Evaluation of the ecological effects of heavy metals on the assemblages of benthic foraminifera of the canals of Aveiro (Portugal)

Aveiro is a town with 80,000 inhabitants situated in the central west coast of Portugal. It is located at the centre of the Ria de Aveiro, a coastal lagoon that functions as a multi-estuarine area. This town is crossed by several canals which are connected with lagoon channels through canal locks. The operation of the canal locks influences the hydro dynamism in Aveiro's canal and this and other human activities have left a sedimentary record. The study of these records was based on the sediments grain size and composition, mineralogy (by XRD techniques), geochemical (by ICP-MS), total organic carbon (TOC), and microfaunal (benthic foraminifera) content in 15 grab-samples collected in 2006 in Aveiro's canal. The total elemental concentrations evaluated by total digestion of the sediment fraction <2000 μm revealed the presence of “hot spots” of pollution caused by heavy metal contaminants in some Aveiro canals, related to legacies of past industrial activities. These “hot spots” have, for instance, higher available concentrations of Al, Cd, Co, Cu, Fe, Pb, Mn and Zn (evaluated by sequential chemical extractions) and are located in Paraíso, Alboi, Botirões and Cojo Canals, at sites where the sediments are finer and richer in TOC. Abiotic and biotic variables submitted to principal component analysis and cluster analysis highlights the hydrodynamics and human effects on the system and the negative influence of pollutants on the benthic organisms (foraminifera).     

Sensitivity of runoff and soil erosion to climate change in two Mediterranean watersheds. Part II: assessing impacts from changes in storm rainfall,soil moisture and vegetation cover

The impacts of climate change on storm runoff and erosion in Mediterranean watersheds are difficult to assess due to the expected increase in storm frequency coupled with a decrease in total rainfall and soil moisture, added to positive or negative changes to different types of vegetation cover. This report, the second part of a two‐part article, addresses this issue by analysing the sensitivity of runoff and erosion to incremental degrees of change (from ? 20 to + 20%) to storm rainfall, pre‐storm soil moisture, and vegetation cover, in two Mediterranean watersheds, using the MEFIDIS model. The main results point to the high sensitivity of storm runoff and peak runoff rates to changes in storm rainfall (2·2% per 1% change) and, to a lesser degree, to soil water content (?1·2% per 1% change). Catchment sediment yield shows a greater sensitivity than within‐watershed erosion rates to both parameters: 7·8 versus 4·0% per 1% change for storm rainfall, and ? 4·9 versus ? 2·3% per 1% change for soil water content, indicating an increase in sensitivity with spatial scale due to changes to sediment connectivity within the catchment. Runoff and erosion showed a relatively low sensitivity to changes in vegetation cover. Finally, the shallow soils in one of the catchments led to a greater sensitivity to changes in storm rainfall and soil moisture. Overall, the results indicate that decreasing soil moisture levels caused by climate change could be sufficient to offset the impact of greater storm intensity in Mediterranean watersheds. Copyright © 2009 John Wiley & Sons, Ltd.     

ERORUN-STAFOR: A collaborative observatory for the multidisciplinary study of the critical zone processes in a tropical volcanic watershed including a Tropical Montane Cloud Forest

Tropical volcanic islands are biodiversity hotspots where the Critical Zone (CZ) still remains poorly studied. In such steep topographic environments associated with extreme climatic events (cyclones), deployment and maintenance of monitoring equipment is highly challenging. While a few Critical Zone Observatories (CZOS) are located in tropical volcanic regions, none of them includes a Tropical Montane Cloud Forest (TMCF) at the watershed scale. We present here the dataset of the first observatory from the French network of critical zone observatories (OZCAR) located in an insular tropical and volcanic context, integrating a ‘Tropical Montane Cloud Forest’: The ERORUN-STAFOR observatory. This collaborative observatory is located in the northern part of La Réunion island (Indian Ocean) within the 45.0 km² watershed of Rivière des Pluies (i.e., Rainfall river) which hosts the TMCF of Plaines des Fougères, one of the best preserved natural habitats in La Réunion Island. Since 2014, the ERORUN-STAFOR monitoring in collaboration with local partners collected a multidisciplinary dataset with a constant improvement of the instrumentation over time. At the watershed scale and in its vicinity, the ERORUN-STAFOR observatory includes 10 measurement stations covering the upstream, midstream and downstream part of the watershed. The stations record a total of 48 different variables through continuous (sensors) or periodic (sampling) monitoring. The dataset consists of continuous time series variables related to (i) meteorology, including precipitation, air temperature, relative humidity, wind speed and direction, net radiation, atmospheric pressure, cloud water flux, irradiance, leaf wetness and soil temperature, (ii) hydrology, including water level and temperature, discharge and electrical conductivity (EC) of stream, (iii) hydrogeology, including (ground)water level, water temperature and EC in two piezometers and one horizontally drilled groundwater gallery completed by soil moisture measurements under the canopy. The dataset is completed by periodic time series variables related to (iv) hydrogeochemistry, including field parameters and water analysis results. The periodic sampling survey provides chemical and isotopic compositions of rainfall, groundwater, and stream water at different locations of this watershed. The ERORUN-STAFOR monitoring dataset extends from 2014 to 2022 with an acquisition frequency from 10 min to hourly for the sensor variables and from weekly to monthly frequency for the sampling. Despite the frequent maintenance of the monitoring sites, several data gaps exist due to the remote location of some sites and instrument destruction by cyclones. Preliminary results show that the Rivière des Pluies watershed is characterized by high annual precipitation (>3000 mm y⁻¹) and a fast hydrologic response to precipitation (≈2 h basin lag time). The long-term evolution of the deep groundwater recharge is mainly driven by the occurrence of cyclone events with a seasonal groundwater response. The water chemical results support existing hydrogeological conceptual models suggesting a deep infiltration of the upstream infiltrated rainfall. The TMCF of Plaine des Fougères shows a high water storage capacity (>2000% for the Bryophytes) that makes this one a significant input of water to groundwater recharge which still needs to be quantified. This observatory is a unique research site in an insular volcanic tropical environment offering three windows of observation for the study of critical zone processes through upstream-midstream-downstream measurements sites. This high-resolution dataset is valuable to assess the response of volcanic tropical watersheds and aquifers at both event and long-term scales (i.e., global change). It will also provide insights in the hydrogeological conceptual model of volcanic islands, including the significant role of the TMCFs in the recharge processes as well as the watershed hydrosedimentary responses to extreme climatic events and their respective evolution under changing climatic conditions. All data sets are available at https://doi.org/10.5281/zenodo.7983138 .     

Natural responses of Neoproterozoic dynamic karst springs to rainfall events,São Miguel Watershed,Minas Gerais,Brazil

Karst aquifers consist of complex networks of conduits in which groundwater flows and recharge/discharge processes are generally more dynamic than in other types of aquifers. Due to their intrinsic heterogeneity and anisotropy, monitoring, quantifying, and analysing natural responses of karst springs is an efficient tool. Unlike Cenozoic and Mesozoic rocks, in Neoproterozoic karst systems, groundwater circulates and stores generally in dissolution features known as tertiary porosity, as the rock's primary porosity is recrystallized, considered negligible. This article studies the hydrodynamics of a karst portion of the São Miguel River basin, southwest of the state of Minas Gerais, Brazil. The region is predominantly composed of Neoproterozoic carbonate rocks, dating from about 570 to 540 million years ago. During a hydrological year (2019–2020), three karst springs (S1, S2, and S3) were daily monitored through their natural responses (variations of electrical conductivity, EC, temperature, T, and discharge, Q) to rainfall episodes. The data were interpreted based on the analysis of spring hydrographs, time series, recession curves (seasonal and intra-annual), and statistics of EC, T, and Q variations. The results show the three springs generally exhibit quick flow, typically karstic, in the case of hydrosystems with a well-structured and functional underground drainage network. The time series indicate the hydrosystem drained by S1 presents slower circulation and a lower degree of linearity, resulting from the higher sinuosity of the system, while the hydrosystems of S2 and S3 have similar behaviours, of quick water circulations immediately after a rainy episode. The degrees of karstification classify S1 and S2 as complex and extensive karst systems consisting of several subsystems, and S3 as a system in which the conduit network is more developed at the upper epiphreatic zone than near the outlet.     

Fluorescent sands for measurements of longshore transport rates: a case study from Praia de Faro in southern Portugal

 A field experiment was carried out on a mesotidal reflective beach to relate longshore sand transport rates to wave measurements in medium-energy conditions (H _rms =0.6 m; T _m =6.5 sec; α=20°). Dispersion of fluorescent sand tracers was analyzed using the spatial integration method (SIM). The measured sand transport rate was three times larger than the prediction computed using the longshore wave power approach, while the K factor was determined empirically as 2.32. The study concluded that there is a need to calibrate bulk longshore transport predictors before applying them to steep gradient slopes under plunging waves. Received: 16 May 1997 / Revision received: 20 November 1997     

Fission‐track dating of a tephra layer related to Poti‐Malal and Seguro drifts in the Río Grande basin,Mendoza, Argentina

Two old drift units called Poti‐Malal and Seguro have been differentiated in the Río Grande basin based on relative‐age criteria, stratigraphical relationships, morphology and fission‐track dating. A tephra dated at 0.226 ± 0.025 Ma was deposited on the Poti‐Malal drift and underlies the Seguro outwash, which is inferred to equate with marine oxygen isotope stage 6. The stratigraphical position and age suggest that the tephra post‐dates the Poti‐Malal glaciation and that it is older than the Seguro drift. The Poti‐Malal glaciation must be at least as old as Early–Middle Pleistocene, and the Seguro glaciation is assigned to the penultimate glaciation. The tephra unit may have been deposited during marine oxygen isotope stage 7. Copyright © 2002 John Wiley & Sons, Ltd.     

Erosion of an active fault scarp leads to drainage capture in the Amazon region,Brazil

Far from the continental margin, drainage basins in Central Amazonia should be in topographic steady state; but they are not. Abandoned remnant fluvial valleys up to hundreds of square kilometers in size are observed throughout Amazonia, and are evidence of significant landscape reorganization. While major Late Miocene drainage shifts occurred due to initiation of the transcontinental Amazon River, local landscape change has remained active until today. Driven either by dynamic topography, tectonism, and/or climatic fluctuations, drainage captures in Amazonia provide a natural experiment for assessing the geomorphic response of low‐slope basins to sudden, capture related base‐level falls. This paper evaluates the timing of geomorphic change by examining a drainage capture event across the Baependi fault scarp involving the Cuieiras and Tarumã‐Mirim River basins northwest of the city of Manaus in Brazil. A system of capture‐related knickpoints was generated by base‐level fall following drainage capture; through numerical modeling of their initiation and propagation, the capture event is inferred to have occurred between the middle and late Pleistocene, consistent with other studies of landscape change in surrounding areas. In low‐slope settings like the Amazon River basin, base‐level fall can increase erosion rates by more than an order of magnitude, and moderate to large river basins can respond to episodes of base‐level fall over timescales of tens to hundreds of thousands of years. Copyright © 2013 John Wiley & Sons, Ltd.     

Can recreational echosounder-chartplotter systems be used to perform accurate nearshore bathymetric surveys?

This work intends to determine if low-cost surveying techniques based on recreational echosounders can be used to perform nearshore bathymetry for analysing evolution of coastal sectors. For that purpose, two hydrographic surveying techniques were compared, i.e. (1) a real-time kinematic differential global positioning system (RTK-DGPS) synchronised with a single beam echosounder with real-time tidal elevation correction and (2) a low-cost recreational echosounder-chartplotter system using Global Navigation Satellite Systems (GNSS) with real-time European Geostationary Navigation Overlay Service (EGNOS) augmentation services and depth values post-processed using measured sea level. Two bathymetric data sets were obtained, one by each method, for the same area and survey lines at an ebb tidal delta (Tavira Inlet, Ria Formosa Portugal). Vertical differences were determined assuming no morphological variations between surveys. Results showed that depth elevation differences between bathymetric surfaces were of 0.10?±?0.16 m, slightly higher but within the same order of the error attributable to the used interpolator (0.00?±?0.11 m, triangular surface fitting). The differences between surveys performed with two different equipment sets and using different methodologies for correcting water elevations are very small both quantitative and qualitatively. Those differences can be diminished by improving the tidal level correction and uncertainties associated to different tidal slopes throughout the survey area. Pitch/roll corrections performed with low-cost GPS receivers would be also a valuable addition to the accuracy and precision of the method. It is then concluded that navigation with EGNOS augmentation services and sounding devices ten times cheaper than combined RTK-DGPS with single beam echosounders allow to measure and monitor accurately the nearshore bathymetry.     

Fumarole/plume and diffuse CO2 emission from Sierra Negra caldera, Galapagos archipelago

Measurements of visible and diffuse gas emission were conducted in 2006 at the summit of Sierra Negra volcano, Galapagos, with the aim to better characterize degassing after the 2005 eruption. A total SO₂ emission of 11?±?2?t day^?1 was derived from miniature differential optical absorption spectrometer (mini-DOAS) ground-based measurements of the plume emanating from the Mini Azufral fumarolic area, the most important site of visible degassing at Sierra Negra volcano. Using a portable multigas system, the H₂S/SO₂, CO₂/SO₂, and H₂O/SO₂ molar ratios in the Mina Azufral plume emissions were found to be 0.41, 52.2, and 867.9, respectively. The corresponding H₂O, CO₂, and H₂S emission rates were 562, 394, and 3?t day^?1, respectively. The total output of diffuse CO₂ emissions from the summit of Sierra Negra volcano was 990?±?85?t day^?1, with 605?t day^?1 being released by a deep source. The diffuse-to-plume CO₂ emission ratio was about 1.5. Mina Azufral fumaroles released gasses containing 73.6?mol% of H₂O; the main noncondensable components amounted to 97.4?mol% CO₂, 1.5?mol% SO₂, 0.6?mol% H₂S, and 0.35?mol%?N₂. The higher H₂S/SO₂ ratio values found in 2006 as compared to those reported before the 2005 eruption reveal a significant hydrothermal contribution to the fumarolic emissions. ³He/⁴He ratios measured at Mina Azufral fumarolic discharges showed values of 17.88?±?0.25?R _A , indicating a mid-ocean ridge basalts (MORB) and a Galapagos plume contribution of 53 and 47?%, respectively.     

Fish bile as a biomarker for metal exposure

Fish accumulate several trace elements in muscle, gills and liver, however studies also indicate that metals can be excreted through bile. Since metal contamination leads to modifications in bile composition, biliary excretion offers an alternative way to evaluate the presence of trace-elements. Bile is easier to obtain than other organs and presents a simpler matrix, making it easier for chemical pre-treatment. To verify if bile can be useful as a biomonitoring tool for metal contamination, liver and bile trace element concentrations were determined and correlated. The Artificial Neural Networks statistical technique was used to verify if liver trace-element quantification could be substituted by bile analysis. Results show that significant correlations were obtained between trace elements in bile and liver and the ANN validated the hypothesis that certain trace-elements in bile could be utilized instead of liver trace-elements. Further studies in this field are of interest to further validate this biomarker.