R/V Isabu-Based First Ultraclean Seawater Sampling for Ocean Trace Elements in Korea

Ocean Science Journal - Trace elements (Mn, Fe, Co, Ni, Cu, Zn, etc.) are essential micronutrients for marine organisms and are thus related to major issues in the ocean, such as climate change,...     

Tracing offshore low-salinity plumes in the Northeastern Gulf of Mexico during the summer season by use of multispectral remote-sensing data

To trace offshore surface low-salinity water (LSW) in the northeastern Gulf of Mexico, a proxy was developed using the surface water beam attenuation coefficient (c _p), and salinity matched with synchronous Sea-viewing Wide Field-of-view Sensor (SeaWiFS) satellite data from three annual summer cruises (July 1998–August 2000) using a two-step empirical approach. First, a relationship between in-situ salinity and c _p was obtained. Second, in-situ c _p was matched with SeaWiFS radiance ratios of all available blue-to-green wavelengths. Finally, satellite-derived surface salinity was determined directly by combining the two empirical relationships, providing a robust estimate over a range of salinities (26–36). This significantly improves the limited spatial and temporal resolution of surface salinity distribution obtained by shipboard sampling. The resulting correlation is best explained as mixing between low-salinity plume waters and normal salinity Gulf waters. The empirical relationships were used to map satellite-derived salinity using the average of SeaWiFS images during each summer cruise. As expected for summer, spatial patterns of LSW plumes with high c _p, particulate matter (PM), particulate organic carbon (POC), and chlorophyll-a (Chl-a) were connected to the mouth of the Mississippi River Delta and extended to the east-southeast. Normal salinity Gulf water with lower c _p, PM, POC, and Chl-a was confined to the shelf and upper slope in the eastern part of the study area, outside the plumes. This proxy approach can be applied throughout the region of shipboard sampling for more detailed coverage and analysis.     

Effects of the degree of polymerization on the structure of sodium silicate and aluminosilicate glasses and melts: An O NMR study

Revealing the atomic structure and disorder in oxide glasses, including sodium silicates and aluminosilicates, with varying degrees of polymerization, is a challenging problem in high-temperature geochemistry as well as glass science. Here, we report ¹⁷O MAS and 3QMAS NMR spectra for binary sodium silicate and ternary sodium aluminosilicate glasses with varying degrees of polymerization (Na₂O/SiO₂ ratio and Na₂O/Al₂O₃ ratio), revealing in detail the extent of disorder (network connectivity and topological disorder) and variations of NMR parameters with the glass composition. In binary sodium silicate glasses [Na₂O-k(SiO₂)], the fraction of non-bridging oxygens (NBOs, Na-O-Si) increases with the Na₂O/SiO₂ ratio (k), as predicted from the composition. The ¹⁷O isotropic chemical shifts (¹⁷O δ_iso) for both bridging oxygen (BO) and NBO increase by about 10-15 ppm with the SiO₂ content (for k = 1-3). The quadrupolar coupling products of BOs and NBOs also increase with the SiO₂ content. These trends suggest that both NBOs and BOs strongly interact with Na; therefore, the Na distributions around BOs and NBOs are likely to be relatively homogenous for the glass compositions studied here, placing some qualitative limits on the extent of segregation of alkali channels from silica-enriched regions as suggested by modified random-network models. The peak width (in the isotropic dimension) and thus bond angle and length distributions of Si-O-Si and Na-O-Si increase with the SiO₂ content, indicating an increase in the topological disorder with the degree of polymerization. In the ternary aluminosilicate glasses [Na₂O]_x[Al₂O₃]_1−xSiO₂, the NBO fraction decreases while the Al-O-Si and Al-O-Al fractions apparently increase with increasing Al₂O₃ content. The variation of oxygen cluster populations suggests that deviation from “Al avoidance” is more apparent near the charge-balanced join (Na/Al = 1). The Si-O-Si fraction, which is closely related to the activity coefficient of silica, would decrease with increasing Al₂O₃ content at a constant mole fraction of SiO₂. Therefore, the activity of silica may decrease from depolymerized binary silicates to fully polymerized sodium aluminosilicate glasses at a constant mole fraction of SiO₂.     

Landslide susceptibility mapping in the Damrei Romel area, Cambodia using frequency ratio and logistic regression models

This study applied, tested and compared a probability model, a frequency ratio and statistical model, a logistic regression to Damre Romel area, Cambodia, using a geographic information system. For landslide susceptibility mapping, landslide locations were identified in the study area from interpretation of aerial photographs and field surveys, and a spatial database was constructed from topographic maps, geology and land cover. The factors that influence landslide occurrence, such as slope, aspect, curvature and distance from drainage were calculated from the topographic database. Lithology and distance from lineament were extracted and calculated from the geology database. Land cover was classified from Landsat TM satellite imagery. The relationship between the factors and the landslides was calculated using frequency ratio and logistic regression models. The relationships, frequency ratio and logistic regression coefficient were overlaid to make landslide susceptibility map. Then the landslide susceptibility map was compared with known landslide locations and tested. As the result, the frequency ratio model (86.97%) and the logistic regression (86.37%) had high and similar prediction accuracy. The landslide susceptibility map can be used to reduce hazards associated with landslides and to land cover planning.     

Assessing temporary carbon sequestration and storage projects through land use, land-use change and forestry: comparison of dynamic life cycle assessment with ton-year approaches

In order to properly assess the climate impact of temporary carbon sequestration and storage projects through land-use, land-use change and forestry (LULUCF), it is important to consider their temporal aspect. Dynamic life cycle assessment (dynamic LCA) was developed to account for time while assessing the potential impact of life cycle greenhouse gases (GHG) emissions. In this paper, the dynamic LCA approach is applied to a temporary carbon sequestration project through afforestation, and the results are compared with those of the two principal ton-year approaches: the Moura-Costa and the Lashof methods. The dynamic LCA covers different scenarios, which are distinguished by the assumptions regarding what happens at the end of the sequestration period. In order to ascertain the degree of compensation of an emission through a LULUCF project, the ratio of the cumulative impact of the project to the cumulative impact of a baseline GHG emission is calculated over time. This ratio tends to 1 when assuming that, after the end of the sequestration project period, the forest is maintained indefinitely. Conversely, the ratio tends to much lower values in scenarios where part of the carbon is released back to the atmosphere due to e.g. fire or forest exploitation. The comparison of dynamic LCA with the ton-year approaches shows that it is a more flexible approach as it allows the consideration of every life cycle stage of the project and it gives decision makers the opportunity to test the sensitivity of the results to the choice of different time horizons.     

Development of an Operational Hybrid Data Assimilation System at KIAPS

This study introduces the operational data assimilation (DA) system at the Korea Institute of Atmospheric Prediction Systems (KIAPS) to the numerical weather prediction community. Its development history and performance are addressed with experimental illustrations and the authors’ previously published studies. Milestones in skill improvements include the initial operational implementation of three-dimensional variational data assimilation (3DVar), the ingestion of additional satellite observations, and changing the DA scheme to a hybrid four-dimensional ensemble-variational DA using forecasts from an ensemble based on the local ensemble transform Kalman filter (LETKF). In the hybrid system, determining the relative contribution of the ensemble-based covariance to the resultant analysis is crucial, particularly for moisture variables including a variety of horizontal scale spectra. Modifications to the humidity control variable, partial rather than full recentering of the ensemble for humidity further improves moisture analysis, and the inclusion of more radiance observations with higher-level peaking channels have significant impacts on stratosphere temperature and wind performance. Recent update of the operational hybrid DA system relative to the previous 3DVar system is described for detailed improvements with interpretation.     

On the polarization of Hα scattered by neutral hydrogen in active galactic nuclei

Raman scattering by atomic hydrogen converts the UV continuum around Lyβ into optical continuum around Hα, and the basic atomic physics has been discussed in several works on symbiotic stars. We propose that the same process may operate in active galactic nuclei (AGN) and calculate the linear polarization of the broad emission lines Raman-scattered by high-column neutral hydrogen component. The conversion efficiency of the Raman scattering process is discussed and the expected scattered flux is computed using the spectral energy distribution of an AGN given by a typical power law. The high-column H  i component in AGN is suggested by many observations, encompassing the radio through UV and X-ray ranges.   When neutral hydrogen component with a column density ∼10²² cm⁻² is present around the active nucleus, it is found that the scattered Hα is characterized by a very broad width ∼20 000 km s⁻¹ and that the strength of the polarized flux is comparable to that of the electron-scattered flux expected from a conventional unified model of narrow-line AGN. The width of the scattered flux is mainly determined by the column density of the neutral scatterers where the total scattering optical depth becomes of order unity. The asymmetry in the Raman scattering cross-section around Lyβ introduces red asymmetric polarized profiles around Hα. The effects of the blended Lyβ and O  vi 1034 doublet are also investigated.   We briefly discuss the spectropolarimetric observations performed on the Seyfert galaxy IRAS 110548-1131 and the narrow line radio galaxy Cyg A. Several predictions regarding the scattering by the high-column neutral hydrogen component in AGN are discussed.     

Characteristics analysis for the flash flood-induced debris flows

Typhoon Haitang caused landfall on Taiwan during 15–21 July, 2005 and brought 2,279 mm of maximum cumulative rain with a maximum intensity of 176 mm/h. The torrential rain was mainly distributed from the central mountain range to southern Taiwan and triggered 222 slopeland-related hazards. Among the hazard events, there were 17 debris flows, 157 cases of traffic cut-off, three large-magnitude deep-seated landslides, and 10 villages isolated in the off-track mountainous areas. The debris flows initiated in southern Taiwan were associated with torrential rain, short channel length (<2 km), and small basin area (<3 km²), and were speculated to be induced by flash flood. These flash flood-induced debris flows have a higher rainfall intensity-duration threshold for initiation than in other areas. The deep-seated landslides, isolated villages due to traffic cut-off in off-track mountain areas, and recurrent hazards in areas affected by the M_L 7.6 Chi-Chi earthquake in 1999 are characteristics of slopeland hazards in Taiwan in recent years. One of the most urgently needed mitigation strategies in response to slopeland hazards is the plan for enhancing self-rescue disaster resistance in off-track mountainous villages in Taiwan.     

How are storm time injections different from nonstorm time injections?

One of the key elements of storms and substorms is the injection of energetic particles into the region of near geosynchronous orbit, that is, the sudden flux enhancement in the energy range of tens to hundreds of keV. This paper reports the observational results on how such injection features during storm times are different from those of nonstorm times. We particularly focus on the difference between proton injections and electron injections. Based on a number of storm time injection events that meet our strict selection criteria, we find a notable difference between proton injections and electron injections in the energy-spectral dependence of the flux enhancement averaged over the first 30 min after the injection onset: The average flux enhancement of many protons injections tends to be bigger at higher energy channels than at lower energy channels, but electron injections exhibit the opposite tendency for the energy-spectral dependence of flux enhancement, i.e., average flux enhancement decreasing with increasing energy. We show that this feature is almost unique only for the injection events during the storm main and early recovery phase. It is suggested that any successful scenario intended to model storm time injections should be able to explain this difference between proton injections and electron injections.