High-frequency multi-solute calibration using an in situ UV–visible sensor

Monitoring the temporal variation of solute concentrations in streams at high temporal frequency can play an important role in understanding the hydrological and biogeochemical behaviour of catchments. UV–visible spectrometry is a relatively inexpensive and easily used tool to infer those concentrations in streams at high temporal resolution. However, it is not yet clear which solutes can be modelled with such an in-situ sensor. Here, we installed a UV–visible spectrometer probe (200–750 nm) in a high-altitude tropical Páramo stream to record the wavelength absorbance at a 5-min temporal resolution. For calibration, we simultaneously sampled stream water at a 4-h frequency from February 2018 to March 2019 for subsequent laboratory analysis. Absorbance spectra and laboratory-determined solute concentrations were used to identify the best calibration method and to determine which solute concentrations can be effectively inferred using in situ spectrometry through the evaluation of six calibration methods of different mathematical complexity. Based on the Nash – Sutcliffe efficiency (NSE) and Akaike information criterion metrics, our results suggest that multivariate methods always outperformed simpler strategies to infer solute concentrations. Eleven out of 21 studied solutes (Al, DOC, Ca, Cu, K, Mg, N, Na, Rb, Si and Sr) were successfully calibrated (NSE >0.50) and could be inferred using UV–visible spectrometry even with a reduced daily sampling frequency. It is worth noting that most calibrated solutes were correlated with wavelengths (WLs) in the low range of the spectra (i.e., UV range) and showed relatively good correlation with DOC. The latter suggests that estimation of metal concentrations could be possible in other streams with a high organic load (e.g., peat dominated catchments). In situ operation of spectrometers to monitor water quality parameters at high temporal frequency (sub-hourly) can enhance the protection of human water supplies and aquatic ecosystems as well as providing information for assessing catchment hydrological functioning.     

Catchment scale hydrology of an irrigated cropping system under soil conservation practices

Soil erosion by water is a pressing environmental problem caused and suffered by agriculture in Mediterranean environments. Soil conservation practices can contribute to alleviating this problem. The aim of this study is to gain more profound knowledge of the effects of conservation practices on soil losses by linking crop management and soil status to runoff and sediment losses measured at the outlet of a catchment during seven years. The catchment has 27.42 ha and is located in a commercial farm in southern Spain, where a package of soil conservation practices is an essential component of the farming system. The catchment is devoted to irrigated annual crops with maize–cotton–wheat as the primary rotation. Mean annual rainfall‐induced runoff coefficient was 0.14 and mean annual soil loss was 2.4 Mg ha^?1 y^?1. Irrigation contributed to 40% of the crop water supply, but the amount of runoff and sediment yield that it generated was negligible. A Principal Components Analysis showed that total soil loss is determined by the magnitude of the event (rainfall and runoff depths, duration) and by factors related to the aggressiveness of the events (rainfall intensity and preceding soil moisture). A third component showed the importance of crop coverage to reduce sediment losses. Cover crops grown during autumn and early winter and crop residues protecting the soil surface enhanced soil conservation notably. The role of irrigation to facilitate growing cover crops in Mediterranean environments is discussed. Copyright © 2016 John Wiley & Sons, Ltd.     

Limits on the detectability of the CMB B-mode polarization imposed by foregrounds

We investigate which practical constraints are imposed by foregrounds on the detection of the B-mode polarization generated by gravitational waves, in the case of experiments of the type currently being planned. As the B-mode signal is probably dominated by foregrounds at all frequencies, the detection of the cosmological component depends drastically on our ability to remove foregrounds. We provide an analytical expression with which to estimate the level of the residual polarization for Galactic foregrounds, according to the method employed for their subtraction. We interpret this result in terms of the lower limit of the tensor-to-scalar ratio r that allows us to disentangle the cosmological B-mode polarization from the foreground contribution. Polarized emission from extragalactic radio sources and gravitational lensing is also taken into account. As a first approach, we consider the ideal limit of an instrumental noise-free experiment: for full-sky coverage and a resolution of 1°, we obtain a limit of   r ∼ 10⁻⁴  . This value can be improved by high-resolution experiments and, in principle, there is no clear fundamental limit on the detectability of the polarization of gravitational waves. Our analysis is also applied to planned or hypothetical future polarization experiments, taking into account expected noise levels.     

An ultradeep submillimetre map: beneath the SCUBA confusion limit with lensing and robust source extraction

Extracting sources with low signal-to-noise ratio (S/N) from maps with structured background is a non-trivial task which has become important in studying the faint end of the submillimetre (submm) number counts. In this paper, we study the source extraction from submm jiggle-maps from the Submillimetre Common-User Bolometer Array (SCUBA) using the Mexican hat wavelet (MHW), an isotropic wavelet technique. As a case study, we use a large (11.8-arcmin²) jiggle-map of the galaxy cluster Abell 2218 (A2218), with a 850-μm 1σ rms sensitivity of 0.6–1 mJy. We show via simulations that MHW is a powerful tool for the reliable extraction of low-S/N sources from the SCUBA jiggle-maps and nine sources are detected in the A2218 850-μm image. Three of these sources are identified as images of a single background source with an unlensed flux of 0.8 mJy. Further, two single-imaged sources also have unlensed fluxes <2 mJy, below the blank-field confusion limit. In this ultradeep map, the individual sources detected resolve nearly all of the extragalactic background light at 850 μm, and the deep data allow to put an upper limit of 44 sources arcmin⁻² to 0.2 mJy at 850 μm.     

Temperate rainforest response to climate change and disturbance agents in northwestern Patagonia (41°S) over the last 2600 years

We present detailed pollen and charcoal records from Lago Pichilafquén (~ 41°S) to decipher the effects of climate change and varying disturbance regimes on the composition and structure of the vegetation on the Andean foothills of northwestern Patagonia during the last 2600 yr. Here, temperate rainforests have dominated the landscape since 2600 cal yr BP with variations ranging from cool-temperate and wet north Patagonian rainforests to relatively warm and summer-drought-resistant Valdivian rainforests. We interpret relatively warm/dry conditions between 1900–2600, 690–750 and 320–430 cal yr BP, alternating with cold/wet conditions between 1500–1900, 750–1100 and 430–690 cal yr BP. Rapid deforestation and spread of plants introduced by Europeans occurred at 320 and 140 cal yr BP. The record includes five tephras with ages of 2130, 1460, 1310, 1210, and 340 cal yr BP, all of which precede local fire events and increases in trees favored by disturbance by less than 100 yr. We conclude that centennial-scale changes in the southern westerlies were the primary driver of vegetation shifts in northwestern Patagonia over the last 2600 yr. Within this interval, local disturbance regimes altered the structure, composition, and dynamics of the lowland rainforest vegetation during several discrete, short-lived episodes.