Photochemical changes in chemical markers of sedimentary organic matter source and age

Several chemical markers of organic matter source and age are shown to be susceptible to light-induced alteration. To test for the photochemical lability of markers previously employed for sediments from the Louisiana coastal zone, we subjected sediments under resuspension conditions to simulated sunlight, and monitored changes in C:N and Br:OC ratios, δ¹³C, Δ¹⁴C, and lignin composition. Markers of terrigenous origin (high C:N, lignin) decreased and δ¹³C became enriched in sediments containing primarily terrigenous organic matter, while a marker of marine organic matter (Br:OC) decreased in samples containing significant contributions from this source. Preferential loss of ¹⁴C from all sediments indicated enhanced photochemical lability of organic matter of relatively recent origin, consistent with the changes in chemical markers. Most, but not all, experimental alterations are consistent with field distributions of these markers. Relatively small experimental changes in the markers in combination with confounding processes in the environment, however, prevent these parallel trends from providing any more than a consistency test for the importance of photochemical reactions in this region.     

Effect of snow cover on pan-Arctic permafrost thermal regimes

This study quantitatively evaluated how insulation by snow depth (SND) affected the soil thermal regime and permafrost degradation in the pan-Arctic area, and more generally defined the characteristics of soil temperature (T_SOIL) and SND from 1901 to 2009. This was achieved through experiments performed with the land surface model CHANGE to assess sensitivity to winter precipitation as well as air temperature. Simulated T_SOIL, active layer thickness (ALT), SND, and snow density were generally comparable with in situ or satellite observations at large scales and over long periods. Northernmost regions had snow that remained relatively stable and in a thicker state during the past four decades, generating greater increases in T_SOIL. Changes in snow cover have led to changes in the thermal state of the underlying soil, which is strongly dependent on both the magnitude and the timing of changes in snowfall. Simulations of the period 2001–2009 revealed significant differences in the extent of near-surface permafrost, reflecting differences in the model’s treatment of meteorology and the soil bottom boundary. Permafrost loss was greater when SND increased in autumn rather than in winter, due to insulation of the soil resulting from early cooling. Simulations revealed that T_SOIL tended to increase over most of the pan-Arctic from 1901 to 2009, and that this increase was significant in northern regions, especially in northeastern Siberia where SND is responsible for 50 % or more of the changes in T_SOIL at a depth of 3.6 m. In the same region, ALT also increased at a rate of approximately 2.3 cm per decade. The most sensitive response of ALT to changes in SND appeared in the southern boundary regions of permafrost, in contrast to permafrost temperatures within the 60°N–80°N region, which were more sensitive to changes in snow cover. Finally, our model suggests that snow cover contributes to the warming of permafrost in northern regions and could play a more important role under conditions of future Arctic warming.     

Water Flows Toward Power: Socioecological Degradation of Lake Urmia,Iran

Water is an invaluable resource, and equitable access to it is a fundamental human right. Disenfranchised groups often lose access to water resources because their interests are not well represented by decision makers. Excluding these groups from resource management policy often results in myopic decisions that contribute to further ecosystem damage. We describe the ecological degradation of Lake Urmia in Iran, which has recently experienced increased salinity and declining water quantity. The lake is a UNESCO Biosphere Reserve and Ramsar site, and supports unique biodiversity in the region. The lake's decline is driven by the destruction of Zagros forests and the government's water policies, which diverted water to more politically connected agricultural land users, increasing social inequity and prompting more deforestation. The most straightforward restoration solution is to discontinue the diversions and allow critical inflows to recharge Lake Urmia, preserving the lake and wetlands for migratory birds, tourists, and local communities.     

Transient hysteresis of near-surface permafrost response to external forcing

Estimates of changes in near-surface permafrost (NSP) area S _p relative to change in globally averaged surface air temperature T _g are made by using the global climate model developed at the A.M. Obukhov Institute of Atmospheric Physics RAS (IAP RAS CM). For ensemble of runs forced by scenarios constructed as return-to-preindustrial continuations of the RCP (Representative Concentration Pathways) scenarios family, a possibility of transient hysteresis in dependence of S _p versus T _g is exhibited: in some temperature range which depends on imposed scenario of external forcing, NSP area is larger, at the same global mean surface air temperature, in a warming climate than in a cooling climate. This hysteresis is visible more clearly for scenarios with higher concentration of greenhouse gases in the atmosphere in comparison to those in which this concentration is lower. Hysteresis details are not sensitive to the type of the prescribed continuation path which is used to return the climate to the preindustrial state. The multiple-valued dependence of S _p on T _g arises due to dependence of soil state in the regions of extra-tropical wetlands and near the contemporary NSP boundaries on sign of external climatic forcing. To study the dependence of permafrost hysteresis on amplitude and temporal scale of external forcing, additional model runs are performed. These runs are forced by idealised scenarios of atmospheric CO₂ content varying, depending on run, with periods from 100 to 1,000 year and with different amplitudes. It is shown that the above-mentioned hysteresis is related to the impact of phase transitions of soil water on apparent inertia of the system as well as to the impact of soil state on atmospheric hydrological cycle and radiation transfer in the atmosphere.     

Application of statistical approaches to analyze geological,geotechnical and hydrogeological data at a fractured-rock mine site in Northern Canada

Mine site characterization often results in the acquisition of geological, geotechnical and hydrogeological data sets that are used in the mine design process but are rarely co-evaluated. For a study site in northern Canada, bivariate and multivariate (hierarchical) statistical techniques are used to evaluate empirical hydraulic conductivity estimation methods based on traditional rock mass characterisation schemes, as well as to assess the regional hydrogeological conceptual model. Bivariate techniques demonstrate that standard geotechnical measures of fracturing are poor indicators of the hydraulic potential of a rock mass at the study site. Additionally, rock-mass-permeability schemes which rely on these measures are shown to be poor predictors of hydraulic conductivity in untested areas. Multivariate techniques employing hierarchical cluster analysis of both geotechnical and geological data sets are able to identify general trends in the data. Specifically, the geological cluster analysis demonstrated spatial relationship between intrusive contacts and increased hydraulic conductivity. This suggests promise in the use of clustering methods in identifying new trends during the early stages of hydrogeological characterization.     

Deciphering petrogenic processes using Pb isotope ratios from time-series samples at Bezymianny and Klyuchevskoy volcanoes,Central Kamchatka Depression

The Klyuchevskoy group of volcanoes in the Kamchatka arc erupts compositionally diverse magmas (high-Mg basalts to dacites) over small spatial scales. New high-precision Pb isotope data from modern juvenile (1956–present) erupted products and hosted enclaves and xenoliths from Bezymianny volcano reveal that Bezymianny and Klyuchevskoy volcanoes, separated by only 9 km, undergo varying degrees of crustal processing through independent crustal columns. Lead isotope compositions of Klyuchevskoy basalts–basaltic andesites are more radiogenic than Bezymianny andesites (²⁰⁸Pb/²⁰⁴Pb = 37.850–37.903, ²⁰⁷Pb/²⁰⁴Pb = 15.468–15.480, and ²⁰⁶Pb/²⁰⁴Pb = 18.249–18.278 at Bezymianny; ²⁰⁸Pb/²⁰⁴Pb = 37.907–37.949, ²⁰⁷Pb/²⁰⁴Pb = 15.478–15.487, and ²⁰⁶Pb/²⁰⁴Pb = 18.289–18.305 at Klyuchevskoy). A mid-crustal xenolith with a crystallization pressure of 5.2 ± 0.6 kbars inferred from two-pyroxene geobarometry and basaltic andesite enclaves from Bezymianny record less radiogenic Pb isotope compositions than their host magmas. Hence, assimilation of such lithologies in the middle or lower crust can explain the Pb isotope data in Bezymianny andesites, although a component of magma mixing with less radiogenic mafic recharge magmas and possible mantle heterogeneity cannot be excluded. Lead isotope compositions for the Klyuchevskoy Group are less radiogenic than other arc segments (Karymsky—Eastern Volcanic Zone; Shiveluch—Northern Central Kamchatka Depression), which indicate increased lower-crustal assimilation beneath the Klyuchevskoy Group. Decadal timescale Pb isotope variations at Klyuchevskoy demonstrate rapid changes in the magnitude of assimilation at a volcanic center. Lead isotope data coupled with trace element data reflect the influence of crustal processes on magma compositions even in thin mafic volcanic arcs.     

Integral transformations of gradiometric data onto a GRACE type of observable

Integral transformations of gravitational gradients onto a Gravity Recovery And Climate Experiment (GRACE) type of observable are derived in this article. The gravitational gradients represent components of the gravitational tensor in the local north-oriented frame. The GRACE type of observable corresponds to a difference between two gravitational vectors as projected onto the line of sight between the two GRACE satellites. In total, three integral transformations relating vertical–vertical, vertical–horizontal and horizontal–horizontal gravitational gradients with the GRACE type of observable are provided. Spectral and closed forms of corresponding isotropic kernels are derived for each transformation. Special cases show that the integral transformations are general and relate gravitational gradients to many other quantities of the gravitational field, such as the gravitational vector, and its radial and tangential components. Correctness of the mathematical derivations is validated in a closed-loop simulation using synthetic data.     

Assess hydrological responses to a warming climate at the Lysina Critical Zone Observatory in Central Europe

Climate warming is having profound effects on the hydrological cycle by increasing atmospheric demand, changing water availability, and snow seasonality. Europe suffered three distinct heat waves in 2019, and 11 of the 12 hottest years ever recorded took place in the past two decades, which will potentially change seasonal streamflow patterns and long-term trends. Central Europe exhibited six dry years in a row since 2014. This study uses data from a well-documented headwater catchment in Central Europe (Lysina) to explore hydrological responses to a warming climate. We applied a lumped parameter hydrologic model Brook90 and a distributed model Penn State Integrated Hydrologic Model (PIHM) to simulate long-term hydrological change under future climate scenarios. Both models performed well on historic streamflow and in agreement with each other according to the catchment water budget. In addition, PIHM was able to simulate lateral groundwater redistribution within the catchment validated by the groundwater table dynamics. The long-term trends in runoff and low flow were captured by PIHM only. We applied different EURO-CORDEX models with two emission scenarios (Representative Concentration Pathways RCP 4.5, 8.5) and found significant impacts on runoff and evapotranspiration (ET) for the period of 2071–2100. Results from both models suggested reduced runoff and increased ET, while the monthly distribution of runoff was different. We used this catchment study to understand the importance of subsurface processes in projection of hydrologic response to a warming climate.     

Evaluating sulfur dynamics during storm events for three watersheds in the northeastern USA: a combined hydrological,chemical and isotopic approach

Concerns related to climate change have resulted in an increasing interest in the importance of hydrological events such as droughts in affecting biogeochemical responses of watersheds. The effects of an unusually dry summer in 2002 had a marked impact on the biogeochemistry of three watersheds in the north‐eastern USA. Chemical, isotopic and hydrological responses with particular emphasis on S dynamics were evaluated for Archer Creek (New York), Sleepers River (Vermont) and Cone Pond (New Hampshire) watersheds. From 1 August to 14 September 2002, all three watersheds had very low precipitation (48 to 69 mm) resulting in either very low or no discharge (mean 0·015, 0·15 and 0·000 mm day^?1 for Archer Creek, Sleepers River and Cone Pond, respectively). From 15 September to 31 October 2002, there was a substantial increase in precipitation totals (212, 246 and 198 mm, respectively) with increased discharge. Archer Creek was characterized by a large range of SO₄^2? concentrations (152 to 389 µeq L^?1, mean = 273 µeq L^?1) and also exhibited the greatest range in δ³⁴S values of SO₄^2? (?1·4 to 8·8 ‰ ). Sleepers River's SO₄^2? concentrations ranged from 136 to 243 µeq L^?1 (mean = 167 µeq L^?1) and δ³⁴S values of SO₄^2? ranged from 4·0 to 9·0 ‰ . Cone Pond's SO₄^2? concentrations (126–187 µeq L^?1, mean = 154 µeq L^?1) and δ³⁴S values (2·4 to 4·3 ‰ ) had the smallest ranges of the three watersheds. The range and mean of δ¹⁸O‐SO₄^2? values for Archer Creek and Cone Pond were similar (3·0 to 8·9 ‰ , mean = 4·5 ‰ ; 3·9 to 6·3 ‰ , mean = 4·9 ‰ ; respectively) while δ¹⁸O‐SO₄^2? values for Sleepers River covered a larger range with a lower mean (1·2 to 10·0 ‰ , mean = 2·5). The difference in Sleepers River chemical and isotopic responses was attributed to weathering reactions contributing SO₄^2?. For Archer Creek wetland areas containing previously reduced S compounds that were reoxidized to SO₄^2? probably provided a substantial source of S. Cone Pond had limited internal S sources and less chemical or isotopic response to storms. Differences among the three watersheds in S biogeochemical responses during these storm events were attributed to differences in S mineral weathering contributions, hydrological pathways and landscape features. Further evaluations of differences and similarities in biogeochemical and hydrological responses among watersheds are needed to predict the impacts of climate change. Copyright © 2008 John Wiley & Sons, Ltd.