Mudrocks from the Siberian Hypostratotype of the Riphean and Vendian: Chemistry,Sm–Nd Isotope Systematics of Sources,and Formation Stages

Lithology and Mineral Resources - The chemical composition and Nd isotope systematics were obtained for mudrocks (mudstones) from sections of the Siberian hypostratotype of the Riphean and Vendian...     

The Cone-in-Cone Structure and Its Origin

Morphostructural investigation of carbonate cone-in-cone formations allows to conclude that they belong to self-organizing (dissipative, according to I. Prigogine's terminology) systems of the geological past formed in a thermogradient field at the expense of energy of heat and mass transfer (Prigogine and Stengers, 1984). First, the fluid-convective metasomatic hypothesis unites and reconciles the most well-known hypotheses that previously seemed to be incompatible and transforms them to rather consistent particular cases of a more intricate multistage geological phenomenon. Second, it helps to identify the morphologically and genetically analogous noncarbonate structures that mimic biogenic ones. The probable indicative role of cone-in-cone structure in the mapping of fluid-conducting systems is a consequence of the proposed hypothesis.     

The Skaergaard Layered Series. Part VI. Excluded Trace Elements

In contrast to the smooth trends of major elements and mineralcompositions, the excluded trace elements in the SkaergaardLayered Series have an irregular distribution that does notconform to the normal trends of Rayleigh-type fractionation.Their concentrations are about constant or even decline throughthe Lower and Middle Zones before increasing sharply to reachmaximum concentrations 100–200 m above the Sandwich Horizon.As in the case of included elements, the relative concentrationsof excluded elements in coexisting phases deviate widely fromthose predicted by experimentally determined partition coefficientsunder presumed magmatic conditions. This is seen most clearlyin the immiscible melanogranophyres and conjugate ferrogabbros.Although the major elements conform to the experimentally determinedrelations for immiscible liquids, the trace elements do not;they follow a totally independent trend. The abrupt increasein the concentrations of excluded elements in the upper partof the intrusion could plausibly be attributed to an additionof new magma or to a density inversion that resulted in upwardmigration of a late liquid or fluid, but these possibilitiesare inconsistent with the compositional and spatial relationsof the upper parts of the intrusion. Although a late residualliquid certainly migrated upward, the most likely explanationfor the observed distribution of excluded elements is that thepartition coefficients were altered by volatile components,which gradually increased during the early stages of crystallizationthen began to exsolve near the top of the Middle Zone. KEY WORDS: igneous differentiation; Skaergaard intrusion     

Reconstruction of the diagenesis of the fluvial-lacustrine- deltaic sandstones and its influence on the reservoir quality evolution-- Evidence from Jurassic and Triassic sandstones, Yanchang Oil Field, Ordos Basin

The reservoir quality of Jurassic and Triassic fluvial and lacustrine-deltaic sandstones of the Yanchang Oil Field in the Ordos Basin is strongly influenced by the burial history and facies-related diagenetic events. The fluvial sandstones have a higher average porosity (14.8%) and a higher permeability (12.7×10?3 ?m2) than those of the deltaic sandstones (9.8% and 5.8 ×10?3 ?m2, respectively). The burial compaction, which resulted in 15% and 20% porosity loss for Jurassic and Triassic sandstones, respectively, is the main factor causing the loss of porosity both for the Jurassic and Triassic sandstones. Among the cements, carbonate is the main one that reduced the reservoir quality of the sandstones. The organic acidic fluid derived from organic matter in the source rocks, the inorganic fluid from rock-water reaction during the late diagenesis, and meteoric waters during the epidiagenesis resulted in the formation of dissolution porosity, which is the main reason for the enhancement of reservoir-quality.     

Mathematical modeling of PCB bioaccumulation in Perna viridis

In the present work, we built a mathematical model of polychlorinated biphenyl (PCB) bioaccumulation in Perna viridis, namely, a one-compartment model with a time dependent incorporation rate R (μg g⁻¹ lipid per ppb water per day), with positive substrate cooperativity as the underlying physical mechanism. The temporal change of the PCB concentration Q (μg g⁻¹ lipid) in the soft tissues of the mussel depends on the competition of the input rate RW and the output rate kQ, where W is the concentration of PCB in water (ppb water) and k is the elimination rate (per day). From our experimental data, k=0.181±0.017 d⁻¹. The critical concentration in water W_c for positive substrate cooperativity was found to be 2.4 ppb. Below W_c, R is a constant. For a water concentration of 0.5 ppb Aroclor 1254, R=24.0±2.4 μg g⁻¹ lipid ppb⁻¹ d⁻¹. Above W_c, positive substrate cooperativity comes into effect and R becomes a function of time and dependent on the concentration Q in a form R=γQ/(Q+δ). This is the case for a water concentration of 5 ppb Aroclor 1254, where γ=15.1 μg g⁻¹ lipid ppb⁻¹ d¹ and δ≈200 μg g⁻¹ lipid. From this model, the uptake is exponentially increasing when the PCB concentration in the mussel is small compared to 200 μg g⁻¹ lipid, and hyperbolically increasing when the concentration is large compared to 200 μg g⁻¹ lipid, which are consistent with the experimental data. The model is useful for understanding the true processes taking place during the bioaccumulation and for risk assessment with higher confidence. Future experimental data which challenge the present model are anticipated and in fact desirable for improvement and perfection of the model.