Ice-rafted volcanic ash in the South Atlantic sector of the Southern Ocean during the last 100,000 years

Eucampia antarctica (Castr.) Mangin abundance curves for two piston cores from the western Agulhas Basin (southeast Atlantic sector of the Southern Ocean) were used to place volcanic glass shard and ice-rafted debris abundance curves into a stratigraphic framework for the last 100,000 years. A direct correlation is shown between increased abundance of E. antarctica, tephra and ice-rafted debris; low abundances are often characterized by calcareous sediment in the northern core. Peaks in abundance of E. antarctica have been interpreted as an indication of glacial periods and the increased ice-rafted debris and tephra during glacial periods is evidence for an ice-rafted origin for the tephra.Microprobe geochemical analysis of volcanic glass shards provides no single distinct source for the ash. The geochemical data is consistent, but not definitive, with a primary source in the Scotia Arc and a minor source from Bouvet Island. Between core correlations of geochemically “fingerprinted” dispersed tephra zones were not successful due to variability of glass shard geochemistry and limited sample size.     

Kinetics of the reactions of hydroxyl radicals with aliphatic ethers studied under simulated atmospheric conditions: Temperature dependences of the rate coefficients

Rate coefficients have been measured for the reactions of hydroxyl radicals with five aliphatic ethers over the temperature range 242–328 K. Competitive studies were carried out in an atmospheric flow reactor in which the hydroxyl radicals were generated by the photolysis of methyl nitrite in the presence of air containing nitric oxide. The reaction of OH with 2,3-dimethyl-butane was used as the reference reaction and the following Arrhenius parameters have been obtained for the reactions: OH+RORproducts:

Sub-B″ layering in the Southern Caribbean: The Aruba Gap and Venezuela Basin

Multichannel seismic data in the Aruba Gap region near JOIDES/DSDP Site 153 verify the presence of a deep sub-B″ reflection. One multichannel seismic line trends NE-SW on and along the edge of Beata Ridge and passes within 1 km of Site 153, and another line runs N-S across the entire Aruba Gap with the drill site 4 km east from its northern end. Closely spaced velocity analyses indicate the presence of deep primary reflection events and enable calculation of interval velocities between the A″-B″ marker horizons. Deconvolved, true amplitude, normal incidence profiles sharply delineate the A″-B″ marker horizons and indicate the presence of the sub-B″ reflection event. On the NE-SW line, this deep reflector is best described as a “diffuse” discontinuous zone, relatively horizontal, lying about 0.8 seconds of two-way travel time below the B″ reflector, with an interval velocity of approximately 5.0 km/s between Horizon B″ and this reflection. The N-S line is more complex since the sub-B′' reflection event is masked by a strong internal multiple from the A″-B″ interval. In the central and western Venezuela Basin, deep primary reflections beneath Horizon B″ are also observed on the northern and western sides of what appears to be a major fault zone. This fault zone separates the smooth B″ and sub-B″ reflectors on the northern and western sides of this fault zone from what appears to be typical oceanic basement. The widespread presence of sub-B″ reflections yielding high interval velocities for the section between these events and Horizon B″ suggest that this material is probably igneous in origin.     

Groundwater’s significance to changing hydrology, water chemistry, and biological communities of a floodplain ecosystem, Everglades, South Florida, USA

The Everglades (Florida, USA) is one of the world’s larger subtropical peatlands with biological communities adapted to waters low in total dissolved solids and nutrients. Detecting how the pre-drainage hydrological system has been altered is crucial to preserving its functional attributes. However, reliable tools for hindcasting historic conditions in the Everglades are limited. A recent synthesis demonstrates that the proportion of surface-water inflows has increased relative to precipitation, accounting for 33% of total inputs compared with 18% historically. The largest new source of water is canal drainage from areas of former wetlands converted to agriculture. Interactions between groundwater and surface water have also increased, due to increasing vertical hydraulic gradients resulting from topographic and water-level alterations on the otherwise extremely flat landscape. Environmental solute tracer data were used to determine groundwater’s changing role, from a freshwater storage reservoir that sustained the Everglades ecosystem during dry periods to a reservoir of increasingly degraded water quality. Although some of this degradation is attributable to increased discharge of deep saline groundwater, other mineral sources such as fertilizer additives and peat oxidation have made a greater contribution to water-quality changes that are altering mineral-sensitive biological communities.