed in numerous studies and attributed to unspecified chemoautotrophs fall within this range.