The Rockall Bank Mass Flow: Collapse of a moated contourite drift onlapping the eastern flank of Rockall Bank,west of Ireland

The Rockall Bank Mass Flow (RBMF) is a large, multi-phase submarine slope failure and mass flow complex. It is located in an area where the Feni Drift impinges upon the eastern flank of the Rockall Bank in the NE Atlantic. A 6100 km² region of slope failure scarps, extending over a wide water depth range and with individual scarps reaching up to 22 km long and 150 m high, lies upslope of a series of mass flow lobes that cover at least 18,000 km² of the base of slope and floor of the Rockall Trough. The downslope lobe complex has a negative topographic relief along much of its northern boundary, being inset below the level of the undisplaced contourite drift at the base of slope. The southern margin is topographically more subtle but is marked by the sharp termination of sediment waves outside the lobe. Within the lobe complex the southern margin of the largest lobe shows a positive relief along its southern margin. The initial failure is suggested to have occurred along coherent layer-parallel detachment surfaces at depths of up to 100 m and this promoted initial downslope block sliding which in turn transformed into debris flows which moved out into the basin. The remains of a deep erosional moat linked to the onlapping contourite complex bisects the region of failed slope, and post-failure thermohaline currents have continued to modify the mass flow in this area. Differential sedimentation and erosion associated with the moat may have promoted slope instability. Following the major failure phase, continuous readjustments of the slope occurred and resulted in small-volume turbidites found in shallow gravity cores collected on the lobes. The short term trigger for the failure remains uncertain but earthquake events associated with a deep-seated tectonic lineament to the north of the mass flow may have been important. A Late Pleistocene age for the slope failure is likely. The RBMF is unusual in that it records large-scale collapse of a contourite body that impinged on a sediment-undersupplied slope system. Unlike many other large slope failure complexes along the NE Atlantic margin, the RBMF occurs in a region where there was little overloading by glacial sediment.     

Molecular characterization of dissolved organic matter (DOM) along a river to ocean transect of the lower Chesapeake Bay by ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry

In this study, electrospray ionization coupled to Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS) is utilized to molecularly characterize DOM as it is transported along a river to estuary to ocean transect of the lower Chesapeake Bay system. The ultrahigh resolving power (greater than 500,000) and mass accuracy of FTICR-MS allow for the resolution of the thousands of components in a single DOM sample, and can therefore elucidate the molecular-level changes that occur during DOM transformation from a terrestrial location to the marine environment. An important feature of FTICR-MS is that its sensitivity allows for direct analysis of low salinity samples without employing the traditional concentration approaches involving C₁₈ extraction or ultrafiltration. To evaluate the advantages of using direct analysis, a C₁₈ extract of riverine water is compared to its whole, unfractionated water, and it was determined that the C₁₈ extraction is selective in that it eliminates two major series of compounds. One group is aliphatic amines/amides that are not adsorbed to the C₁₈ disk because they exist as positive ions prior to extraction. The second group is tannin-like compounds with higher oxygen contents and a more polar quality that also allow them not to be adsorbed to the C₁₈ disk. This direct approach could not be used for brackish/saline waters, so the C₁₈ method is resorted to for those samples. Along the subject transect, a significant difference is observed in the molecular composition of DOM, as determined from assigned molecular formulas. The DOM tends to become more aliphatic and contain lower abundances of oxygen-rich molecules as one progresses from inshore to the offshore. A considerable amount of molecular formula overlap does exist between samples from sites along the transect. This can be explained as either the presence of refractory material that persists throughout the transect, due to its resistance to degradation, or that the assigned molecular formulas are the same but the chemical structures are different. ESI-FTICR-MS is a powerful technique for the investigation of DOM and has the ability to detect compositional variations along the river to ocean transect. Visualization tools such as two dimensional and three dimensional van Krevelen diagrams greatly assist in highlighting the shift from the more aromatic, terrestrial DOM to the more aliphatic, marine DOM.     

Impact of a sea breeze on the boundary-layer dynamics and the atmospheric stratification in a coastal area of the North Sea

In-situ sodar and lidar measurements were coupled with numerical simulations for studying a sea-breeze event in a flat coastal area of the North Sea. The study’s aims included the recognition of the dynamics of a sea-breeze structure, and its effects on the lower troposphere stratification and the three-dimensional (3D) pollutant distribution. A sea breeze was observed with ground-based remote sensing instruments and analysed by means of numerical simulations using the 3D non-hydrostatic atmospheric model Meso-NH. The vertical structure of the lower troposphere was experimentally determined from the lidar and sodar measurements, while numerical simulations focused on the propagation of the sea breeze inland. The sea-breeze front, the headwind, the thermal internal boundary layer, the gravity current and the sea-breeze circulation were observed and analysed. The development of a late stratification was also observed by the lidar and simulated by the model, suggesting the formation of a stable multilayered structure. The transport of passive tracers inside the sea breeze and their redistribution above the gravity current was simulated too. Numerical modelling showed that local pollutants may travel backward to the sea above the gravity current at relatively low speed due to the shearing between the landward gravity current and the seaward synoptic wind. Such dynamic conditions may enhance an accumulation of pollutants above coastal industrial areas.     

Influence of a Two-scale Surface Roughness on a Neutral Turbulent Boundary Layer

Flow in the urban boundary layer is strongly influenced by the surface roughness, which is composed principally of isolated buildings or groups of buildings. Previous research has shown that the flow regime depends on the characteristic height of these obstacles (H), and the spacing between them (W). In reality, the urban boundary layer contains roughness elements with a wide range of length scales; in many practical situations these can be classified into large-scale roughness—buildings, or groups of buildings—and small-scale roughness, such as street furniture and elements on the façades and roofs. It is important to understand how the small-scale roughness might modify mass and momentum transfer in the urban boundary layer, but relatively little information is available concerning the potential interaction between large- and small-scale roughness elements in the different flow regimes. This problem has been studied using wind-tunnel experiments, by measuring vertical velocity profiles over a two-dimensional obstacle array, adding small-scale roughness elements to the top of larger parallel square bars. The experiments were performed for different cavity aspect ratios: the results show that the small-scale roughness increases the turbulence intensities and the momentum transfer when the large-scale obstacles are closely packed (H/W > 1) but it has very little effect for more widely-spaced obstacles (H/W < 1).     

Steering of upper ocean currents and fronts by the topographically constrained abyssal circulation

A two-layer theory is used to investigate (1) the steering of upper ocean current pathways by topographically constrained abyssal currents that do not impinge on the bottom topography and (2) its application to upper ocean – topographic coupling via flow instabilities where topographically constrained eddy-driven deep mean flows in turn steer the mean pathways of upper ocean currents and associated fronts. In earlier studies the two-layer theory was applied to ocean models with low vertical resolution (2–6 layers). Here we investigate its relevance to complex ocean general circulation models (OGCMs) with high vertical resolution that are designed to simulate a wide range of ocean processes. The theory can be easily applied to models ranging from idealized to complex OGCMs, provided it is valid for the application. It can also be used in understanding some persistent features seen in observed ocean frontal pathways (over deep water) derived from satellite imagery and other data. To facilitate its application, a more thorough explanation of the theory is presented that emphasizes its range of validity. Three regions of the world ocean are used to investigate its application to eddy-resolving ocean models with high vertical resolution, including one where an assumption of the two-layer theory is violated. Results from the OGCMs with high vertical resolution are compared to those from models with low vertical resolution and to observations. In the Kuroshio region upper ocean – topographic coupling via flow instabilities and a modest seamount complex are used to explain the observed northward mean meander east of Japan where the Kuroshio separates from the coast. The Japan/East Sea (JES) is used to demonstrate the impact of upper ocean – topographic coupling in a relatively weak flow regime. East of South Island, New Zealand, the Southland Current is an observed western boundary current that flows in a direction counter to the demands of Sverdrup flow and counter to the direction simulated in nonlinear global flat bottom and reduced gravity models. A model with high vertical resolution (and topography extending through any number of layers) and a model with low vertical resolution (and vertically compressed but otherwise realistic topography confined to the lowest layer) both simulate a Southland Current in the observed direction with dynamics depending on the configuration of the regional seafloor. However, the dynamics of these simulations are very different because the Campbell Plateau and Chatham Rise east and southeast of New Zealand are rare features of the world ocean where the topography intrudes into the stratified water column over a relatively broad area but lies deeper than the nominal 200 m depth of the continental shelf break, violating a limitation of the two-layer theory. Observations confirm the results from the high vertical resolution model. Overall, the model simulations show increasingly widespread upper ocean – topographic coupling via flow instabilities as the horizontal resolution of the ocean models is increased, but fine resolution of mesoscale variability and the associated flow instabilities are required to obtain sufficient coupling. As a result, this type of coupling is critical in distinguishing between eddy-resolving and eddy-permitting ocean models in regions where it occurs.     

Distribution and storage of sediment-associated heavy metals downstream of the remediated Rum Jungle Mine on the East Branch of the Finniss River,Northern Territory,Australia

Instream, overbank and cut riverbank exposures along the East Branch of the Finniss River downstream of Rum Jungle Mine, Northern Territory have been analysed for their total metal concentrations using instrumental neutron activation analysis (INAA). Concentration values for the < 62.5 μm and bulk sample fractions are compared to Australian sediment quality guidelines values (ANZECC/ARMCANZ, 2000). The results reveal that channel and overbank environments are contaminated with heavy metals, with many samples exceeding the low and high sediment guidelines values. The < 62.5 μm fraction is consistently more contaminated than bulk samples as are instream environments compared to adjacent overbank environments. Metal concentrations are strongly correlated to sediment pH and Fe values, suggesting that these variables are significant in controlling the spatial distribution of sediment-associated metals. The strong positive correlation between sediment-associated metals and Fe is probably related to the process of metal sequestration by Fe (and Mn) oxyhydroxides. The spatial distribution of sediment-associated metals downstream of the Rum Jungle Mine site does not display a simple distance–metal concentration decay pattern. It is suggested that the non-uniform spatial distribution of sediment-associated metals is a function of local, reach-scale variations in channel geometry and geomorphology, which control sediment storage and transfer patterns. In cut riverbank exposures the vertical of metals distribution is non-uniform and probably reflects differential metal mobility. Despite rehabilitation of the mine site in the 1980s, the elevated sediment-associated metal concentrations that remain within the East Branch of the Finniss River system are likely to render the system contaminated for the foreseeable future and limit the potential for the full recovery of aquatic and terrestrial flora and fauna.     

5: Late Variscan mineralizing systems related to orogenic processes: The French Massif Central

The French Massif Central constitutes an exceptional study area due to the diversity of its metallic deposits, its internal position in the Variscan belt, and the abundance of available geological, geophysical and metallogenic data obtained within the GeoFrance 3D programme. The deposits, formed towards the end of the orogenic evolution, represent the economic products of two distinct mineralizing systems, a Au ± Sb hydrothermal system and a W ± Sn and rare-metals magmatic–hydrothermal system, which were simultaneously active during a short time span between ca. 310 and 300 Ma.Two types of gold deposit can be distinguished on the basis of their depth of emplacement: “deep-seated” gold deposits developed under lithostatic to hydrostatic pressure during rapid exhumation, and “shallow” gold deposits emplaced under hydrostatic pressure with no significant uplift.Deposits of W ± Sn and rare-metals were emplaced in the upper crust during final crystallization of specialized magmas after their rapid ascent, perhaps enhanced by simultaneous regional uplift. The gold-bearing systems are associated with a complex network of re-activated crustal-scale faults initially active during the period between 335 and 315 Ma. Normal motion along the faults, coeval with 335 to 315 Ma granite–migmatite domes, played a major role in the 3D distribution of the hydrothermal plumbing system. Gold and related metals were carried within huge hydrothermal cells, which reached ca. 100 km by 10 km in area, and 30 km in depth. In contrast, granites rich in magmatophile elements (W, Sn, rare-metals) generated smaller hydrothermal cells (10 km by 10 km in area, and < 6 km deep). Extraction of metals, by both deep-seated fluids and specialized magmas, occurred during granulitization of the lower crust at 300 ± 15 Ma. In the French Massif Central, the genesis of the two late Carboniferous mineralizing systems coincided with the end of syn-collisional extension and ended just before post-collisional extension.     

Evidence and Implications of Recent Climate Change in Northern Alaska and Other Arctic Regions

The Arctic climate is changing. Permafrost is warming, hydrological processes are changing and biological and social systems are also evolving in response to these changing conditions. Knowing how the structure and function of arctic terrestrial ecosystems are responding to recent and persistent climate change is paramount to understanding the future state of the Earth system and how humans will need to adapt. Our holistic review presents a broad array of evidence that illustrates convincingly; the Arctic is undergoing a system-wide response to an altered climatic state. New extreme and seasonal surface climatic conditions are being experienced, a range of biophysical states and processes influenced by the threshold and phase change of freezing point are being altered, hydrological and biogeochemical cycles are shifting, and more regularly human sub-systems are being affected. Importantly, the patterns, magnitude and mechanisms of change have sometimes been unpredictable or difficult to isolate due to compounding factors. In almost every discipline represented, we show how the biocomplexity of the Arctic system has highlighted and challenged a paucity of integrated scientific knowledge, the lack of sustained observational and experimental time series, and the technical and logistic constraints of researching the Arctic environment. This study supports ongoing efforts to strengthen the interdisciplinarity of arctic system science and improve the coupling of large scale experimental manipulation with sustained time series observations by incorporating and integrating novel technologies, remote sensing and modeling.