The channel shape—grain size relation in eastern Australia and some paleohydrologic implications

The relation F = 255 M^?1.08 does not hold for clay-bedded streams in the Namoi—Gwydir distributary system of eastern Australia. Of the streams studied, only those with mobile beds conform to the relation. The application of the relation in paleohydrologic studies must include investigations of the nature of the paleochannels.     

Acute toxicity of the water-soluble fraction of Cook Inlet crude oil to the Manila clam

Recognition of the inherent complexities of oil bioassays prompted the development of several apparatuses designed to deliver uniform solutions of the water-soluble components of crude oil and capable of system equilibration for both static and continuous-flow bioassays without the loss of the more volatile compounds and without the formation of emulsions. Clams from a relatively contaminated area exhibited greater resistance to the water-soluble fraction of Cook Inlet crude oil than specimens from a more pristine area. Behaviour was altered below lethal levels suggesting the possibility of using behavioural modifications as a concommitant criterion of toxicity with mortality. An increase in mortality with a longer exposure period and a significant rate of latent mortalities following the end of the 96-h exposure period suggest that future bioassays with bivalves should be determined over a longer exposure period.     

The distribution of short-chain halogenated aliphatic hydrocarbons in some marine organisms

A number of halogenated aliphatic hydrocarbons have been determined in the various organs of three species of molluscs and five species of fish. In general, the compounds were only slightly enriched (2–25 times) on a dry weight basis relative to their seawater concentrations. The usual order of enrichment was found to be brain > gill > liver > muscle. Methyl iodide was found to be the compound most strongly concentrated.     

Friction in faulted rock at high temperature and pressure

Two hundred observations of frictional behavior of seven low-porosity silicate rocks were made at temperatures to 700°C and pressures from 2.5 to 6 kbar. For all rocks except one, peridotite, stick-slip occurred at low temperature and gave way to stable sliding at some high temperature, different for each rock. These differences could be related to the presence or absence of minerals such as amphibole, mica, or serpentine. Up to some temperature, depending on rock type, the friction stress was relatively unaffected by temperature. The shear stress decreased at higher temperature, and in some cases such decrease was related to the coincidence of fracture and friction strength. While somewhat dependent on rock type, the friction stress for the seven rocks studied was about the same, within 10–15%. Up to 265°C, water had little effect on the frictional behavior of faulted granite at 3 kbar effective pressure. The frictional stresses measured in the laboratory were significantly higher than estimated for natural faults. This difference could be accounted for by high pore pressure or weak alteration materials in the natural fault zone.     

Mercury in some surface waters of the world ocean

Mercury concentrations in mid-latitude eastern Atlantic surface waters is about twice as high as the oceanic average, perhaps due to pollution. Low concentrations in the tropical Atlantic may be due to uptake by plankton off the west coast of Africa.     

The Seasat scanning multichannel microwave radiometer (SMMR): Radiometric calibration algorithm development and performance

Radiometric calibration algorithms for processing Seasat scanning multichannel microwave radiometer (SMMR) flight data are presented. An equation is derived which accounts for losses and reradiation in the microwave components and nonlinearities in the radiometer. The application of pre-launch calibration data to this derivation is described. A performance evaluation of the post-launch operation of the algorithm is presented, indicating temperature resolution of 0.63 K at 6.6 GHz and 1.39 K at 37 GHz.     

The effect of Al(OH)4 on the dissolution rate of quartz

The influence of Al(OH)₄⁻ on the dissolution rate of quartz at pH 10-13 and 59-89 °C was determined using batch experiments. Al(OH)₄⁻ at concentrations below gibbsite solubility depressed the dissolution rate by as much as 85%, and this effect was greater at lower pH and higher Al(OH)₄⁻ concentration. Dissolution rates increased with increasing temperature; however, the percent decrease in rate due to the presence of Al(OH)₄⁻ was invariant with temperature for a given H⁺ activity and Al(OH)₄⁻ concentration. These data, along with what is known about Al-Si interactions at high pH, are consistent with Al(OH)₄⁻ and Na⁺ co-adsorbing on silanol sites and passivating the surrounding quartz surface. The observed pH dependence, and lack of temperature dependence, of inferred Al(OH)₄⁻ sorption also supports the assumption that the acid-base behavior of the surface silanol groups has only a small temperature dependence in this range. A Langmuir-type adsorption model was used to express the degree of rate depression for a given in situ pH and Al(OH)₄⁻ concentration. Incorporation of the rate data in the absence of aluminate into models that assume a first-order dependence of the rate on the fraction of deprotonated silanol sites was unsuccessful. However, the data are consistent with the hypothesis proposed in the literature that two dissolution mechanisms may be operative in alkaline solutions: nucleophilic attack of water on siloxane bonds catalyzed by the presence of a deprotonated silanol group and OH⁻ attack catalyzed by the presence of a neutral silanol group. The data support the dominance of the second mechanism at higher pH and temperature.     

Topographic relations: developing a heuristic device for conceptualising networked relations

This paper considers whether the deployment of a topographical metaphor may add value to the recent discussion of networked relations. The paper discusses how viewing relations as part of a relational landscape may add a third dimension to the discussion by allowing an appreciation of the strength, or entrenchment, of relations, and how these entrenchments impact on the development of new relations and the resistance to watershed events. The heuristic device is explored through the case of air survey in the 1920s and 1930s. This illustrative case demonstrates how relations are held together, resisted and reformed to different degrees depending on the varying topography of the relational landscape.