Improvement of the solute transfer in a conceptual unsaturated zone scheme: a case study of the Seine River basin

For predicting the evolution of solute concentrations in groundwater and testing the impact of remediation policies, a coupling between the agronomical model STICS and the hydrogeological model MODCOU was implemented. When applied to the Seine River basin, this model accurately represents the temporal evolution of average nitrate concentrations in the aquifer, but with large local errors. We propose an improvement to the simple unsaturated zone (UZ) scheme NonsatSW used in STICS–MODCOU. The modifications are based on a comparison with the mechanistic model Metis considered as a reference as it solves Richards' equation. A more realistic saturation profile and a varying percolation rate are integrated in NonsatSW. This new model, named NonsatVG, is assessed by comparing it with NonsatSW and Metis. In an ideal case, NonsatVG generates a solute transfer and a dispersion closer to that of Metis than of NonsatSW. In real cases, without additional calibration, NonsatVG and Metis simulate better the average transfer velocities of the observed nitrate profiles. Furthermore, modifications in NonsatVG give a direct relationship between the depth of the water table and the saturation profile. We obtain, therefore, as in Metis, an evolution of the solute transfer velocity depending on the piezometric level. These dynamics are not simulated in NonsatSW. Despite a modified water transfer through the UZ, NonsatVG is also as valid as NonsatSW in the modelling of water transfer to the saturated zone. Finally, an application to the Seine basin shows that solute transfer velocities are lower with NonsatVG than with NonsatSW, but are in better agreement with literature. Copyright © 2010 John Wiley & Sons, Ltd.     

Quantitative Zn speciation in a contaminated dredged sediment by μ-PIXE, μ-SXRF, EXAFS spectroscopy and principal component analysis

Dredging and disposal of sediments onto agricultural soils is a common practice in industrial and urban areas that can be hazardous to the environment when the sediments contain heavy metals. This chemical hazard can be assessed by evaluating the mobility and speciation of metals after sediment deposition. In this study, the speciation of Zn in the coarse (500 to 2000 μm) and fine (<2 μm) fractions of a contaminated sediment dredged from a ship canal in northern France and deposited on an agricultural soil was determined by physical analytical techniques on raw and chemically treated samples. Zn partitioning between coexisting mineral phases and its chemical associations were first determined by micro-particle-induced X-ray emission and micro-synchrotron-based X-ray radiation fluorescence. Zn-containing mineral species were then identified by X-ray diffraction and powder and polarized extended X-ray absorption fine structure spectroscopy (EXAFS). The number, nature, and proportion of Zn species were obtained by a coupled principal component analysis (PCA) and least squares fitting (LSF) procedure, applied herein for the first time to qualitatively (number and nature of species) and quantitatively (relative proportion of species) speciate a metal in a natural system.The coarse fraction consists of slag grains originating from nearby Zn smelters. In this fraction, Zn is primarily present as sphalerite (ZnS) and to a lesser extent as willemite (Zn₂SiO₄), Zn-containing ferric (oxyhydr)oxides, and zincite (ZnO). In the fine fraction, ZnS and Zn-containing Fe (oxyhydr)oxides are the major forms, and Zn-containing phyllosilicate is the minor species. Weathering of ZnS, Zn₂SiO₄, and ZnO under oxidizing conditions after the sediment disposal accounts for the uptake of Zn by Fe (oxyhydr)oxides and phyllosilicates. Two geochemical processes can explain the retention of Zn by secondary minerals: uptake on preexisting minerals and precipitation with dissolved Fe and Si. The second process likely occurs because dissolved Zn and Si are supersaturated with respect to Zn phyllosilicate. EXAFS spectroscopy, in combination with PCA and LSF, is shown to be a meaningful approach to quantitatively determining the speciation of trace elements in sediments and soils.     

Multidecadal oscillatory behaviour of rainfall extremes in Europe

Many studies have observed changes in the frequency and intensity of precipitation extremes and floods during the last decade(s). Natural variability by climate oscillations partly determines the observed evolution of precipitation extremes. Based on a technique for the identification and analysis of changes in extremes, this paper shows that precipitation extremes have oscillatory behaviour at multidecadal time scales. The analysis is based on a unique dataset of 108 years of 10-minute precipitation intensities at Uccle (Brussels), not affected by instrumental changes. We also checked the consistency of the findings with long precipitation records at 724 stations across Europe and the Middle East. The past 100 years show for northwestern Europe, both in winter and summer, larger and more precipitation extremes around the 1910s, 1950–1960s, and more recently during the 1990s–2000s. The oscillations for southwestern Europe are anti-correlated with these of northwestern Europe, thus with oscillation highs in the 1930–1940s and 1970s. The precipitation oscillation peaks are explained by persistence in atmospheric circulation patterns over the North Atlantic during periods of 10 to 15 years.     

5. Prebiotic Chemistry – Biochemistry – Emergence of Life (4.4–2 Ga)

This chapter is devoted to a discussion about the difficulties and even the impossibility to date the events that occurred during the transition from non-living matter to the first living cells. Nevertheless, the attempts to devise plausible scenarios accounting for the emergence of the main molecular devices and processes found in biology are presented including the role of nucleotides at early stages (RNA world). On the other hand, hypotheses on the development of early metabolisms, compartments and genetic encoding are also discussed in relation with their role in extant living organisms. The nature of the Last Common Ancestor is also presented as well as hypotheses on the evolution of viruses. The following sections constitute a collection of independent articles providing a general overview of these aspects.     

Physical effects on the Lyα forest flux power spectrum: damping wings, ionizing radiation fluctuations and galactic winds

We explore several physical effects on the power spectrum of the Lyα forest transmitted flux. The effects we investigate here are not usually part of hydrodynamic simulations and so need to be estimated separately. The most important effect is that of high column density absorbers with damping wings, which add power on large scales. We compute their effect using the observational constraints on their abundance as a function of column density. Ignoring their effect leads to an underestimation of the slope of the linear theory power spectrum. The second effect we investigate is that of fluctuations in the ionizing radiation field. For this purpose we use a very large high-resolution N -body simulation, which allows us to simulate both the fluctuations in the ionizing radiation and the small-scale Lyα forest within the same simulation. We find an enhancement of power on large scales for quasars and a suppression for galaxies. The strength of the effect rapidly increases with increasing redshift, allowing it to be uniquely identified in cases where it is significant. We develop templates that can be used to search for this effect as a function of quasar lifetime, quasar luminosity function and attenuation length. Finally, we explore the effects of galactic winds using hydrodynamic simulations. We find the wind effects on the Lyα forest power spectrum to be degenerate with parameters related to the temperature of the gas that are already marginalized over in cosmological fits. While more work is needed to conclusively exclude all possible systematic errors, our results suggest that, in the context of data analysis procedures, where parameters of the Lyα forest model are properly marginalized over, the flux power spectrum is a reliable tracer of cosmological information.     

Anatomy of Piton de la Fournaise volcano (La Réunion, Indian Ocean)

The aim of this work is to propose a general model of Piton de la Fournaise volcano using information from geological and geophysical studies. Firstly, we make a graphical compilation of all available geophysical information along a W–E profile. Secondly, we construct a geological section that integrates both the geophysical information and the geological information. The lithosphere beneath Piton de la Fournaise is not significantly flexed, and the crust is underlain by an underplating body, which might represent the deep magma reservoir for La Réunion volcanism. Piton de la Fournaise is a relatively thin volcano lying on a huge volcanic construction attributed mostly to Les Alizés volcano. Indeed, if the differentiated rocks observed at the bottom of the Rivière des Remparts are the top of Les Alizés volcano, the interface with Piton de La Fournaise may be located at about sea level beneath the summit area. The endogenous constructions (intrusive complexes) related to Les Alizés and Piton de la Fournaise volcanoes represent a large volume. The huge intrusive complex of Les Alizés volcano probably rests on the top of the oceanic crust and appears to have a buttressing effect for the present eastern volcano-tectonic activity of Piton de la Fournaise. The early Piton de la Fournaise edifice was built around a focus located beneath the Plaine des Sables area. The center subsequently moved 5–6?km eastward to its current location. The dense, high-velocity body beneath the Plaines des Sables and the western part of the Enclos probably corresponds to the hypovolcanic intrusive complex that developed before the volcanic center shifted to its present-day position. Magma reservoirs may have existed, and may still exist, as illustrated by the March 1998 crisis, at the mechanical and density interface between the oceanic crust and the Les Alizés edifice. Strong evidence also exists for the presence of a shallower magma reservoir located near sea level beneath the summit. The March 1998 pre-eruptive seismic pattern (location and upward migration) seems to be evidence for a transfer of magma between the two reservoirs. The dominant structural feature of the central zone is a collapse structure beneath the summit craters, above the inferred magma reservoir near sea level. The collapsed column constitutes a major mechanical heterogeneity and concentrates most of the seismic, intrusive, and hydrothermal activity because of its higher permeability and weaker mechanical strength.     

Effects of current exposure on habitat preference of mobile 0-group epibenthos for intertidal seagrass beds (Zostera noltii) in the northern Wadden Sea

In the northern Wadden Sea, the extent of intertidal seagrass beds, their plant biomass and shoot density highly depends on local current regimes. This study deals with the role of intertidal Zostera noltii beds as nursery for mobile epibenthic macrofauna and the impact of seagrass bed characteristics on their abundance and distribution patterns. According to their exposure to the main tidal gullies, sampling sites were separated into exposed, semi-exposed and sheltered. Dominant species of crustaceans and demersal fish were studied in respect of their abundances within seagrass beds and adjacent unvegetated areas. Quantitative sampling was performed at day and night high tide using a portable drop trap. In general, species composition varied little between seagrass beds and bare sand. However, the presence of vegetation had a quantitative effect increasing individual numbers of common epifaunal species. Abundances of 0-group shore crabs (Carcinus maenas), common gobies (Pomatoschistus microps) and brown shrimps (Crangon crangon) were highest within sheltered seagrass beds. With decreasing plant density habitat preference of epibenthos changed on species level. By regulating the habitat complexity the currents regime is profoundly influencing the nursery function of intertidal seagrass beds in the Wadden Sea.     

A Simulation of Historic Hydrology and Salinity in Everglades National Park: Coupling Paleoecologic Assemblage Data with Regression Models

Restoration of Florida’s Everglades requires scientifically supportable hydrologic targets. This study establishes a restoration baseline by developing a method to simulate hydrologic and salinity conditions prior to anthropogenic changes. The method couples paleoecologic data on long-term historic ecosystem conditions with statistical models derived from observed meteorologic and hydrologic data that provide seasonal and annual variation. Results indicate that pre-drainage freshwater levels and hydroperiods in major sloughs of the Everglades were about 0.15 m higher and two to four times greater, respectively, on average compared to today’s values. Pre-drainage freshwater delivered to the wetlands and estuaries is estimated to be 2.5 to four times greater than the modern-day flow, and the largest deficit is during the dry season. In Florida Bay, salinity has increased between 5.3 and 20.1 with the largest differences in the areas near freshwater outflow points. These results suggest that additional freshwater flows to the Everglades are needed for restoration of the freshwater marshes of the Everglades and estuarine environment of Florida Bay, particularly near the end of the dry season.     

Measuring accelerometer dynamic range from seismic data using Allan deviation

We propose a new approach for calculating the dynamic range of an accelerometer based on an Allan deviation analysis of production seismic data. This test is intended as a field audit technique and does not require an unconditioned dataset from a low‐noise environment. We first show that Allan deviation can measure white noise levels using two commercial accelerometers. The analysis accurately captures the manufacturing noise density specifications and known relationships between white noise, preamplifier gain, and group forming. We then show that a production seismic dataset is suitable for an Allan deviation analysis because the results are not critically affected by a recording filter. Finally, we illustrate the proposed technique by calculating the dynamic range of an accelerometer channel in a seismic streamer using a production dataset.