High-frequency multi-solute calibration using an in situ UV–visible sensor

Monitoring the temporal variation of solute concentrations in streams at high temporal frequency can play an important role in understanding the hydrological and biogeochemical behaviour of catchments. UV–visible spectrometry is a relatively inexpensive and easily used tool to infer those concentrations in streams at high temporal resolution. However, it is not yet clear which solutes can be modelled with such an in-situ sensor. Here, we installed a UV–visible spectrometer probe (200–750 nm) in a high-altitude tropical Páramo stream to record the wavelength absorbance at a 5-min temporal resolution. For calibration, we simultaneously sampled stream water at a 4-h frequency from February 2018 to March 2019 for subsequent laboratory analysis. Absorbance spectra and laboratory-determined solute concentrations were used to identify the best calibration method and to determine which solute concentrations can be effectively inferred using in situ spectrometry through the evaluation of six calibration methods of different mathematical complexity. Based on the Nash – Sutcliffe efficiency (NSE) and Akaike information criterion metrics, our results suggest that multivariate methods always outperformed simpler strategies to infer solute concentrations. Eleven out of 21 studied solutes (Al, DOC, Ca, Cu, K, Mg, N, Na, Rb, Si and Sr) were successfully calibrated (NSE >0.50) and could be inferred using UV–visible spectrometry even with a reduced daily sampling frequency. It is worth noting that most calibrated solutes were correlated with wavelengths (WLs) in the low range of the spectra (i.e., UV range) and showed relatively good correlation with DOC. The latter suggests that estimation of metal concentrations could be possible in other streams with a high organic load (e.g., peat dominated catchments). In situ operation of spectrometers to monitor water quality parameters at high temporal frequency (sub-hourly) can enhance the protection of human water supplies and aquatic ecosystems as well as providing information for assessing catchment hydrological functioning.     

Unravelling evapotranspiration controls and components in tropical Andean tussock grasslands

The study of the environmental factors that control evapotranspiration and the components of evapotranspiration leads to a better understanding of the actual evapotranspiration (ET) process that links the functioning of the soil, water and atmosphere. It also improves local, regional and global ET modelling. Globally, few studies so far focussed on the controls and components of ET in alpine grasslands, especially in mountainous sites such as the tussock grasslands located in the páramo biome (above 3300 m a.s.l.). The páramo occupies 35 000 km² and provides water resources for many cities in the Andes. In this article, we unveiled the controls on ET and provided the first insights on the contribution of transpiration to ET. We found that the wet páramo is an energy-limited region and net radiation (Rn) is primarily controlling ET. ET was on average 1.7 mm/day. The monthly average evaporative fraction (ET/Rn) was 0.47 and it remained similar for wet and dry periods. The secondary controls on ET were wind speed, aerodynamic resistance and surface resistance that appeared more important for dry periods, where significantly higher ET rates were found (20% increase). During dry events, transpiration was on average 1.5 mm/day (range 0.7–2.7 mm/day), similar to other tussock grasslands in New Zealand (range 0.6–3.3 mm/day). Evidence showed interception contributes more to ET than transpiration. This study sets a precedent towards a better understanding of the evapotranspiration process and will ultimately lead to a better land-atmosphere fluxes modelling in the tropics.     

Long-lasting floods buffer the thermal regime of the Pampas

The presence of large water masses influences the thermal regime of nearby land shaping the local climate of coastal areas by the ocean or large continental lakes. Large surface water bodies have an ephemeral nature in the vast sedimentary plains of the Pampas (Argentina) where non-flooded periods alternate with flooding cycles covering up to one third of the landscape for several months. Based on temperature records from 17 sites located 1 to 700 km away from the Atlantic coast and MODIS land surface temperature data, we explore the effects of floods on diurnal and seasonal thermal ranges as well as temperature extremes. In non-flooded periods, there is a linear increase of mean diurnal thermal range (DTR) from the coast towards the interior of the region (DTR increasing from 10 to 16 K, 0.79 K/100 km, r ² = 0.81). This relationship weakens during flood episodes when the DTR of flood-prone inland locations shows a decline of 2 to 4 K, depending on surface water coverage in the surrounding area. DTR even approaches typical coastal values 500 km away from the ocean in the most flooded location that we studied during the three flooding cycles recorded in the study period. Frosts-free periods, a key driver of the phenology of both natural and cultivated ecosystems, are extended by up to 55 days during floods, most likely as a result of enhanced ground heat storage across the landscape (~2.7 fold change in day-night heat transfer) combined with other effects on the surface energy balance such as greater night evaporation rates. The reduced thermal range and longer frost-free periods affect plant growth development and may offer an opportunity for longer crop growing periods, which may not only contribute to partially compensating for regional production losses caused by floods, but also open avenues for flood mitigation through higher plant evapotranspirative water losses.     

Diversity of faunal assemblages associated with ribbed mussel beds along the South American coast: relative roles of biogeography and bioengineering

Benthic organisms are among the most diverse and abundant in the marine realm, and some species are a key factor in studies related to bioengineering. However, their importance has not been well noted in biogeographic studies. Macrofaunal assemblages associated with subtidal beds of the ribbed mussel (Aulacomya atra) along South America were studied to assess the relationship between their diversity patterns and the proposed biogeographic provinces in the Southeastern Pacific and Southwestern Atlantic Oceans. Samples from ribbed mussel beds were obtained from 10 sites distributed from the Peruvian coast (17°S) to the Argentinean coast (41°S). The sampling included eight beds in the Pacific and two in the Atlantic and the collections were carried out using five 0.04 m² quadrants per site. Faunal assemblages were assessed through classification analyses using binary and log‐transformed abundance data. Variation in the size and density of mussels, and in the species richness, abundance and structure of their faunal assemblages were tested using a permutational multivariate analysis of variance. Faunal assemblages showed a north–south latitudinal gradient along both the Pacific and Atlantic coasts. Binary and abundance data showed a difference in the resulting clustering arrangement of Pacific sites between 40°S and 44°S, indicating a pattern of continuity in the species distribution associated with biological substrates. At a regional scale, the distribution of species along the South American coast matched the general provincial pattern shown by prior studies, which show two biogeographic units on the Pacific coast separated by an intermediate (probably transitional) zone and a single province on the Atlantic coast extending up to Northern Argentina. Biological substrates such as ribbed mussel beds play an important ecological role by making a similar habitat type available on a large scale for a variety of invertebrate species. Despite such habitat homogeneity, however, the associated fauna exhibit marked distribution breaks, suggesting strong constraints on dispersal. This therefore suggests that macrofaunal assemblages could possibly be used as biogeographic indicators.     

Preliminary evaluation of the runoff processes in a remote montane cloud forest basin using Mixing Model Analysis and Mean Transit Time

In this study, the Mean Transit Time and Mixing Model Analysis methods are combined to unravel the runoff generation process of the San Francisco River basin (73.5 km²) situated on the Amazonian side of the Cordillera Real in the southernmost Andes of Ecuador. The montane basin is covered with cloud forest, sub‐páramo, pasture and ferns. Nested sampling was applied for the collection of streamwater samples and discharge measurements in the main tributaries and outlet of the basin, and for the collection of soil and rock water samples. Weekly to biweekly water grab samples were taken at all stations in the period April 2007–November 2008. Hydrometric data, Mean Transit Time and Mixing Model Analysis allowed preliminary evaluation of the processes controlling the runoff in the San Francisco River basin. Results suggest that flow during dry conditions mainly consists of lateral flow through the C‐horizon and cracks in the top weathered bedrock layer, and that all subcatchments have an important contribution of this deep water to runoff, no matter whether pristine or deforested. During normal to low precipitation intensities, when antecedent soil moisture conditions favour water infiltration, vertical flow paths to deeper soil horizons with subsequent lateral subsurface flow contribute most to streamflow. Under wet conditions in forested catchments, streamflow is controlled by near surface lateral flow through the organic horizon. Exceptionally, saturation excess overland flow occurs. By absence of the litter layer in pasture, streamflow under wet conditions originates from the A horizon, and overland flow. Copyright © 2011 John Wiley & Sons, Ltd.     

Catchment scale hydrology of an irrigated cropping system under soil conservation practices

Soil erosion by water is a pressing environmental problem caused and suffered by agriculture in Mediterranean environments. Soil conservation practices can contribute to alleviating this problem. The aim of this study is to gain more profound knowledge of the effects of conservation practices on soil losses by linking crop management and soil status to runoff and sediment losses measured at the outlet of a catchment during seven years. The catchment has 27.42 ha and is located in a commercial farm in southern Spain, where a package of soil conservation practices is an essential component of the farming system. The catchment is devoted to irrigated annual crops with maize–cotton–wheat as the primary rotation. Mean annual rainfall‐induced runoff coefficient was 0.14 and mean annual soil loss was 2.4 Mg ha^?1 y^?1. Irrigation contributed to 40% of the crop water supply, but the amount of runoff and sediment yield that it generated was negligible. A Principal Components Analysis showed that total soil loss is determined by the magnitude of the event (rainfall and runoff depths, duration) and by factors related to the aggressiveness of the events (rainfall intensity and preceding soil moisture). A third component showed the importance of crop coverage to reduce sediment losses. Cover crops grown during autumn and early winter and crop residues protecting the soil surface enhanced soil conservation notably. The role of irrigation to facilitate growing cover crops in Mediterranean environments is discussed. Copyright © 2016 John Wiley & Sons, Ltd.     

Continuous versus event‐based sampling: how many samples are required for deriving general hydrological understanding on Ecuador's páramo region?

As a consequence of the remote location of the Andean páramo, knowledge on their hydrologic functioning is limited; notwithstanding, these alpine tundra ecosystems act as water towers for a large fraction of the society. Given the harsh environmental conditions in this region, year‐round monitoring is cumbersome, and it would be beneficial if the monitoring needed for the understanding of the rainfall–runoff response could be limited in time. To identify the hydrological response and the effect of temporal monitoring, a nested (n = 7) hydrological monitoring network was set up in the Zhurucay catchment (7.53 km²), south Ecuador. The research questions were as follows: (1) Can event sampling provide similar information in comparison with continuous monitoring, and (2) if so, how many events are needed to achieve a similar degree of information? A subset of 34 rainfall–runoff events was compared with monthly values derived from a continuous monitoring scheme from December 2010 to November 2013. Land cover and physiographic characteristics were correlated with 11 hydrological indices. Results show that despite some distinct differences between event and continuous sampling, both data sets reveal similar information; more in particular, the monitoring of a single event in the rainy season provides the same information as continuous monitoring, while during the dry season, ten events ought to be monitored. Copyright © 2016 John Wiley & Sons, Ltd.