Observations of the Labrador Sea eddy field

This paper is an observational study of small-scale coherent eddies in the Labrador Sea, a region of dense water formation thought to be of considerable importance to the North Atlantic overturning circulation. Numerical studies of deep convection emphasize coherent eddies as a mechanism for the lateral transport of heat, yet their small size has hindered observational progress. A large part of this paper is therefore devoted to developing new methods for identifying and describing coherent eddies in two observational platforms, current meter moorings and satellite altimetry. Details of the current and water mass structure of individual eddy events, as they are swept past by an advecting flow, can then be extracted from the mooring data. A transition is seen during mid-1997, with long-lived boundary current eddies dominating the central Labrador Sea year-round after this time, and convectively formed eddies similar to those seen in deep convection modeling studies apparent prior to this time. The TOPEX / Poseidon altimeter covers the Labrador Sea with a loose “net” of observations, through which coherent eddies can seem to appear and disappear. By concentrating on locating and describing anomalous events in individual altimeter tracks, a portrait of the spatial and temporal variability of the underlying eddy field can be constructed. The altimeter results reveal an annual “pulsation” of energy and of coherent eddies originating during the late fall at a particular location in the boundary current, pinpointing the time and place of the boundary current-type eddy formation. The interannual variability seen at the mooring is reproduced, but the mooring site is found to be within a localized region of greatly enhanced eddy activity. Notably lacking in both the annual cycle and interannual variability is a clear relationship between the eddies or eddy energy and the intensity of wintertime cooling. These eddy observations, as well as hydrographic evidence, suggest an active role for boundary current dynamics in shaping the energetics and water mass properties of the interior region.     

Comment on “Complete Eulerian-mean tracer equation for coarse resolution OGCMs” by M. S. Dubovikov and V. M. Canuto

Dubovikov and Canuto (Dubovikov, M.S. and Canuto, V.M., Complete Eulerian-mean tracer equation for coarse resolution OGCMs. Geophys. Astrophys. Fluid Dyn., 2006, 100, 197–214), after averaging the tracer conservation equation in density coordinates and transforming to height coordinates, concluded that present ocean models are missing important terms in their mean tracer equations. Here we point out some errors made by Dubovikov and Canuto (2006 Dubovikov, MS and Canuto, VM. 2006. Complete Eulerian-mean tracer equation for coarse resolution OGCMs. Geophys. & Astrophys. Fluid Dynam., 100: 197–214. [Taylor & Francis Online], [Web of Science ®] , [Google Scholar]) in their isopycnal averaging procedure. We draw on the temporal-residual-mean (TRM) theory and show that when the isopycnal averaging and coordinate transformation are performed correctly, the tracer equations of present ocean circulation models are recovered. We therefore conclude that present ocean circulation models are not neglecting the leading order terms identified by Dubovikov and Canuto (2006 Dubovikov, MS and Canuto, VM. 2006. Complete Eulerian-mean tracer equation for coarse resolution OGCMs. Geophys. & Astrophys. Fluid Dynam., 100: 197–214. [Taylor & Francis Online], [Web of Science ®] , [Google Scholar]).     

Intergranular diffusion rates from the analysis of garnet surfaces: Implications for metamorphic equilibration

Novel approaches to garnet analysis have been used to assess rates of intergranular diffusion between different matrix phases and garnet porphyroblasts in a regionally metamorphosed staurolite‐mica‐schist from the Barrovian‐type area in Scotland. X‐ray maps and chemical traverses of planar porphyroblast surfaces reveal chemical heterogeneity of the garnet grain boundary linked to the nature of the adjacent matrix phase. The garnet preserves evidence of low temperature retrograde exchange with matrix minerals and diffusion profiles documenting cation movement along the garnet boundaries. Garnet–quartz and garnet–plagioclase boundaries preserve evidence of sluggish Mg, Mn and Fe diffusion at comparable rates to volume diffusion in garnet, whereas diffusion along garnet–biotite interfaces is much more effective. Evidence of particularly slow Al transport, probably coupled to Fe³⁺ exchange, is locally preserved on garnet surfaces adjacent to Fe‐oxide phases. The Ca distribution on the garnet surface shows the most complex behaviour, with long‐wavelength heterogeneities apparently unrelated to the matrix grain boundaries. This implies that the Ca content of garnet is controlled by local availability and is thought likely to reflect disequilibrium established during garnet growth. Geochemical anomalies on the garnet surfaces are also linked to the location of triple junctions between the porphyroblasts and the matrix phases, and imply enhanced transport along these channels. The slow rates of intergranular diffusion and the characteristics of different boundary types may explain many features associated with the prograde growth of garnet porphyroblasts. Thus, minerals such as quartz, Fe‐oxides and plagioclase whose boundaries with garnet are characterized by slow intergranular diffusion rates appear to be preferentially trapped as inclusions within porphyroblasts. As such grain boundary diffusion rates may be a significant kinetic impediment to metamorphic equilibrium and garnet may struggle to maintain chemical and textural equilibrium during growth in pelites.     

Review: The Yucat��n Peninsula karst aquifer, Mexico

The Yucatán Peninsula karst aquifer is one of the most extensive and spectacular karst aquifer systems on the planet. This transboundary aquifer system extends over an area of approximately 165,000? km² in México, Guatemala and Belize. The Triassic to Holocene Yucatán limestone platform is located in the vicinity of the North American/Caribbean plate boundary and has been reshaped by a series of tectonic events over its long geologic history. At the end of the Cretaceous period, the Yucatán Peninsula was hit by a large asteroid, which formed the Chicxulub impact crater. The Yucatán Peninsula karst aquifer hosts large amounts of groundwater resources which maintain highly diverse groundwater-dependent ecosystems. Large parts of the aquifer are affected by seawater intrusion. Anthropogenic pollution of the aquifer has been increasing over the past few decades, owing to relentless economic development and population growth on the Peninsula. This review summarizes the state of knowledge on the Yucatán Peninsula karst aquifer and outlines the main challenges for hydrologic research and practical groundwater-resources management on the Peninsula.     

The geology of kimberlite pipes of the Ekati property, Northwest Territories, Canada

This paper reviews key characteristics of kimberlites on the Ekati property, NWT, Canada. To date 150 kimberlites have been discovered on the property, five of which are mined for diamonds. The kimberlites intrude Archean basement of the central Slave craton. Numerous Proterozoic diabase dykes intrude the area. The Precambrian rocks are overlain by Quaternary glacial sediments. No Phanerozoic rocks are present. However, mudstone xenoliths and disaggregated sediment within the kimberlites indicate that late-Cretaceous and Tertiary cover (likely <200 m) was present at the time of emplacement. The Ekati kimberlites range in age from 45 to 75 Ma. They are mostly small pipe-like bodies (surface area mostly <3 ha but up to 20 ha) that typically extend to projected depths of 400–600 m below current surface. Pipe morphologies are strongly controlled by joints and faults. The kimberlites consist primarily of variably bedded volcaniclastic kimberlite (VK). This is dominated by juvenile constituents (olivine and lesser kimberlitic ash) and variable amounts of exotic sediment (primarily mud), with minor amounts of xenolithic wall-rock material (generally <5%). Kimberlite types include: mud-rich resedimented VK (mRVK); olivine-rich VK (oVK); sedimentary kimberlite; primary VK (PVK); tuffisitic kimberlite (TK) and magmatic kimberlite (MK). The presence and arrangement of these rock types varies widely. The majority of bodies are dominated by oVK and mRVK, but PVK is prominent in the lower portions of certain kimberlites. TK is rare. MK occurs primarily as precursor dykes but, in a few cases, forms pipe-filling intrusions. The internal geology of the kimberlites ranges from simple single-phase pipes (RVK or MK), to complex bodies with multiple, distinct units of VK. The latter include pipes infilled with steep, irregular VK blocks/wedges and at least one case in which the pipe is occupied by well-defined sub-horizontal VK phases, including a unique, 100-m-thick graded sequence. The whole-rock compositions of VK samples suggest significant loss of kimberlitic fines during eruption followed by variable dilution by surface sediment and concurrent incorporation of kimberlitic ash. Diamond distribution within the kimberlites reflects the amount and nature of mantle material sampled by individual kimberlite phases, but is modified considerably by eruption and depositional processes. The characteristics of the Ekati kimberlites are consistent with a two-stage emplacement process: (1) explosive eruption/s causing vent clearing followed by formation of a significant tephra rim/cone of highly fragmented, olivine-enriched juvenile material with varying amounts of kimberlitic ash and surface sediments (predominantly mud); and (2) infilling of the vent by direct deposition from the eruption column and/or resedimentation of crater rim materials. The presence of less fragmented, juvenile-rich PVK in the lower portions of certain pipes and the intrusion of large volumes of MK to shallow levels in some bodies suggest emplacement of relatively volatile-depleted, less explosive kimberlite in the later stages of pipe formation and/or filling. Explosive devolatilisation of CO₂-rich kimberlite magma is interpreted to have been the dominant eruption mechanism, but phreatomagmatism is thought to have played a role and, in certain cases, may have been dominant.     

Snow distribution from SSM/I and its relationships to the hydroclimatology of the Mackenzie River Basin,Canada

The spatial and temporal distribution of snow cover extent (SCE) and snow water equivalent (SWE) play vital roles in the hydrology of northern watersheds. We apply remotely sensed Special Sensor Microwave Imager (SSM/I) data from 1988 to 2007 to explore the relationships between snow distribution and the hydroclimatology of the Mackenzie River Basin (MRB) of Canada and its major sub-basins. The Environment Canada (EC) algorithm is adopted to retrieve the SWE from SSM/I data. Moderate Resolution Imaging Spectroradiometer (MODIS) 8-day maximum snow cover extent products (MOD10A2) are used to estimate the different thresholds of retrieved SWE from SSM/I to classify the land cover as snow or no snow for various sub-basins in the MRB. The sub-basins have varying topography and hence different thresholds that range from 10 mm to 30 mm SWE. The accuracy of snow cover mapping based on the combination of several thresholds for the different sub-basins reaches ≈ 90%. The northern basins are found to have stronger linear relationships between the date on which snow cover fraction (SCF) reaches 50% or when SWE reaches 50% and mean air temperatures, than the southern basins. Correlation coefficients between SCF, SWE, and hydroclimatological variables show the new SCF products from SSM/I perform better than SWE from SSM/I to analyze the relationships with the regional hydroclimatology. Statistical models relating SCF and SWE to runoff indicate that the SCF and SWE from EC algorithms are able to predict the discharge in the early snow ablation seasons in northern watersheds.     

Effectiveness of post-fire salvage logging stream buffer management for hillslope erosion in the U.S. Inland Northwest Mountains

Active wildfire seasons in the western U.S. warrant the evaluation of post-fire forest management strategies. Ground-based salvage logging is often used to recover economic loss of burned timber. In unburned forests, ground-based logging often follows best management practices by leaving undisturbed areas near streams called stream buffers. However, the effectiveness of these buffers has not been tested in a post-wildfire setting. This experiment tested buffer width effectiveness with a novel field-simulated rill experiment using sediment-laden runoff (25 g/L) released over 40 min at evenly timed flow rates (50, 100 and 150 L/min) to measure surface runoff travel length and sediment concentration under unburned and high and low soil burn severity conditions at 2-, 10- and 22-month post-fire. High severity areas 2-month post-fire had rill lengths of up to 100 m. Rill length significantly decreased over time as vegetation regrowth provided ground cover. Sediment concentration and sediment dropout rate also varied significantly by soil burn severity. Sediment concentrations were 19 g/L for the highest flow 2-month post-fire and reduced to 6.9–14 g/L 10-month post-fire due to abundant vegetation recovery. The amount of sediment dropping out of the flow consistently increased over the study period with the low burn severity rate of 1.15 g L⁻¹ m⁻¹ approaching the unburned rate of 1.29 g L⁻¹ m⁻¹ by 2-year post-fire. These results suggest that an often-used standard, 15 m buffer, was sufficient to contain surface runoff and reduce sediment concentration on unburned sites, however buffers on high burn severity sites need to be eight times greater (120 m) immediately after wildfire and four times greater (60 m) 1-year post-fire. Low burn severity areas 1-year post-fire may need to be only twice the width of an unburned buffer (30 m), and 2-year post-fire these could return to unburned widths.     

Anomalous subsidence on the rifted volcanic margin of Pakistan: No influence from Deccan plume

The role of hotter than ambient plume mantle in the formation of a rifted volcanic margin in the northern Arabian Sea is investigated using subsidence analysis of a drill site located on the seismically defined Somnath volcanic ridge. The ridge has experienced > 4 km of subsidence since 65 Ma and lies within oceanic lithosphere. We estimate crustal thickness to be 9.5–11.5 km. Curiously < 400 m of the thermal subsidence occurred prior to 37 Ma, when subsidence rates would normally be at a maximum. We reject the hypothesis that this was caused by increasing plume dynamic support after continental break-up because the size of the thermal anomalies required are unrealistic (> 600 °C), especially considering the rapid northward drift of India relative to the Deccan-Réunion hotspot. We suggest that this reflects very slow lithospheric growth, possibly caused by vigorous asthenospheric convection lasting > 28 m.y., and induced by the steep continent–ocean boundary. Post-rift slow subsidence is also recognized on volcanic margins in the NE Atlantic and SE Newfoundland and cannot be used as a unique indicator of plume mantle involvement in continental break-up.     

A community-wide intercomparison exercise for the determination of dissolved iron in seawater

The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.