Infrared study of the pyrolysis products of sporopollenin and lignite

The effect of pyrolysis at increasing temperature on sporopollenin, lignite and sporopollenin oxidized at 200°C has been investigated using measured infrared band absorption coefficients.Oxidation of sporopollenin in air at 200°C is marked by a decrease in the content of saturated hydrocarbon chains and a strong increase in the concentration of carboxylic acid groups.Pyrolysis of a thick bed of sporopollenin at increasing temperatures leads to the removal of a large proportion of oxygenated functions, before the removal of hydrocarbons. For lignite and oxidized sporopollenin, the loss of both types of functional groups extends over a broader temperature range. Reorganization of the carbonaceous residue at high temperature is hindered if a sufficiently low content of oxygenated functions, carbonyl and carboxyl as well as hydroxyl and ether groups, is not reached before the elimination of hydrocarbons.     

The Bataan orogene: Eastward subduction, tectonic rotations, and volcanism in the western Pacific (Philippines)

The Philippine mobile belt represents a crustal fragment, wedged between two subduction systems exhibiting opposite polarity. The eastern (Philippine—Quezon) system probably originated in the Eocene during northwest—southeast spreading of the west Philippine basin. Westward subduction is continued, probably as a result of northward motion of the Philippine basin crust. The western (Manila—Bataan) system originated in the Oligocene by spreading and formation of the South China Sea basin. Eastward subduction dominates the tectonics in the northern part of the archipelago and resulted in the formation of the Bataan orogene, a sequence of three parallel volcanic arcs emplaced in obducted oceanic crust. Geochemical and radiometric data indicate that the arcs migrated eastward with time (Miocene to Present) while changing composition from tholeiitic via calc-alkaline to shoshonitic. Centers of the latter two types are presently active. Depocenters behind the arcs also migrated eastward with time, suggesting correction of the isostatic disequilibrium caused by geanticlinal uplift of the orogene. Paleomagnetic evidence suggests that central Luzon is rotating counterclockwise probably due to differential spreading in the South China Sea basin. The west Philippine basin rotates clockwise. This results in significant “Einengung” in the southern part of the archipelago.     

Structural identification using linear models and earthquake records

The problem of determining linear models of structures from seismic response data is investigated using ideas from the theory of system identification. The approach is to determine the optimal estimates of the model parameters by minimizing a selected measure-of-fit between the responses of the structure and the model. Because earthquake records are normally available from only a small number of locations in a structure, and because of noise in the records, it is necessary in practice to estimate parameters of the dominant modes in the records, rather than the stiffness and damping matrices of the linear model. A new algorithm is developed to determine the optimal estimates of the modal parameters. After tests with simulated data, the method is applied to a multi-storey building using records from the 1971 San Fernando earthquake in California. New information is obtained concerning the properties of the lower modes of the building and the time-varying character of the equivalent linear parameters.     

Experimental investigation of the metamorphism of siliceous dolomites

For the reaction: 1 diopside+3 dolomite ?2 forsterite+4 calcite+2 CO₂ (14) the following P _total?T-brackets have been determined experimentally in the presence of a gasphase consisting of 90 mole%CO₂ and 10 mole%H₂O∶1 kb, 544°±20° C; 3kb, 638°±15° C; 5kb, 708°±10° C; 10kb, 861°±10° C. The determination was carried out with well defined synthetic minerals in the starting mixture. The MgCO₃-contents of the magnesian calcites formed by the reaction in equilibrium with dolomite agree very well with the calcite-dolomite miscibility gap, which can be recalculated from the activities and the activity coefficients of MgCO₃ as given by Gordon and Greenwood (1970). The equilibrium constant K _14b was calculated with respect to the reference pressure P ₀=1 bar using the experimentally determined \(P_{total} TX_{CO_2 }\) brackets, the activities of MgCO₃ and CaCO₃ (Gordon and Greenwood 1970; Skippen 1974) and the fugacities of CO₂ Holloway (1977) considering the correction of Flowers (1979). Results are plotted as function of the absolute reciprocal temperature in Fig. 1. For the temperature range of 530° to 750° C the following linear expression can be given for the natural logarithm of K_14b: (g) $$[ln K_{14b} ]_T^P = - \frac{{18064.43}}{{T\left( {^\circ K} \right)}} + 38.58 + \frac{{0.308(P - 1 bar)}}{{T\left( {^\circ K} \right)}}$$ where P is the total pressure in bars and T the temperature in degrees Kelvin. Combining Equation (g) with the activities of MgCO₃ and CaCO₃ gives the equilibrium fugacity \(f_{CO_2 }\) : (i) $$[ln f_{CO_2 } ]_T^P = - \frac{{11635.44}}{{T\left( {^\circ K} \right)}} + 21.09 + \frac{{0.154(P - 1 bar)}}{{T\left( {^\circ K} \right)}}$$ Equation (i) and the fugacities of CO₂ permit to calculate the equilibrium data in terms of \(P_{CO_2 }\) and T (see Fig. 3) or P _total, T and \(X_{CO_2 }\) (see Fig. 5). Combining the \(P_{total} TX_{CO_2 }\) equilibrium data of the above reaction with those of the previously investigated reaction (Metz 1976): 1 tremolite+11 dolomite ?8 forsterite+13 calcite+9 CO₂+1 H₂O yields the stability conditions of the four-mineral assemblage: diopside+calcian dolomite+forsterite +magnesian calcite and the stability conditions of the five-mineral assemblage: tremolite+calcian dolomite+forsterite +magnesian calcite+diopside both shown in Fig. 6. Since these assemblages are by no means rare in metamorphic siliceous dolomites (Trommsdorff 1972; Suzuki 1977; Puhan 1979) the data of Fig. 6 can be used to determine the pressure of metamorphism and to estimate the composition of the CO₂-H₂O fluid provided the temperature of the metamorphic event was determined using the calcite-dolomite geothermometer.     

Some thermodynamical and microphysical aspects of monsoon clouds

The thermodynamical and microphysical characteristics of monsoon clouds in the Poona, Bombay and Rihand regions were investigated using extensive aircraft in-cloud observations. The number of clouds sampled at Poona, Bombay and Rihand is 2199, 169 and 104 respectively. The temperatures inside the cloud are colder than its environment at Poona and Rihand. The maximum difference is about 3°C at the cloud base level and the difference decreased with height. At Bombay the difference is less than 1°C and at some levels the temperatures inside the cloud are warmer than its environment. The lapse rates of temperatures inside the cloud are slightly less than those in the immediate environment of the cloud. The environmental lapse rates are nearly equal to the saturated adiabatic value. The positive increments in liquid water content (LWC) are associated with the increments in temperature inside the cloud. Similarly positive increments in temperatures inside the cloud are associated with the increments in temperature of its immediate environment at the same level or the layer immediately above. The maximum cloud lengths observed at Poona and Bombay respectively are 14 and 3 km. The horizontal cross-section of LWC showed a maximum number of 13 peaks in clouds at Poona while only 7 peaks were observed at Bombay. The location of maximum LWC in the horizontal cross-section is more or less at the centre of the cloud. The LWC profile showed an increase with height from the base of the cloud at Poona and Bombay. There is no marked variation of LWC with height at Rihand. The total droplet concentration at different altitudes at Poona and Bombay is in the range 28–82 cm^?3. The size distribution of cloud droplets experienced a broadening effect with increase in height from the cloud base at Poona. The broadening effect at Bombay is not as marked as that at Poona.     

The solubility of aragonite in seawater—I. Effect of pH and water chemistry at one atmosphere

The effect of water chemistry on the solubility of aragonite in seawater has been defined experimentally as a series of apparent solubility products measured with respect to pH at one atmosphere.The dominant control of the apparent solubility product of aragonite is the carbonate ion concentration, and this is primarily a function of pH. In the light of this fact, we have reconciled our data with 81 other reported values of aragonite solubility by simply examining the water chemistry of the waters in which they were determined.     

Pyrolysis-high resolution gas chromatography and pyrolysis gas chromatography-mass spectrometry of kerogens and kerogen precursors

A series of kerogens and kerogen precursors isolated from DSDP samples, oil shales and Recent algal mats have been examined by Curie point pyrolysis-high resolution gas chromatography and gas chromatography-mass spectrometry. This study has shown that the three main types of kerogens (marine, terrestrial and mixtures of both) can be characterized using these techniques. The marine (algal) kerogens yield principally aliphatic products and the terrestrial kerogens yield more aromatic and phenolic products with some n-alkanes and n-alkenes. The yields of n-alkanes and n-alkenes increase and phenols decrease with increasing geologic age, however, pyrolysis-GC cannot be used to characterize the influence of short term diagenesis on the kerogen structure.     

On propagation of love-type waves on a spherical model with rigidity and density both varying exponentially with the radial distance

Summary The propagation of Love type waves on a spherical model' in the mantle of which the rigidity and density vary exponentially with the radial distance while in the core they remain constant — has been investigated. The frequency equation that has been worked out has been examined in detail for the existence of root in the particular cases when they involve Bessel Functions of smallest and largest orders.