The hydrochemical facies and anomalous fluoride content in the Serra Geral aquifer system,southern Brazil: a GIS approach with tectonic and principal component analysis

Groundwater with high fluoride content and water mixture patterns were studied in Serra Geral aquifer system (SGAS) using three aspects, principal component analysis (PCA), tectonic scenery and hydrochemical interpretation from 309 groundwater chemical data information from deep wells. A four-component model is suggested and explains 81% of total variance in the PCA. Six hydrochemical facies were identified. These facies suggest two different fluoride sources. Tectonic approach shows the relationship between defined hydrochemical facies and regional fracture control. The applied methodology reveals a minimum level to understand hydrochemical mixtures. The fluoride enrichment mechanisms into the groundwater are comprised in advance to guide the future uses of SGAS to the public supply.     

Dynamics of sedimentary environments in the accelerated siltation of a reservoir: the case of Alhama de Granada,southern Spain

An analysis has been made of sedimentary systems involved in the rapid silting of a reservoir constructed in 1974 in Alhama de Granada (S. Spain); in only 30 years the storage capacity of the reservoir has shrunk by 80% and its perimeter has decreased by 64%. A study of sediment lithofacies identified in a series of shallow trenches and of georadar facies identified in a series of almost 900 m lines of ground penetrating radar (GPR) images, together with a survey of surface geology, has identified 3 alluvial systems (2 transversal systems and a longitudinal system) whose deltas have filled in the reservoir. Thus, there are three phases in the evolution of the reservoir siltation: (1) an initial stage (1974–1977) typified by northward progradation of the longitudinal river delta of about 100 m year⁻¹ and an eastward progradation of the transversal system delta of about 20 m year⁻¹; (2) an intermediate stage (1977–1984) in which the longitudinal river delta progradation slowed to 25 m year⁻¹ and the axial drainage became obstructed due to the considerable eastward progradation of the transversal delta; and (3) a final phase (1984–present) in which there have been few changes in the areal distribution of the deltas apart from a southeastward expansion of the transversal delta. Generally, aggradational growth patterns (vertical accretion) have dominated in this final phase. The lithology of the source area, the slope and precipitation distribution has a significant effect not only on the sediment supply, but also indirectly on the creation of accommodation space and on the evolution of stratal growth patterns.     

Map making in small field modulated CMB polarization experiments: approximating the maximum likelihood method

Map making presents a significant computational challenge to the next generation of kilopixel cosmic microwave background polarization experiments. Years worth of time ordered data (TOD) from thousands of detectors will need to be compressed into maps of the T , Q and U Stokes parameters. Fundamental to the science goal of these experiments, the observation of B modes, is the ability to control noise and systematics. In this paper, we consider an alternative to the maximum likelihood method, called destriping , where the noise is modelled as a set of discrete offset functions and then subtracted from the time stream. We compare our destriping code (Descart: the DEStriping CARTographer) to a full maximum likelihood mapmaker, applying them to 200 Monte Carlo simulations of TOD from a ground-based, partial-sky polarization modulation experiment. In these simulations, the noise is dominated by either detector or atmospheric  1/ f   noise. Using prior information of the power spectrum of this noise, we produce destriped maps of T , Q and U which are negligibly different from optimal. The method does not filter the signal or bias the E- or B-mode power spectra. Depending on the length of the destriping baseline, the method delivers between five and 22 times improvement in computation time over the maximum likelihood algorithm. We find that, for the specific case of single detector maps, it is essential to destripe the atmospheric  1/ f   in order to detect B modes, even though the Q and U signals are modulated by a half-wave plate spinning at 5 Hz.     

Warp and eccentricity propagation in discs around black holes

We consider the inward propagation of warping and eccentric disturbances in discs around black holes under a wide variety of conditions. In our calculations, we use secular theories of warped and eccentric discs and assume the deformations to be stationary and propagating in a disc model similar to regions (a) and (b) of Shakura & Sunyaev discs. We find that the propagation of deformations to the innermost regions of the disc is facilitated for low viscous damping and high accretion rate. We relate our results to the possible excitation of trapped inertial modes, and to the observations of high-frequency quasi-periodic oscillations (QPOs) in black hole systems in the very high spectral state.     

Dolomitization,gypsum calcitization and silicification in carbonate–evaporite shallow lacustrine deposits

This paper describes and interprets the mineral and facies assemblages that occur in carbonate–evaporite shallow lacustrine deposits, considering the importance of the processes pathway (i.e. dolomitization, gypsum calcitization and silicification). The Palaeogene deposits of the Deza Formation (Almazán Basin, central‐northern Spain) are selected as a case study to determine the variety of physicochemical processes taking place in carbonate–evaporite shallow lakes and their resulting diagenetic features. Dolostones are the predominant lithology and are composed mainly of dolomite with variable amounts of secondary calcite (5 to 50%), which mainly mimic lenticular gypsum (pseudomorphs). Five morphological types of dolomite crystal were identified as follows: dolomite tubes, dolomite cylinders, rhombohedral dolomite, spheroidal and quasi‐rhombohedral dolomite, and cocoon‐shaped dolomite. The dolomite cylinders and tubes are interpreted as the dolomitized cells of a widespread microbial community. The sequence of diagenetic processes started with growth of microlenticular interstitial gypsum in a calcareous mud deposited on the playa margin mudflats, and that sometimes included microbial sediments. Immediately following growth of gypsum, dolomite replaced the original calcite (or possibly aragonite) muds, the microbial community and the gypsum. Partial or total replacement of gypsum by dolomite was related mainly to the biomineralization of endolithic microbial communities on gypsum crystals. Later calcitization took place under vadose, subaerial exposure conditions. The development of calcrete in distal alluvial settings favoured the release of silica and subsequent silicification on the playa margin mudflats. Stable isotope compositions of calcite range from ?9·02 to ?5·83‰ δ¹³C_PDB and ?7·10 to 1·22‰ δ¹⁸O_PDB; for the dolomite, these values vary from ?8·93 to ?3·96‰ δ¹³C_PDB and ?5·53 to 2·4‰ δ¹⁸O_PDB. Quartz from the cherts has δ¹⁸O_SMOW values ranging from 27·1 to 31·1‰. Wide variation and relatively high δ¹⁸O_SMOW values for dolomite indicate evaporitic and closed hydrological conditions; increased influx of meteoric waters reigned during the formation of secondary calcite spar.     

River tributaries as sediment sinks: Processes operating where the Tapajós and Xingu rivers meet the Amazon tidal river

The Amazon River is the largest fluvial source of fresh water and sediment to the global ocean and has the longest tidally influenced reach in the world. Two major rivers, the Tapajós and Xingu, enter the Amazon along its tidal reach. However, unlike most fluvial confluences, these are not one‐way conduits through which water and sediment flow downstream towards the sea. The drowned‐river valleys (rias) at the confluences of the Tapajós and Xingu with the Amazon River experience water‐level fluctuations associated not only with the seasonal rise and fall of the river network, but also with semidiurnal tides that propagate as far as 800 km up the Amazon River. Superimposed seasonal and tidal forcing, distinct sediment and temperature signatures of Amazon and tributary waters, and antecedent geomorphology combine to create mainstem–tributary confluences that act as sediment traps rather than sources of sediment. Hydrodynamic measurements are combined with data from sediment cores to determine the distribution of tributary‐derived and Amazon‐derived sediment within the ria basins, characterize the sediment‐transport mechanisms within the confluence areas and estimate rates of sediment accumulation within both rias. The Tapajós and Xingu ria basins trap the majority of the sediment carried by the tributaries themselves in addition to ca 20 Mt year^?1 of sediment sourced from the Amazon River. These findings have implications for the interpretation of stratigraphy associated with incised‐valley systems, such as those that dominated the transfer of sediment to the oceans during lowstands in sea level.     

Asbestiform and non-asbestiform morphologies in a talc and vermiculite mine from the province of Córdoba (Argentina): a case study

In this work, a talc and vermiculite mine from the province of Córdoba (Argentina) was investigated with special emphasis on the occurrence of asbestiform and non-asbestiform phases. The meta-ultramafic rock was studied by a multimethodological approach, complementing field studies with petrographic-mineralogical, compositional and morphological analyses. Samples were examined by stereomicroscopy, polarizing light microscopy, SEM–EDS, XRD, DSC-TGA and FTIR. Complementary, compositional and textural analyses were performed with FE-SEM–EDS and EPMA. Talc-rich veins with a laminar and fibrous appearance were at first recognized. However, the fibrous morphology observed both in the field and by microscopy is due to an apparent habit because of the sample orientation. To avoid erroneous interpretations, studies by secondary electron images (SEM) are fundamental to carrying out this type of analysis. Tremolite was identified in different zones of the outcrop; however, only ~40% of the crystals located in the vermiculite zone have dimensions to be considered as asbestiform fibres in the range of respirable particles. In these types of complex deposits affected by superimposed metamorphic, igneous and deformational events, multimethodological approaches are necessary to develop models of occurrence of asbestiform morphologies that may be applicable to other with similar characteristics.     

Estuarine flooding in urban areas: enhancing vulnerability assessment

The assessment of vulnerability provides valuable knowledge in the risk assessment steps of a risk governance process. Given the multiscale, multilevel, and multisectorial aspects of flood risk, the diversified entities that directly and indirectly intervene in risk management require specific outputs from the assessment studies. Urban areas in estuarine margins are particularly exposed and vulnerable to flooding. Such interface conditions are found in the Old City Centre of the Seixal, located in the Tagus estuary, Portugal. Here, two distinct methodologies were applied for the assessment of territorial vulnerability. A regional, lower-scale, methodology explores the application of the statistical procedure based on the SoVI^® at the statistical block level. A second, local and higher-scale, methodology is based in data collected through field matrices at the building and statistical sub-block level. Comparison of results revealed that the lower-scale assessment provides information on the vulnerability drivers at the regional and municipal level. Nevertheless, only at a higher-scale, it is possible to characterize and differentiate the smaller geographical units of analysis that compose the Old City Centre of Seixal. The lower-scale vulnerability assessment allows a strategic response, based on adaptation measures such as spatial planning, institutional capacity building and public awareness. The local level assessment provides more accurate knowledge to support local emergency planning and the allocation of operational and material resources at the urban level. Nevertheless, rather than antagonistic, both models can be considered as complementary, having in mind the requirements of an holistic flood risk governance model.

     

Estimating greenhouse gas emissions from cattle raising in Brazil

The study estimated, for the first time, the greenhouse gas emissions associated with cattle raising in Brazil, focusing on the period from 2003 to 2008 and the three principal sources: 1) portion of deforestation resulting in pasture establishment and subsequent burning of felled vegetation; 2) pasture burning; and 3) bovine enteric fermentation. Deforestation for pasture establishment was only considered for the Amazon and Cerrado. Emissions from pasture burning and enteric fermentation were accounted for the entire country. The consolidated emissions estimate lies between approximately 813 Mt CO₂eq in 2008 (smallest value) and approximately 1,090 Mt CO₂eq in 2003 (greatest value). The total emissions associated with Amazon cattle ranching ranged from 499 to 775 Mt CO₂eq, that of the Cerrado from 229 to 231 Mt CO₂eq, and that of the rest of the country between 84 and 87 Mt CO₂eq. The full set of emissions originating from cattle raising is responsible for approximately half of all Brazilian emissions (estimated to be approximately 1,055 Mt CO₂eq in 2005), even without considering cattle related sources not explicitly estimated in this study, such as energy use for transport and refrigeration along the beef and derivatives supply chain. The potential for reduction of greenhouse gas emissions offered by the Brazilian cattle industry is very high and might constitute Brazil’s most important opportunity for emissions mitigation. The study offers a series of policy recommendations for mitigation that can be implemented by public and private administrators at a low cost relative to other greenhouse gas reduction options.     

Selenium and other trace elements in phosphate rock of Bayovar–Sechura (Peru)

Selenium is an essential trace element in regard to human and other animals' health, but it presents a narrow range of dietary deficiency and toxic excess. Some phosphate rocks are rich in selenium. Furthermore it is necessary to control selenium's and other trace elements’ compositions in the phosphate rocks, because phosphorite ores of different geographical sites are varied, and even ores from the same outcrop can vary substantially in trace element levels.