Low solubility of He and Ar in carbonatitic liquids: Implications for decoupling noble gas and lithophile isotope systems

In order to asses the importance of carbonatitic liquids in transporting noble gases in the mantle, the solubilities of He and Ar in carbonatitic liquids were estimated from analyses of calcium-potassium carbonate glasses that had been synthesized at 1 bar and temperatures between 850 and 950 °C under He or Ar enriched atmospheres. Despite poor reproducibility related to difficulties synthesizing carbonatite glass, we have been able to estimate He and Ar solubilities in carbonatite liquids to be 1 × 10⁻⁸ and 2 × 10⁻⁹ mol g⁻¹ at 1 bar respectively (with ?50% uncertainty). Despite the significant uncertainties on these estimates, it is clear that the noble gases are not massively soluble in carbonatite liquids (within error, these solubilities are identical to their equivalent solubilities in tholeiitic melts). Assuming the results of these low pressure experiments can be applied to mantle conditions, it seems unlikely that carbonatite metasomatism per se transports noble gases within the mantle. It is nevertheless possible that partitioning of lithophile trace elements (including the important radioelements, U, K and Th) and noble gases between a carbonatitic melt and a silicate melt could effectively decouple lithophile and noble gas isotope systematics because the carbonatitic melt expressedly does not transport noble gases, yet is known to efficiently transport incompatible trace elements.     

Comparative Study of MHD Modeling of the Background Solar Wind

Knowledge about the background solar wind plays a crucial role in the framework of space-weather forecasting. In-situ measurements of the background solar wind are only available for a few points in the heliosphere where spacecraft are located, therefore we have to rely on heliospheric models to derive the distribution of solar-wind parameters in interplanetary space. We test the performance of different solar-wind models, namely Magnetohydrodynamic Algorithm outside a Sphere/ENLIL (MAS/ENLIL), Wang–Sheeley–Arge/ENLIL (WSA/ENLIL), and MAS/MAS, by comparing model results with in-situ measurements from spacecraft located at 1 AU distance to the Sun (ACE, Wind). To exclude the influence of interplanetary coronal mass ejections (ICMEs), we chose the year 2007 as a time period with low solar activity for our comparison. We found that the general structure of the background solar wind is well reproduced by all models. The best model results were obtained for the parameter solar-wind speed. However, the predicted arrival times of high-speed solar-wind streams have typical uncertainties of the order of about one day. Comparison of model runs with synoptic magnetic maps from different observatories revealed that the choice of the synoptic map significantly affects the model performance.     

Perceived scientific agreement and support for government action on climate change in the USA

Given the well-documented campaign in the USA to deny the reality and seriousness of anthropogenic climate change (a major goal of which is to “manufacture uncertainty” in the minds of policy-makers and the general public), we examine the influence that perception of the scientific agreement on global warming has on the public’s beliefs about global warming and support for government action to reduce emissions. A recent study by Ding et al. (Nat Clim Chang 1:462–466, 2011) using nationally representative survey data from 2010 finds that misperception of scientific agreement among climate scientists is associated with lower levels of support for climate policy and beliefs that action should be taken to deal with global warming. Our study replicates and extends Ding et al. (Nat Clim Chang 1:462–466, 2011) using nationally representative survey data from March 2012. We generally confirm their findings, suggesting that the crucial role of perceived scientific agreement on views of global warming and support for climate policy is robust. Further, we show that political orientation has a significant influence on perceived scientific agreement, global warming beliefs, and support for government action to reduce emissions. Our results suggest the importance of improving public perception of the scientific agreement on global warming, but in ways that do not trigger or aggravate ideological or partisan divisions.     

Deep 610-MHz Giant Metrewave Radio Telescope observations of the Spitzer extragalactic First Look Survey field – I. Observations, data analysis and source catalogue

Observations of the Spitzer extragalactic First Look Survey field taken at 610 MHz with the Giant Metrewave Radio Telescope are presented. Seven individual pointings were observed, covering a total area of ∼4 deg² with a resolution of 5.8 × 4.7 arcsec², PA 60°. The rms noise at the centre of the pointings is between 27 and 30 μJy before correction for the Giant Metrewave Radio Telescope (GMRT) primary beam. The techniques used for data reduction and production of a mosaicked image of the region are described, and the final mosaic, along with a catalogue of 3944 sources detected above ∼5σ, are presented. The survey complements existing radio and infrared data available for this region.     

Inter-comparison of cosmogenic in-situ He, Ne and Cl at low latitude along an altitude transect on the SE slope of Kilimanjaro volcano (3°S, Tanzania)

Because the intensity and energy spectrum of the cosmic ray flux are affected by atmospheric depth and geomagnetic-field strength, cosmogenic nuclide production rates increase considerably with altitude and to a lesser degree with latitude. The scaling methods used to account for spatial variability in production rates assume that all cosmogenic nuclides have the same altitude dependence. In this study we evaluate whether the production rates of cosmogenic ³⁶Cl, ³He and ²¹Ne change differently with altitude, which is plausible due to the different threshold energies of their production reactions. If so, nuclide-specific scaling factors would be required.Concentrations of the three cosmogenic nuclides were determined in mafic phenocrysts over an altitude transect between 1000 and 4300 m at Kilimanjaro volcano (3°S). Altitude dependence of relative production rates was assessed in two ways: by determination of concentration ratios and by calculation of apparent exposure age ratios for all nuclide pairs. The latter accounts for characteristics of ³⁶Cl that the stable nuclides ³He and ²¹Ne do not possess (radioactive decay, high sensitivity to mineral composition and significant contributions from production reactions other than spallation). All ratios overlap within error over the entire transect, and altitudinal variation in relative production rates is not therefore evident. This suggests that nuclide-specific scaling factors are not required for the studied nuclides at this low-latitude location. However, because previous studies have documented anomalous altitude-dependent variations in ³He production at mid-latitude sites, the effect of latitude on cross-calibrations should be further evaluated.We determined cosmogenic ²¹Ne/³He concentration ratios of 0.1864 ± 0.0085 in pyroxenes and 0.377 ± 0.018 in olivines, agreeing with those reported in previous studies.Despite the absence of independently determined ages for the studied lava surfaces, the consistency in the dataset should enable progress to be made in the determination of the production rates of all three nuclides as soon as the production rate of one of the nuclides has been accurately defined.To our knowledge this is the first time that ³⁶Cl has been measured in pyroxene. The Cl extraction method was validated by measuring ³⁶Cl in co-existing plagioclase phenocrysts in one of the samples.     

‘Letting them go’ - Agricultural retirement and human-livestock relations

Through a focus on agricultural retirement, this paper extends on the recent work considering human-livestock relations. Drawing on research conducted in Hampshire and West Sussex (UK), the paper utilises farmers’ narratives of farm work and retirement to explore the themes of [dis]connection between farmers and their dairy cattle. The paper attempts to add complexity and nuance to assumptions about the nature and extent of animal objectification with commercial dairy farming, and consider the intricate moral geographies [re]created within the individual farm. The discursive and material ‘placings’ of animals are considered alongside an exploration of how the intricate temporality and spatiality of these are disturbed and disrupted by the move to retirement. In discussing these relations the paper examines how animals are central to the everyday lives and identities of farmers and how separation from them alters farmers’ attachment to particular practices, places and social networks.     

Road density as a proxy for population density in regional-scale risk modeling

This paper examines the use of road network data as a proxy for interpreting population density, which is of use in regional-scale qualitative risk assessment for natural hazards. Comparison of available road network and population data at various scales in Ontario and Quebec yields a best-fit relationship of D _P  = 28 D _R ² . Analysis of available high-resolution topographic data for the Caribbean island nation of Saint Lucia suggests similar power law trends, with expected population density in Saint Lucia roughly half that of Canada for the same road density. Together, these findings suggest that D _P  ~ 10–30 D _R ² may represent a useful range broadly applicable for a wide variety of geographic, climactic and socioeconomic settings. The Canadian relationship has been used to generate a population density model for the lowlands of eastern Ontario and southern Quebec, and this model has been compared with the spatial distribution of seismic hazard to develop a qualitative seismic risk map. The seismic risk map, presented primarily for illustrative purposes, shows elevated seismic risk in urban centers in the study area, and along a predominantly rural area east of Quebec City on both shores of the Saint Lawrence River.     

Influence of junction angle on three‐dimensional flow structure and bed morphology at confluent meander bends during different hydrological conditions

Recent field and modeling investigations have examined the fluvial dynamics of confluent meander bends where a straight tributary channel enters a meandering river at the apex of a bend with a 90° junction angle. Past work on confluences with asymmetrical and symmetrical planforms has shown that the angle of tributary entry has a strong influence on mutual deflection of confluent flows and the spatial extent of confluence hydrodynamic and morphodynamic features. This paper examines three‐dimensional flow structure and bed morphology for incoming flows with high and low momentum‐flux ratios at two large, natural confluent meander bends that have different tributary entry angles. At the high‐angle (90°) confluent meander bend, mutual deflection of converging flows abruptly turns fluid from the lateral tributary into the downstream channel and flow in the main river is deflected away from the outer bank of the bend by a bar that extends downstream of the junction corner along the inner bank of the tributary. Two counter‐rotating helical cells inherited from upstream flow curvature flank the mixing interface, which overlies a central pool. A large influx of sediment to the confluence from a meander cutoff immediately upstream has produced substantial morphologic change during large, tributary‐dominant discharge events, resulting in displacement of the pool inward and substantial erosion of the point bar in the main channel. In contrast, flow deflection is less pronounced at the low‐angle (36°) confluent meander bend, where the converging flows are nearly parallel to one another upon entering the confluence. A large helical cell imparted from upstream flow curvature in the main river occupies most of the downstream channel for prevailing low momentum‐flux ratio conditions and a weak counter‐rotating cell forms during infrequent tributary‐dominant flow events. Bed morphology remains relatively stable and does not exhibit extensive scour that often occurs at confluences with concordant beds. Copyright © 2014 John Wiley & Sons, Ltd.     

Laser Ablation (193 nm), Purification and Determination of Very Low Concentrations of Solar Wind Nitrogen Implanted in Targets from the GENESIS Spacecraft

The GENESIS space mission recovered ions emitted by the Sun during a 27 month period. In order to extract, purify and determine the very low quantities of solar nitrogen implanted in the GENESIS targets, a new installation was developed and constructed at the CRPG (Nancy, France). It permitted the simultaneous determination of nitrogen and noble gases extracted from the target by laser ablation. The extraction procedure used a 193 nm excimer laser that allowed for surface contamination in the outer 5 nm to be removed, followed by a step that removed 50 nm of the target material, extracting the solar nitrogen and noble gases implanted in the target. Following purification using Ti and Zr getters for noble gases and a Cu-CuO oxidation cycle for N₂, the extracted gases were analysed by static mode (pumps closed) mass spectrometry using electron multiplier and Faraday cup detectors. The nitrogen blanks from the purification section and the static line (30 minutes) were only 0.46 picomole and 0.47 picomole, respectively.