Modelling nitrogen and oxygen isotope fractionation during denitrification in a lacustrine redox-transition zone

The stable isotope composition (δ¹⁵N and δ¹⁸O) of nitrate was measured during Summer 1999 in the anaerobic hypolimnion of eutrophic Lake Lugano (Switzerland). Denitrification was demonstrated by a progressive nitrate depletion coupled to increasing δ¹⁵N and δ¹⁸O values for residual nitrate. Maximum δ¹⁵N and δ¹⁸O values amounted to 27.2 and 15.7‰, respectively.¹⁵N and ¹⁸O enrichment factors for denitrification (ε) were estimated using a closed-system model and a dynamic diffusion-reaction model. Using the Rayleigh equation (closed-system approach), we obtained ε values of −11.2 and −6.6‰ for nitrogen and oxygen, respectively. The average ε values derived using the diffusion-reaction model were determined to be −20.7 ± 3.8 for nitrogen and −11.0 ± 1.7 for oxygen. Both N and O isotope fractionation appeared to be lower when denitrification rates where high, possibly in association with high organic carbon availability. In addition, variations in the isotope effects may be attributed to the variable importance of sedimentary denitrification having only a small isotope effect on the water column. The combined measurement of N and O isotope ratios in nitrate revealed that coupled nitrification-denitrification in the open-water was of minor importance. This is the first study of nitrogen and oxygen isotope effects associated with microbial denitrification in a natural lake. Moreover, this study confirms the high potential of δ¹⁸O of nitrate as a valuable biogeochemical tracer in aquatic systems, complementing nitrate δ¹⁵N.     

The presolar grain inventory of fine‐grained chondrule rims in the Mighei‐type (CM) chondrites

We investigated the inventory of presolar silicate, oxide, and silicon carbide (SiC) grains of fine‐grained chondrule rims in six Mighei‐type (CM) carbonaceous chondrites (Banten, Jbilet Winselwan, Maribo, Murchison, Murray and Yamato 791198), and the CM‐related carbonaceous chondrite Sutter's Mill. Sixteen O‐anomalous grains (nine silicates, six oxides) were detected, corresponding to a combined matrix‐normalized abundance of ~18 ppm, together with 21 presolar SiC grains (~42 ppm). Twelve of the O‐rich grains are enriched in ¹⁷O, and could originate from low‐mass asymptotic giant branch stars. One grain is enriched in ¹⁷O and significantly depleted in ¹⁸O, indicative of additional cool bottom processing or hot bottom burning in its stellar parent, and three grains are of likely core‐collapse supernova origin showing enhanced ¹⁸O/¹⁶O ratios relative to the solar system ratio. We find a presolar silicate/oxide ratio of 1.5, significantly lower than the ratios typically observed for chondritic meteorites. This may indicate a higher degree of aqueous alteration in the studied meteorites, or hint at a heterogeneous distribution of presolar silicates and oxides in the solar nebula. Nevertheless, the low O‐anomalous grain abundance is consistent with aqueous alteration occurring in the protosolar nebula and/or on the respective parent bodies. Six O‐rich presolar grains were studied by Auger Electron Spectroscopy, revealing two Fe‐rich silicates, one forsterite‐like Mg‐rich silicate, two Al‐oxides with spinel‐like compositions, and one Fe‐(Mg‐)oxide. Scanning electron and transmission electron microscopic investigation of a relatively large silicate grain (490 nm × 735 nm) revealed that it was crystalline åkermanite (Ca₂Mg[Si₂O₇]) or a an åkermanite‐diopside (MgCaSi₂O₆) intergrowth.     

On the thermal evolution of the terrestrial planets

Physical and chemical constraints for such different planetary objects as the Earth, the Moon and meteorite parent bodies can best be satisfied by thermal history models having high initial temperatures. On the basis of thermal calculations it is suggested that the evolution of the other terrestrial planets (Mars, Venus and Mercury) was also characterized by high initial temperatures. Under these conditions, melting and, consequently, fractionation would set in at an early stage. Because of the resulting redistribution of the long-lived radioactive heat sources and the concentration of these elements in the surface layers, large-scale differentiation could be achieved by partial melting.Paper presented at the Lunar Science Institute Conference on Geophysical and Geochemical Exploration of the Moon and Planets, January 10–12, 1973.     

The occultation of κ geminorum by Eros

The predictions and observations of the occultation of κ Gem by Eros on January 24, 1975, are described. At least eight positive and several critical negative observations were made in western New England. The paucity of observations on the western side of the track makes the analysis somewhat ambiguous, but a circular cross section of diameter up to 23 km gives a good fit to most of the available data. Consideration of a crucial, unconfirmed negative observation indicates that an elliptical solution 17 by 7 km (with the long axis in the direction of motion of the “shadow” of Eros) may be preferable, but this does not represent the positive observations so satisfactorily. The ellipse was therefore distorted into a more irregular shape about 20 km long and 7 km wide, rounded on one long side and flattened on the other. Both this irregular shape and the ellipse yield geometric albedos near 0.5, which is considerably higher than has been derived for most other planets or satellites lacking an atmosphere. The albedo that corresponds to the circular solution (0.1) is less than the polarimetric albedo of 0.21 for Eros. It is suggested either that the circle should be warped into an ellipse of dimensions 21 by 13 km, or, if some weight is given to the critical negative observation and the westernmost positive observation, that the profile is a kind of dumbbell.     

Constraining the Mass Distribution of Cluster Galaxies by Weak Lensing

Analysing the weak lensing distortions of the images of faint background galaxies provides a means to constrain the average mass distribution of cluster galaxies and potentially to test the extent of their dark matter haloes as a function of the density of their environment. The observable image distortions are a consequence of the interplay between the effects of a global cluster mass distribution and the perturbations resulting from individual cluster galaxies. Starting from a reconstruction of the cluster mass distribution with conventional techniques, we apply a maximum likelihood method to infer the average properties of an ensemble of cluster galaxies. From simulations this approach is found to be reliable as long as the galaxies including their dark matter haloes only contribute a small fraction to the total mass of the system. If their haloes are extended, the galaxies contain a substantial mass fraction. In this case our method is still applicable in the outer regions of clusters, where the surface mass density is low, but yields biased estimates of the parameters describing the mass profiles of the cluster galaxies in the central part of the cluster. In that case it will be necessary to resort to more sophisticated strategies by modelling cluster galaxies and an underlying global mass distribution simultaneously. We conclude that galaxy–galaxy lensing in clusters provides a unique means to probe the presence and extent of dark haloes of cluster galaxies.     

A study of presolar material in hydrated lithic clasts from metal-rich carbonaceous chondrites

We report on the investigation of presolar grain inventories of hydrated lithic clasts in three metal-rich carbonaceous chondrites from the CR clan, Acfer 182 (CH3), Isheyevo (CH3/CB_b3), and Lewis Cliff (LEW) 85332 (C3-un), as well as the carbon- and nitrogen-isotopic compositions of the fine-grained clast material. Eleven presolar silicate grains as well as nine presolar silicon carbide (SiC) grains were identified in the clasts. Presolar silicate abundances range from 4 to 22 parts per million (ppm), significantly lower than in pristine meteorites and interplanetary dust particles (IDP), and comparable to recent findings for CM2s and CR2 interchondrule matrix. SiC concentrations lie between 9 and 23 ppm, and are comparable to the values for CI, CM, and CR chondrites. The results of our investigation suggest similar alteration pathways for the clast material, the interchondrule matrix of the CR2 chondrites, and the fine-grained fraction of CM2 chondrites. Fine-grained matter of all three meteorites contains moderate to high ¹⁵N-enrichments (~50‰ ≤ δ¹⁵N ≤ ~1600‰) compared to the terrestrial value, indicating the presence of primitive organic material. We observed no correlation between ¹⁵N-enrichments and presolar dust concentrations in the clasts. This is in contrast to the findings from a suite of primitive IDPs, which display in several cases enhanced bulk ¹⁵N/¹⁴N ratios and high presolar grain abundances of several hundred or even thousand ppm. The bulk ¹⁵N/¹⁴N ratios of the clasts are comparable to the range for primitive IDPs, suggesting a nitrogen carrier less susceptible to destruction by aqueous alteration than silicate stardust.     

Model of the W3(OH) Environment Based on Data for Both Maser and “Quasi-Thermal” Methanol Lines

In studies of the environment of massive young stellar objects, recent progress in both observations and theory allows a unified treatment of data for maser and quasi-thermal lines. Interferometric maser images provide information on the distribution and kinematics of masing gas on small spatial scales. Observations of multiple masing transitions provide constraints on the physical parameters.Interferometric data on quasi-thermal molecular lines permits an investigation of the overall distribution and kinematics of the molecular gas in the vicinity of young stellar objects, including those which are deeply embedded. Using multiple transitions of different molecules, one can obtain good constraints on the physical and chemical parameters. Combining these data enables the construction of unified models, which take into account spatial scales differing by orders of magnitude.Here, we present such a combined analysis of the environment around the ultracompact HII region in W3(OH). This includes the structure of the methanol masing region, physical structure of the near vicinity of W3(OH), detection of new masers in the large-scale shock front and embedded sources in the vicinity of the TW young stellar object.